Positive electrode active material, production method thereof and non-aqueous electrolyte secondary battery

Patent metadata

Field	Value
Publication number	US-9391325-B2
Application number	US-43191906-A
Country	US
Kind code	B2
Filing date	May 11, 2006
Priority date	Mar 1, 2002
Publication date	Jul 12, 2016
Grant date	Jul 12, 2016

Abstract

In order to provide a 3V level non-aqueous electrolyte secondary battery with a flat voltage and excellent cycle life at a high rate with low cost, the present invention provides a positive electrode represented by the formula: Li 2±α [Me] 4 O 8−x , wherein 0≦α<0.4, 0≦x<2, and Me is a transition metal containing Mn and at least one selected from the group consisting of Ni, Cr, Fe, Co and Cu, said active material exhibiting topotactic two-phase reactions during charge and discharge.

First claim

The invention claimed is:

1. An assembled battery comprising a plurality of non-aqueous electrolyte secondary batteries, each of said non-aqueous secondary batteries comprising a positive electrode containing a positive electrode active material; a negative electrode containing a titanium oxide; a non-aqueous electrolyte and a separator, wherein:
said positive electrode active material is represented by a composition formula: Li 2±α [Me] 4 O 8-x , where 0≦α<0.4, 0 ≦x<2, and Me is a transition metal containing Mn and at least one selected from the group consisting of Ni, Cr, Fe, Co and Cu, said active material exhibiting topotactic two-phase reactions during charge and discharge,
said titanium oxide has a spinel structure,
said positive and negative electrodes have a current collector made of aluminum or an aluminum alloy, said non-aqueous electrolyte is a non-aqueous electrolyte solution containing acetonitrile as a solvent, and
the capacity of each of said non-aqueous electrolyte secondary batteries is regulated by a capacity of said negative electrode of each of said non-aqueous electrolyte secondary batteries.

2. The assembled battery in accordance with claim 1 , wherein said titanium oxide is Li 4 Ti 5 O 12 .

3. The assembled battery in accordance with claim 1 , wherein each of said non-aqueous electrolyte secondary batteries has an operating discharge curve with a potential difference of 0.2 to 0.8 V.

4. The assembled battery in accordance with claim 1 , wherein said non-aqueous electrolyte comprises at least one selected from the group consisting of propylene carbonate, γ-butyrolactone, γ-valerolactone, methyl diglyme, sulfolane, trimethyl phosphate triethyl phosphate and methoxymethylethyl carbonate.

5. The assembled battery in accordance with claim 1 , wherein said separator is made of non-woven fabric.

6. The assembled battery in accordance with claim 5 , wherein said non-woven fabric comprises at least one selected from the group consisting of polyethylene, polypropylene and polybutylene terephthalate.

7. The assembled battery in accordance with claim 1 , wherein the weight ratio of said negative electrode active material to said positive electrode active material is not less than 0.5 and not greater than 1.2.

8. The assembled battery in accordance with claim 1 , wherein each of said non-aqueous electrolyte secondary batteries has a usable charging/discharging region of 2.5 to 3.5 V and a practical average voltage of 3V level.

9. The assembled battery in accordance with claim 1 , wherein, in said positive electrode active material, the phase of the transition metal has a 2×2 superlattice.

10. The assembled battery in accordance with claim 1 , wherein, in said positive electrode active material, the ratio between Mn and other transition metal is substantially 3:1.

11. The assembled battery in accordance with claim 1 , wherein said positive electrode active material has a spinel-framework-structure and the Li and/or Me exist in the 16(c) site in the space group Fd3m.

12. The assembled battery in accordance with claim 1 , wherein said positive electrode active material has a lattice constant attributed to a cubic crystal of not greater than 8.3 Å.

13. The assembled battery in accordance with claim 1 , wherein said positive electrode active material comprises a mixture of crystal particles with a particle size of 0.1 to 8 μm and secondary particles of said crystal particles with a particle size of 2 to 30 μm.

14. The assembled battery in accordance with claim 1 , wherein said non-aqueous electrolyte secondary batteries are connected in series, in parallel, or in series-parallel.

Assignees

• Ohzuku Tsutomu
• Yoshizawa Hiroshi
• Nagayama Masatoshi
• Koshina Hizuru
• Panasonic Corp
• Univ Osaka City

Inventors

• Ohzuku Tsutomu
• Yoshizawa Hiroshi
• Nagayama Masatoshi
• Koshina Hizuru

Classifications

• H01M50/417

  Polyolefins · CPC title

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• C01P2002/82

  by IR- or Raman-data · CPC title

• H01M4/505 Primary

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• C01P2004/03

  obtained by SEM · CPC title