Catalysts for oxidation of carbon monoxide and/or volatile organic compounds

Patent metadata

Field	Value
Publication number	US-9399208-B2
Application number	US-201414465471-A
Country	US
Kind code	B2
Filing date	Aug 21, 2014
Priority date	Aug 23, 2013
Publication date	Jul 26, 2016
Grant date	Jul 26, 2016

Abstract

This application discloses catalysts and methods of making the catalysts. In one embodiment, a catalyst comprising: a reduced precious group metal in an amount greater than about 30 wt % based on the total precious group metal weight in the catalyst, wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at a temperature of about 150° C. or lower, is disclosed. In another embodiment, a catalyst for oxidation of formaldehyde, methanol, formic acid, and/or carbon monoxide to form carbon dioxide at a temperature of from about 20° C. to about 45° C. and at about atmospheric pressure, the catalyst comprising: a reduced precious group metal dispersed on a support selected from the group consisting of CeO 2 , TiO 2 , ZrO 2 , Al 2 O 3 , SiO 2 , and combinations thereof, is disclosed.

First claim

What is claimed is:

1. A catalyst comprising:
a precious group metal,
wherein between about 30 wt % and about 95 wt % of the precious group metal is a reduced precious group metal, and
wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at a temperature ranging from about 15° C. to about 50° C. and at an atmospheric pressure.

2. The catalyst of claim 1 , wherein the reduced precious group metal has a mean crystallite size of about 3 nm or less.

3. The catalyst of claim 1 , wherein the reduced precious group metal is selected from the group consisting of platinum, palladium, rhodium, ruthenium, iridium, gold, and mixtures thereof.

4. The catalyst of claim 1 , wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at temperatures ranging from about 15° C. to about 30° C.

5. The catalyst of claim 1 , wherein the reduced precious group metal is dispersed on a support selected from the group consisting of CeO 2 , ZrO 2 , TiO 2 , SiO 2 , Al 2 0 3 , clay, zeolite, and mixtures thereof.

6. The catalyst of claim 1 , wherein the reduced precious group metal is dispersed on a support selected from the group consisting of a polymer, activated carbon, cellulose, wood, powder, and mixtures thereof.

7. The catalyst of claim 1 , wherein the reduced precious group metal is dispersed on a composite material support, inorganic support, organic support, or combinations thereof.

8. A catalytic system comprising the catalyst of claim 1 .

9. The catalyst of claim 1 , wherein the oxidation of the volatile organic compounds and/or the carbon monoxide to form carbon dioxide at a temperature of from about 20° C. to about 45° C. and at about atmospheric pressure is completed at a conversion of about 90% or higher.

10. The catalyst of claim 9 , wherein the conversion is about 95% or higher.

11. A catalyst comprising:
a precious group metal,
wherein between about 30 wt % and about 95 wt % of the precious group metal is a reduced precious group metal,
wherein the reduced precious group metal is dispersed on a support selected from the group consisting of CeO 2 , TiO 2 , ZrO 2 , Al 2 0 3 , SiO 2 , and combinations thereof, and
wherein the catalyst oxidizes volatile organic compounds and/or carbon monoxide at a temperature ranging from about 20° C. to about 45° C. and at about an atmospheric pressure.

12. The catalyst of claim 11 , wherein the oxidation of the volatile organic compounds and/or the carbon monoxide to form carbon dioxide at a temperature of from about 20° C. to about 45° C. and at about atmospheric pressure is completed at a conversion of about 90% or higher.

13. The catalyst of claim 11 , wherein the reduced precious group metal is selected from the group consisting of platinum, palladium, rhodium, ruthenium, iridium, gold, and mixtures thereof.

14. The catalyst of claim 11 , wherein the catalyst is promoted by bismuth oxide.

15. The catalyst of claim 14 , wherein the weight ratio of bismuth to the reduced precious group metal is between about 0.1 to about 100.

16. The catalyst of claim 11 , wherein the volatile organic compounds include formaldehyde, methanol, and/or formic acid.

17. A method of making a precious group metal catalyst comprising:
(i) impregnating a precious group metal on a support in the form of a dissolved salt solution; and
(ii) reducing the precious group metal in cationic form to a reduced precious group metal in metallic form by reductants in liquid phase, solid phase, or combinations thereof,
wherein the reductants in liquid or solid phase are formic acid, ammonium formate, ascorbic acid, hydrazine, and combinations thereof.

18. The method of claim 17 , wherein step (i) is completed by incipient wetness, rotary evaporation, spray drying, or combinations thereof.

19. The catalyst obtained from the method of claim 17 .

20. The catalyst of claim 19 is coated on a monolith honeycomb, a formed refractory oxide substrate, a formed polymer substrate, or combinations thereof.

21. The catalyst of claim 19 removes and/or oxidizes carbon monoxide and/or volatile organic compounds including alkanes, alkenes, alcohols, aldehydes, ketones, amines, organic acids, aromatic compounds, or combinations thereof, from a medium.

22. The catalyst of claim 21 wherein the medium is air or water.

23. The catalyst of claim 19 , wherein at least about 500 ppm of water is added to a reactant gas mixture to promote oxidation of carbon monoxide and/or to remove moisture from the reactant gas mixture to maximize oxidation of volatile organic compounds.

Assignees

• Basf Corp

Inventors

• Yang Xiaolin
• Tran Pascaline
• Hu Qingyuan

Classifications

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/77

  Compounds characterised by their crystallite size · CPC title

• B01J35/006

  Operations & Transport · mapped topic