Acetylated polyol hydroxystearate plasticizers and plasticized polymeric compositions

Patent metadata

Field	Value
Publication number	US-9394425-B2
Application number	US-201314395390-A
Country	US
Kind code	B2
Filing date	May 7, 2013
Priority date	Jun 22, 2012
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

Plasticizers having an acetylated polyol hydroxystearate and plasticized polymeric compositions containing such plasticizers. Such plasticized polymeric compositions can be employed in forming various articles of manufacture, such as coated conductors.

First claim

The invention claimed is:

1. A polymeric composition comprising:
(a) a vinyl chloride resin; and
(b) a plasticizer comprising an acetylated polyol hydroxystearate,
wherein said acetylated polyol hydroxystearate comprises acetylated polyol monohydroxystearate in an amount of at least 70 weight percent, based on the entire weight of the acetylated polyol hydroxystearate,
wherein the polyol of said acetylated polyol hydroxystearate is not glycerol.

2. The composition of claim 1 , wherein said vinyl chloride resin has a solution temperature of less than 180° C. in said plasticizer, as determined by Deutsches Institut für Normung (“DIN”) standard method 53 408.

3. The composition of claim 1 , wherein the polyol of said acetylated polyol hydroxystearate is selected from the group consisting of alkylene glycols, triethylene glycol, trimethylolethane, trimethylolpropane, pentaerythritol, mannitol, sorbitol, and mixtures of two or more thereof.

4. The composition of claim 3 , wherein said polyol is an alkylene glycol, wherein said alkylene glycol is selected from the group consisting of ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2-ethyl-1,3-hexanediol, 2-methyl-2-propyl-1,3-propanediol, and mixtures of two or more thereof.

5. The composition of claim 4 , wherein said alkylene glycol is propylene glycol.

6. The composition of claim 1 , wherein said polymeric composition has a Shore D hardness of less than 34 when said plasticizer is present in an amount of 50 parts per hundred resin based on 100 parts by weight of the vinyl chloride resin, wherein said polymeric composition has a tensile elongation retention of at least 30% when aged at 113° C. for 168 hours, as determined by ASTM D638.

7. The composition of claim 1 , wherein said plasticizer further comprises an additional plasticizer component selected from the group consisting of an epoxidized natural oil, an epoxidized fatty acid alkyl ester, or mixtures thereof.

8. The composition of claim 7 , wherein said additional plasticizer component is an epoxidized soybean oil.

9. A coated conductor comprising a conductive core and a polymeric layer surrounding at least a portion of said conductive core, wherein said polymeric composition of claim 1 constitutes said polymeric layer.

10. The coated conductor of claim 9 , wherein said coated conductor is a 60° C., 75° C., 80° C., 90° C., or 105° C. rated cable according to Underwriters Laboratories (“UL”) standards 83 and 1581 under dry conditions.

Assignees

• Chaudhary Bharat I
• Sczekalla Beate
• Dow Global Technologies Llc

Inventors

• Chaudhary Bharat I
• Sczekalla Beate

Classifications

• C08K5/1515

  Three-membered rings · CPC title

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title

• C08L27/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• C08K5/103 Primary

  with polyalcohols · CPC title

• H01B3/443

  from vinylhalogenides or other halogenoethylenic compounds · CPC title