Method for making carbon nanotube film

Patent metadata

Field	Value
Publication number	US-9394176-B2
Application number	US-201414521242-A
Country	US
Kind code	B2
Filing date	Oct 22, 2014
Priority date	Jun 13, 2014
Publication date	Jul 19, 2016
Grant date	Jul 19, 2016

Abstract

A method for forming a carbon nanotube film is disclosed. More than one carbon nanotube array is transferred onto a surface of more than one substitute substrate. The substitute substrates are arranged side by side to contact and combined side surfaces of the plurality of carbon nanotube arrays with each other by van der Waals attractive force to form an assembling array. The assembling array is larger than the carbon nanotube array. Carbon nanotube segments are drawn from the assembling array.

First claim

What is claimed is:

1. A method for making a carbon nanotube film, the method comprising:
providing a plurality of carbon nanotube arrays transferred onto a plurality of substitute substrates, the plurality of carbon nanotube arrays having an ability to have the carbon nanotube film drawn therefrom, and the carbon nanotube film comprising a plurality of carbon nanotubes joined end to end;
placing the plurality of substitute substrates side by side to contact and combine side surfaces of the plurality of carbon nanotube arrays with each other by van der Waals attractive force to form an assembling array, the assembling array is larger than each of the plurality of carbon nanotube arrays;
drawing a plurality of carbon nanotube segments joined end to end by van der Waals attractive force from the assembling array.

2. The method of claim 1 , wherein the plurality of substitute substrates comprises a first substitute substrate, the plurality of carbon nanotube arrays comprises a first carbon nanotube array, the providing the plurality of carbon nanotube arrays transferred onto the plurality of substitute substrates comprises:
providing a growing substrate having the first carbon nanotube array grown thereon, the first carbon nanotube array having a bottom surface on the growing substrate and a top surface away from the growing substrate, and the first carbon nanotube array having the ability to have the carbon nanotube film drawn therefrom;
contacting a surface of the first substitute substrate to the top surface of the first carbon nanotube array; and
separating the first substitute substrate from the growing substrate, thereby separating the bottom surface of the first carbon nanotube array from the growing substrate to transfer the first carbon nanotube array from the growing substrate to the first substitute substrate, the first carbon nanotube array still having the ability to have the carbon nanotube film drawn therefrom.

3. The method of claim 2 , wherein the surface of the first substitute substrate and the top surface of the first carbon nanotube array are combined only by van der Waals attractive forces.

4. The method of claim 2 , wherein the surface of the first substitute substrate has a plurality of microstructures located thereon.

5. The method of claim 2 , wherein the first substitute substrate is spaced from the growing substrate by a spacing element, and the spacing element has a height between the first substitute substrate and the growing substrate less than or equal to the height of the first carbon nanotube array.

6. The method of claim 1 , wherein the plurality of substitute substrates comprises a first substitute substrate, the plurality of carbon nanotube arrays comprises a first carbon nanotube array, the providing the plurality of carbon nanotube arrays transferred onto the plurality of substitute substrate comprises:
providing a growing substrate having the first carbon nanotube array grown thereon, the first carbon nanotube array having a bottom surface on the growing substrate and a top surface away from the growing substrate, and the first carbon nanotube array having the ability to have a carbon nanotube film drawn therefrom;
placing the first substitute substrate on the top surface of the first carbon nanotube array and sandwiching liquid medium between the first substitute substrate and the first carbon nanotube array;
solidifying the liquid medium between the first substitute substrate and the first carbon nanotube array into solid medium;
separating the first substitute substrate from the growing substrate, thereby separating the bottom surface of the first carbon nanotube array from the growing substrate; and
removing the solid medium between the first substitute substrate and the first carbon nanotube array, wherein the first carbon nanotube array still having the ability to have the carbon nanotube film drawn therefrom.

7. The method of claim 6 , wherein the sandwiching the liquid medium between the first substitute substrate and the first carbon nanotube array comprises:
forming the liquid medium on the top surface of the first carbon nanotube array; and
contacting a surface of the first substitute substrate and the liquid medium on the top surface with each other.

8. The method of claim 7 , wherein the solidifying the liquid medium between the first substitute substrate and the first carbon nanotube array comprises contacting the first substitute substrate having a temperature below a freezing point with the liquid medium on the top surface of the first carbon nanotube array.

9. The method of claim 6 , wherein the sandwiching the liquid medium between the first substitute substrate and the first carbon nanotube array comprises:
forming the liquid medium on a surface of the first substitute substrate; and
contacting the top surface of the first carbon nanotube array and the liquid medium on the surface of the first substitute substrate with each other.

10. The method of claim 6 , wherein the solidifying the liquid medium between the first substitute substrate and the first carbon nanotube array comprises placing a laminate of the growing substrate, the first carbon nanotube array, the liquid medium, and the first substitute substrate into an environment having a temperature below a freezing point of the liquid medium.

11. The method of claim 6 , wherein the liquid medium comprises water.

12. The method of claim 1 , wherein the plurality of substitute substrates have side walls being alignment with the side surfaces of the plurality of carbon nanotube arrays transferred thereon.

13. The method of claim 1 , wherein the assembling array has a size larger than one of the plurality of carbon nanotube arrays along a first direction, and the plurality of carbon nanotube segments are drawn along a second direction substantially perpendicular to the first direction.

14. The method of claim 1 , wherein the plurality of substitute substrates are elastic.

15. A method for making a carbon nanotube film, the method comprising:
providing a plurality carbon nanotube arrays transferred onto a plurality of second substrates from a plurality of first substrates, the plurality of carbon nanotube arrays having an ability to have the carbon nanotube film drawn therefrom, and the carbon nanotube film comprising a plurality of carbon nanotubes joined end to end;
placing the plurality of second substrates side by side to contact and combined side surfaces of the plurality of carbon nanotube arrays with each other by van der Waals attractive force to form an assembling array, the assembling array is larger than each of the plurality of carbon nanotube arrays;
drawing a plurality of carbon nanotube segments joined end to end by van der Waals attractive force from the assembling array.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wei Yang
• Fan Shou-Shan

Classifications

• C01B31/0253 Primary

  Chemistry & Metallurgy · mapped topic

• C01B31/022

  Chemistry & Metallurgy · mapped topic

• B29C65/002 Primary

  Joining methods not otherwise provided for · CPC title

• C01B32/168 Primary

  After-treatment · CPC title