Apparatus and method for sputter-deposited coatings on fluidized particle beds

Patent metadata

Field	Value
Publication number	US-9394604-B2
Application number	US-201313863081-A
Country	US
Kind code	B2
Filing date	Apr 15, 2013
Priority date	Apr 16, 2012
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

A method and an apparatus for producing metal and ceramic coatings on a fluidized bed of particles or fibers are described. The method utilizes a unique apparatus to transfer vibratory motion through a wall of a deposition chamber in order to produce a fluidized bed of particle or fluidized bed of fibers inside the chamber. The method and apparatus are versatile, allowing particles of different shapes, sizes, materials and masses to be fluidized and coated. The fluidization process allows uniform and conformal coatings on particles and fibers. Coatings of pure metals, alloys, or ceramic materials can be produced.

First claim

The invention claimed is:

1. A method for physical vapor deposition of a coating onto a plurality of particles or fibers, the method comprising:
placing a plurality of particles or fibers in a holder in a chamber,
sealing the chamber,
reducing the pressure inside the chamber,
vibrating the holder and the plurality of particles or fibers in the holder with a means for generating vibration wherein the means for generating vibration is external to the chamber and is connected to the holder through the wall of the chamber via a sealed, mechanical linkage that extends through a wall of the chamber,
and depositing a metal coating or a ceramic coating onto the plurality of particles or fibers.

2. The method of claim 1 wherein the metal coating or the ceramic coating is deposited via sputtering.

3. The method of claim 1 wherein the metal coating or the ceramic coating is deposited via evaporation.

4. The method of claim 1 wherein the means for generating vibration is selected from the group consisting of electromagnetic and piezoelectric shakers.

5. The method of claim 1 wherein the sealed, mechanical linkage comprises a rotary feed-through that transmits the vibration that is generated external to the chamber by the means for generating vibration through a wall of the chamber to the holder inside of the chamber while maintaining reduced pressure inside of the chamber.

6. The method of claim 1 wherein the mechanical linkage comprises an angled metal or an angled composite rod.

7. The method of claim 1 wherein the mechanical linkage comprises a first rigid angled rod that is coupled to the means for generating vibrations, a first shaft coupler rigidly connecting first rigid angled rod to a vacuum-rated rotary motion feedthrough, a second shaft coupler rigidly coupling the feedthrough to a second rigid metal rod that is rigidly connected to the holder.

8. The method of claim 1 wherein the chamber includes more than one deposition source and the coating on the particles comprises an alloy of deposited materials.

9. The method of claim 1 wherein the chamber includes more than one deposition source and the coating on the particles comprises a multi-layer coating.

10. The method of claim 1 wherein the means for generating vibrations and the sealed, mechanical linkage that extends through a wall of the chamber generates a vibrofluidized bed of particles or fibers.

11. The method of claim 1 wherein the particles or fibers are scavengable or soluble and after coating, the coated particles or coated fibers are placed in a scavenging environment to remove the particle and leave the coating as a free-standing shell.

12. The method of claim 1 wherein the environment within the coating chamber is reactive with respect to the coating material.

13. The method of claim 1 wherein the environment within the coating chamber is inert with respect to the coating material.

14. The method of claim 1 wherein the metal coating or the ceramic coating provides desired spectral reflectivity that varies with wavelength.

15. The method of claim 1 wherein the particle comprises a metal coating that provides increased electrical conductivity.

16. The method of claim 1 wherein the particle comprises a metal coating that provides a barrier that inhibits physical degradation of the particle due to environmental factors.

17. The method of claim 16 wherein the particle comprises a barrier that inhibits physical degradation of the particle due to environmental conditions and comprises Cu, Ag, Au, Al, Ni, Cr, Ti, and alloys of the same.

18. The method of claim 1 wherein the particle is selected from the group comprising NaCl, WCl 6 , WOCl 4 , RuCl 3 .3H 2 O, Grubbs catalysts, and Schrock catalysts.

19. The method of claim 1 wherein the particle is water soluble.

20. The method of claim 1 wherein particle is water reactive.

21. The method of claim 1 wherein particle is oxygen reactive.

22. A composite material comprising coated particles produced by the method of claim 1 .

23. The method of claim 1 wherein the mechanical linkage transfers vibratory motion from outside the chamber to inside the chamber.

24. The method of claim 1 wherein the mechanical linkage is a ferro-magnetic fluid rotary feedthrough.

Assignees

• Baechle Daniel Murphy
• Wetzel Eric D
• Us Army

Inventors

• Baechle Daniel Murphy
• Wetzel Eric D

Classifications

• C23C14/50 Primary

  Substrate holders · CPC title

• Y10T428/2991

  Coated · CPC title

• Y10T428/2993

  Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.] · CPC title