Systems, compositions, and methods for enhanced electromagnetic shielding and corrosion resistance
US-11965116-B2 · Apr 23, 2024 · US
US9390831B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9390831-B2 |
| Application number | US-201213680893-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 19, 2012 |
| Priority date | Nov 23, 2011 |
| Publication date | Jul 12, 2016 |
| Grant date | Jul 12, 2016 |
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An electronic device includes a connection material formed from an adhesive composition that includes: a polymer resin; a cationic polymerization catalyst represented by Formula 1; and an organic base, where, in Formula 1, R 1 may be selected from the group of hydrogen, C 1 -C 6 alkyl, C 6 -C 14 aryl, —C(═O)R 4 , —C(═O)OR 5 , and —C(═O)NHR 6 (in which R 4 , R 5 , and R 6 may each independently be selected from C 1 -C 6 alkyl and C 6 -C 14 aryl), R 2 may be C 1 -C 6 alkyl, and R 3 may be selected from the group of a nitrobenzyl group, a dinitrobenzyl group, a trinitrobenzyl group, a benzyl group, a C 1 -C 6 alkyl-substituted benzyl group, and a naphthylmethyl group.
Opening claim text (preview).
What is claimed is: 1. An electronic device comprising an anisotropic conductive connection material formed from an anisotropic conductive adhesive composition that includes: a polymer resin; a cationic polymerization catalyst represented by Formula 1; conductive particles, and an organic base, wherein the organic base includes at least one selected from the group of triethylamine, triisobutylamine, trioctylamine, triisodecylamine, triethanolamine, and an ammonium salt wherein: R 1 is selected from the group of hydrogen, C 1 -C 6 alkyl, C 6 -C 14 aryl, —C(═O)R 4 , —C(═O)OR 5 , and —C(═O)NHR 6 (in which R 4 , R 5 , and R 6 are each independently selected from C 1 -C 6 alkyl and C 6 -C 14 aryl), R 2 is C 1 -C 6 alkyl, and R 3 is selected from the group of a nitrobenzyl group, a dinitrobenzyl group, a trinitrobenzyl group, a benzyl group, a C 1 -C 6 alkyl-substituted benzyl group, and a naphthylmethyl group. 2. The electronic device as claimed in claim 1 , wherein: R 1 is selected from the group of hydrogen, C 1 -C 4 alkyl, —C(═O)R 4 , and —C(═O)OR 5 (in which R 4 and R 5 are each independently C 1 -C 4 alkyl), R 2 is C 1 -C 4 alkyl, and R 3 is selected from the group of a nitrobenzyl group, a dinitrobenzyl group, a trinitrobenzyl group, and a naphthylmethyl group. 3. The electronic device as claimed in claim 1 , wherein R 1 is methyl, R 2 is methyl, and R 3 is a naphthylmethyl group. 4. The electronic device as claimed in claim 1 , wherein the polymer resin includes at least one of an epoxy resin or a phenoxy resin. 5. The electronic device as claimed in claim 1 , wherein: the cationic polymerization catalyst represented by Formula 1 is present in an amount of about 0.1 to about 20 parts by weight, based on 100 parts by weight of the polymer resin, and the organic base is present in an amount of about 0.1 to about 30 parts by weight, based on 100 parts by weight of the cationic polymerization catalyst represented by Formula 1. 6. A electronic device comprising an anisotropic adhesive film as and anisotropic conductive connection material, the anisotropic conductive adhesive film being formed from a mixture that includes a polymer resin, a cationic polymerization catalyst represented by Formula 1, conductive particles, and an organic base, the anisotropic conductive adhesive film exhibiting a decrease in adhesive strength of about 30% or less after being left at 25° C. for 300 hours, wherein: R 1 is selected from the group of hydrogen, C 1 -C 6 alkyl, C 6 -C 14 aryl, —C(═O)R 4 , —C(═O)OR 5 , and —C(═O)NHR 6 (in which R 4 and R 6 are each independently selected from C 1 -C 6 alkyl and C 6 -C 14 aryl), R 2 is C 1 -C 6 alkyl, and R 3 is selected from the group of a nitrobenzyl group, a dinitrobenzyl group, a trinitrobenzyl group, a benzyl group, a C 1 -C 6 alkyl-substituted benzyl group, and a naphthylmethyl group. 7. The electronic device as claimed in claim 6 , wherein: R 1 is selected from the group of hydrogen, C 1 -C 4 alkyl, —C(═O)R 4 , and —C(═O)OR 5 (in which R 4 and R 5 are each independently C 1 -C 4 alkyl), R 2 is C 1 -C 4 alkyl, and R 3 is selected from the group of a nitrobenzyl group, a dinitrobenzyl group, a trinitrobenzyl group, and a naphthylmethyl group. 8. The electronic device as claimed in claim 6 , wherein R 1 is methyl, R 2 is methyl, and R 3 is a naphthylmethyl group. 9. The electronic device as claimed in claim 6 , wherein the polymer resin includes at least one of an epoxy resin or a phenoxy resin. 10. The electronic device as claimed in claim 6 , wherein the organic base includes at least one selected from the group of triethylamine, triisobutylamine, trioctylamine, triisodecylamine, triethanolamine, and an ammonium salt.
Electrically-conducting adhesives · CPC title
Ionic conductors · CPC title
the conductive material comprising metals or alloys · CPC title
organic substances {(organic macromolecular compounds or compositions C08)} · CPC title
by applying an anisotropic conductive adhesive layer over an array of pads · CPC title
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