Polychloroprene latex, rubber composition and dip-molded article

Patent metadata

Field	Value
Publication number	US-9394454-B2
Application number	US-201214006579-A
Country	US
Kind code	B2
Filing date	Mar 29, 2012
Priority date	Apr 6, 2011
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

Provided is a polychloroprene latex that shows favorable low-temperature stability without deterioration in the rubber agglutinating property during production of the dip-molded article, a rubber composition, and a dip-molded article, prepared by using the same.
Prepared is a polychloroprene latex of a chloroprene copolymer obtained by polymerization of raw monomers at least containing chloroprene and 2,3-dichloro-1,3-butadiene, which is dispersed in water, wherein the 2,3-dichloro-1,3-butadiene content in the raw monomers is controlled to 1 to 30 mass % and the potassium ion content is adjusted to 0.7 to 1.5 parts by mass and the sodium ion content to 0.2 part or less by mass with respect to 100 parts by mass of the solid matter. In addition, a metal oxide: 1 to 10 parts by mass, sulfur: 0.1 to 3 parts by mass, an aging inhibitor: 0.1 to 5 parts by mass and a surfactant: 0.1 to 10 parts by mass, respectively with respect to 100 parts by mass of the solid matter, were added to the chloroprene latex, to give a rubber composition.

First claim

The invention claimed is:

1. A polychloroprene latex comprising a chloroprene copolymer prepared by polymerizing raw monomers at least containing chloroprene and 2,3-dichloro-1,3-butadiene, dispersed in water, wherein
the 2,3-dichloro-1,3-butadiene content in the raw monomers is 1 to 30 mass %: and the potassium ion content in the polychloroprene latex is 0.9 to 1.1 parts by mass and the sodium ion content in the polychloroprene latex is 0.08 to 0.17 parts by mass with respect to 100 parts by mass of the solid matter.

2. The polychloroprene latex according to claim 1 , wherein the chloroprene copolymer has a gel content of 30 to 95 mass %.

3. The polychloroprene latex according to claim 1 , prepared by initiating emulsion polymerization, as the monomer amount initially added is adjusted to 10 to 50 mass % with respect to all monomers, and continuing the emulsion polymerization by adding the remaining monomers, which are cooled to a temperature lower than the polymerization temperature, to the polymerization system continuously during the polymerization period of from a monomer conversion rate of 1 to 40% to the final conversion rate.

4. A rubber composition, comprising the polychloroprene latex according to claim 1 , in an amount of 100 parts by mass as solid matter,
a metal oxide in an amount of 1 to 10 parts by mass,
sulfur in an amount of 0.1 to 3 parts by mass,
an aging inhibitor in an amount of 0.1 to 5 parts by mass, and
a surfactant in an amount of 0.1 to 10 parts by mass.

5. A dip-molded article, prepared by dip molding, using the polychloroprene latex according to claim 1 .

6. The dip-molded article according to claim 5 , which is disposable medical gloves.

7. A rubber composition, comprising the polychloroprene latex according to claim 2 , in an amount of 100 parts by mass as solid matter,
a metal oxide in an amount of 1 to 10 parts by mass,
sulfur in an amount of 0.1 to 3 parts by mass,
an aging inhibitor in an amount of 0.1 to 5 parts by mass, and
a surfactant in an amount of 0.1 to 10 parts by mass.

8. A rubber composition, comprising the polychloroprene latex according to claim 3 , in an amount of 100 parts by mass as solid matter,
a metal oxide in an amount of 1 to 10 parts by mass,
sulfur in an amount of 0.1 to 3 parts by mass,
an aging inhibitor in an amount of 0.1 to 5 parts by mass, and
a surfactant in an amount of 0.1 to 10 parts by mass.

9. A dip-molded article, prepared by dip molding, using the rubber composition according to claim 4 .

10. The dip-molded article according to claim 9 , which is disposable medical gloves.

11. A dip-molded article, prepared by dip molding, using the polychloroprene latex according to claim 2 .

12. A dip-molded article, prepared by dip molding, using the polychloroprene latex according to claim 3 .

Assignees

• Hashimoto Ikuka
• Yashima Hiroyuki
• Mori Takeo
• Denka Company Ltd

Inventors

• Hashimoto Ikuka
• Yashima Hiroyuki
• Mori Takeo

Classifications

• C08F236/18 Primary

  containing chlorine · CPC title

• C09D111/02 Primary

  Latex · CPC title

• A61B2017/00526

  Methods of manufacturing · CPC title

• C08L11/02

  Latex · CPC title

• C08J5/02

  Direct processing of dispersions, e.g. latex, to articles · CPC title