Solar cell front contact doping
US-2015380600-A1 · Dec 31, 2015 · US
US9397244B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9397244-B2 |
| Application number | US-201514686084-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 14, 2015 |
| Priority date | Apr 22, 2014 |
| Publication date | Jul 19, 2016 |
| Grant date | Jul 19, 2016 |
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A photodiodes array includes a useful layer made of Cd x Hg 1-x Te; first doped zones each forming a PN junction with a second doped zone surrounding the first doped zones. The array includes regions located between two PN junctions, with a cadmium concentration gradient decreasing from the upper face to the lower face of the useful layer. A method of making such a photodiodes array includes producing, on the upper face of the useful layer, of a structured layer with at least one through opening, and with a cadmium concentration higher than the cadmium concentration in the useful layer; annealing the useful layer covered by the structured layer, with diffusion of cadmium atoms of the structured layer, from the structured layer to the useful layer; producing at least two PN junctions in the useful layer.
Opening claim text (preview).
The invention claimed is: 1. A photodiodes array comprising: a useful layer made of a semiconducting alloy of cadmium, mercury and tellurium of the Cd x Hg 1-x Te type, the useful layer having an upper face and a lower face; at least two first doped zones, located in the useful layer, each forming a PN junction with a second doped zone surrounding the first doped zones, the PN junctions being flush with the upper face of the useful layer; wherein the array comprises at least one region, located between two neighbouring PN junctions, and has a cadmium concentration gradient decreasing from the upper face to the lower face of the useful layer. 2. The array according to claim 1 , wherein the average concentration of cadmium in said region is higher than the average concentration of cadmium in the remainder of the useful layer. 3. The array according to claim 1 , wherein said region extends between two PN junctions, and outside each first doped zone. 4. The array according to claim 3 , wherein said region extends in the useful layer deeper than the first doped zones. 5. The array according to claim 1 , wherein said region extends between two PN junctions, and in an upper peripheral volume of each of the first doped zones. 6. The array according to claim 5 , wherein said region extends in the useful layer less deep than the first doped zones. 7. The array according to claim 5 , wherein said region extends in a first doped zone over less than half of the volume of this first doped zone. 8. The array according to claim 1 , wherein said region has: a first portion extending outside the first doped zones; and a second portion extending in an upper peripheral volume of at least one first doped zone; the first portion extending deeper in the useful layer than the second portion, and the first portion being surrounded by the second portion. 9. The array according to claim 1 , wherein the first doped zone is P-doped by arsenic atoms. 10. A method of fabrication of a photodiodes array according to claim 1 , comprises the following steps: producing, on the upper face of the useful layer, a structured layer with at least one through opening, and with a cadmium concentration higher than the cadmium concentration in the useful layer; annealing of the useful layer covered by the structured layer, with diffusion of cadmium atoms of the structured layer, from the structured layer to the useful layer; producing at least two PN junctions in the useful layer. 11. The method according to claim 10 , wherein the production of a structured layer involves: depositing of a reservoir layer on the upper face of the useful layer; and etching of at least one through opening in the reservoir layer, the etching being a chemical etching. 12. The method according to claim 10 , wherein the steps of production of a structured layer and annealing form a fabrication cycle, and at least two fabrication cycles are implemented. 13. The method according to claim 10 , wherein the step of production of the PN junctions make use of an arsenic ion implantation. 14. The method according to claim 10 , wherein annealing is done at a temperature of between 100° C. and 500° C. 15. The method according to claim 14 , wherein annealing is done for a duration of between 1 hour and 100 hours.
characterised by the dopants · CPC title
Shapes of potential barriers · CPC title
comprising at least three elements, e.g. HgCdTe · CPC title
having multiple elements covered by H10F30/00 in a repetitive configuration, e.g. radiation detectors comprising photodiode arrays · CPC title
the at least one element covered by H10F30/00 having potential barriers, e.g. integrated devices comprising photodiodes or phototransistors · CPC title
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