Vegetable oil derivatives as extender oils for elastomer compositions

Patent metadata

Field	Value
Publication number	US-9394426-B2
Application number	US-201514601326-A
Country	US
Kind code	B2
Filing date	Jan 21, 2015
Priority date	Dec 20, 2010
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

Elastomer composition comprising at least one elastomer and at least one vegetable oil derivative selected from one or more of: a. mixture of triglycerides comprising one or more of the following oligomeric structures: R 4 [OC(O)R 1 C(O)OCH 2 CH(OR 2 )CH 2 ] n OR 3 and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000, b. triglycerides of one or more long chain carboxylic acids including at least one carboxylic acid containing adjacent hydroxyl groups, c. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides.

First claim

The invention claimed is:

1. An elastomer composition comprising:
(i) at least one elastomer;
(ii) from 5 to 75 phr of an extender oil comprising at least one of vegetable oil derivative selected from one or more of:
a. mixture of triglycerides comprising one or more of the following oligomeric structures:
R 4 —[O—C(O)—R 1 —C(O)—O—CH 2 —CH(OR 2 )—CH 2 ] n —O—R 3

wherein
R 1 is selected from C 2 -C 22 alkylenes,
R 2 is selected from one or more of the following groups consisting of C 6 -C 24 dicarboxylic acid residues and C 6 -C 24 monocarboxylic acid residues,
R 3 is selected from one or more of the following groups consisting of H, C 6 -C 24 dicarboxylic acid residues and C 6 -C 24 monocarboxylic acid residues,
R 4 is an alkyl group,
n is an integer greater than or equal to 2,
said C 6 -C 24 dicarboxylic acid residues of R 2 and R 3 being esterified with monoalcohols and said mixture of triglycerides having a Numerical Average Molecular Weight (Mn) of between 800 and 10,000,

b. triglycerides of one or more long chain carboxylic acids including at least one carboxylic acid containing adjacent hydroxyl groups,
c. esters of polyols with at least a monocarboxylic acid and at least a dicarboxylic acid, the said esters being other than triglycerides;

(iii) at least one selected from the group consisting of:
from 10 to 150 phr of silica,
from 10 to 150 phr of carbon black,
from 0.1 to 10 phr of a vulcanizing agent.

2. The elastomer composition according to claim 1 comprising silica and coupling agents.

3. The elastomer composition according to claim 1 wherein said at least one elastomer is a natural rubber or a synthetic rubber.

4. The elastomer composition according to claim 3 , wherein said at least one elastomer is a synthetic rubber selected from the group consisting of diene-based rubbers, thermoplastic elastomers, nitrile rubbers, acrylonitrile-butadiene copolymers (NBR) and styrene-isoprene-styrene (SIS) polar rubbers.

5. The elastomer composition according to claim 4 , wherein said at least one elastomer is a diene-based rubber.

6. The elastomer composition according to claim 5 , wherein said diene-based rubber is a vinylarene-conjugated diene copolymer.

7. The elastomer composition according to claim 6 , wherein said vinylarene-conjugated diene copolymer is a styrene-1,3-butadiene random copolymer.

8. The elastomer composition according to claim 7 , wherein said styrene-1,3-butadiene random copolymer has a styrene content from 15 to 50% by weight.

9. The elastomer composition according to claim 7 , wherein said styrene-1,3-butadiene random copolymer has a vinyl unit content from 10 to 80% with respect to the diene content.

10. The elastomer composition according to claim 7 , wherein said styrene-1,3-butadiene random copolymer is obtained from solution or as emulsion.

11. The elastomer composition according to claim 1 , wherein the R 1 group of the vegetable oil derivatives of type (a) is C 6 -C 11 alkylene.

12. The elastomer composition according to claim 1 , wherein the C 6 -C 24 dicarboxylic acid residues of R 2 and R 3 are suberic acid, azelaic acid and brassylic acid and their mixtures.

13. The elastomer composition according to claim 1 , wherein the R 4 group of the vegetable oil derivatives of type (a) is a C 1 -C 12 alkyl group.

14. The elastomer composition according to claim 1 , wherein the vegetable oil derivatives of type (a) comprise dimer and/or trimer esters of triglycerides containing C 6 -C 24 dicarboxylic acids residues.

15. The elastomer composition according to claim 1 , wherein the vegetable oil derivative is of type (a).

16. The elastomer composition according to claim 1 , wherein the extender oil comprises a mixture of at least a vegetable oil derivative with mineral and/or natural oils.

17. The elastomer composition according to claim 16 , wherein said mixture contains 15-45% by weight of vegetable oil derivatives.

18. The elastomer composition according to claim 1 comprising one or more of the following ingredients: vulcanisation accelerators, activators, retardants, organic acids, antioxidants, fillers, process coadjuvants.

19. A rubber compound prepared from the elastomeric composition according to claim 1 .

20. A tyre comprising the rubber compound according to claim 19 .

Assignees

• Novamont Spa

Inventors

• Bastioli Catia
• Capuzzi Luigi
• Magistrali Paolo
• Gesti′ Garcia Sebastia
• Viola Gian Tommaso
• Savini Giuseppe
• Bacchelli Fabio

Classifications

• C08L9/06

  Copolymers with styrene · CPC title

• C08K3/04

  Carbon · CPC title

• C08K5/11 Primary

  of acyclic polycarboxylic acids · CPC title

• C08K3/36

  Silica · CPC title

• C08K5/092

  Polycarboxylic acids · CPC title