Molybdenum oxide and cobalt oxyhydroxide composite electrochemical glucose sensor
US-2024175842-A1 · May 30, 2024 · US
US9393618B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9393618-B2 |
| Application number | US-201414322977-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 3, 2014 |
| Priority date | Jul 3, 2013 |
| Publication date | Jul 19, 2016 |
| Grant date | Jul 19, 2016 |
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The present disclosure relates to a method of making a sintered cutting body having a side with binder metal capping and another side without binder metal capping. The disclosure also relates to a sintered cutting body produced according to the method.
Opening claim text (preview).
The invention claimed is: 1. A method of producing a sintered cutting body comprising the steps of: providing a body of cermet or cemented carbide comprising carbon and binder metal; providing a sintering device for sintering the body; sintering the body in a sintering process by means of the sintering device; providing the sintering process with a time range, the time range being a heating time range where temperature at a certain moment in time is either constant or rising; providing a subsequent cooling time range of the sintering process where a cooling temperature in the cooling time range is arranged at a certain moment in time to be constant or decreasing; and providing an atmosphere comprising at least one inert gas at a pressure, at least during a first part time range of the cooling time range in order to provide decarburizing conditions, wherein a pressure in the sintering device during the first part time range fulfills the condition 100 Pa≦P≦15000 Pa, wherein at least during a second part time range, subsequent to the first part time range, a partial pressure of the binder metal is maintained higher for a side or part of a side of the body and wherein the other part of the side or other sides of the body has/have a lower partial pressure of the binder metal, such that the binder metal is evaporated, thus providing a side or part of a side with binder metal capping, and other part of a side or other sides with essentially no binder metal capping. 2. The method according to claim 1 , wherein the higher partial pressure for the binder metal is achieved by contacting the side or the part of the side of the body, with a tray, thus achieving a sintered body provided with a side or part of a side comprising a surface layer of the binder metal, wherein the other sides or part of the side of the body that have not been in contact with a tray are subjected to the low partial pressure of the binder metal and thus are essentially free of binder metal capping. 3. The method in accordance with claim 2 , wherein the tray is provided with ridges such that when a body rests on the tray, two sides of the body are in contact with the surface of the tray. 4. The method according to claim 1 , wherein at least two sides of the body are provided with binder metal capping while the other sides are essentially not. 5. The method in accordance with claim 1 , wherein the partial pressures of binder metal during the second part time range is achieved by decreasing the pressure in the sintering device to a value below the pressure during the first part time range. 6. The method in accordance with claim 1 , wherein during the second part time range the pressure fulfills the condition 0.01 Pa≦P≦70 Pa. 7. The method in accordance with claim 1 , wherein the second part time range is started when the temperature has decreased below a solidification temperature of the binder metal. 8. The method in accordance with claim 7 , wherein the second part time range is started when the temperature has decreased about 10 degrees below the solidification temperature of the binder metal. 9. The method in accordance with claim 1 , wherein the binder metal comprises cobalt. 10. The method in accordance with claim 1 , wherein the inert gas is argon during the first part time range. 11. The method in accordance with claim 1 , wherein the atmosphere comprises argon and one or both of carbon monoxide and nitrogen during the first part time range. 12. The method according to claim 1 , wherein the sintering temperature is in the range 1400° C.≦TS≦1500° C. 13. The method according to claim 1 , wherein the thickness of the binder metal capping layer is 1-20 μm. 14. The method according to claim 1 , wherein the sintering temperature is in the range 1430°≦TS≦1480° C. 15. A sintered cutting body produced according to the method of claim 1 .
Sintering only · CPC title
Changing atmosphere · CPC title
Hard, i.e. after being hardened · CPC title
Cermet · CPC title
Controlled cooling · CPC title
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