Process for producing molecular sieve materials

Patent metadata

Field	Value
Publication number	US-9387465-B2
Application number	US-201214009570-A
Country	US
Kind code	B2
Filing date	Mar 12, 2012
Priority date	Apr 15, 2011
Publication date	Jul 12, 2016
Grant date	Jul 12, 2016

Abstract

In a process for producing a molecular sieve material, water, at least one source of an oxide of a tetravalent and/or a trivalent element and at least one structure directing agent are mixed in a plough shear mixer/dryer/reactor equipped with a mixer having a Froude number of at least 1, to produce a molecular sieve synthesis mixture having a solids content of at least about 20 wt %. The molecular sieve synthesis mixture is heated in said reactor while agitating said mixture with said mixer to form crystals of said molecular sieve material and said molecular sieve crystals are subsequently recovered from said reactor.

First claim

We claim:

1. A process for producing a molecular sieve material, said process comprising the steps of:
(a) mixing water, at least one source of an oxide of a tetravalent element, and optionally a trivalent element, and at least one structure directing agent in a plough shear mixer/dryer/reactor equipped with a mixer having a Froude number of at least 1, to produce a molecular sieve synthesis mixture having a solids content of at least 20 wt %,
(b) heating said molecular sieve synthesis mixture in said reactor while agitating said mixture with said plough shear mixer/dryer/reactor to form crystals of said molecular sieve material; and then
(c) recovering said molecular sieve crystals from the reactor.

2. The process of claim 1 and further comprising the step of:
(d) prior to step (c), removing water from said molecular sieve synthesis mixture in said plough shear mixer/dryer/reactor while agitating said molecular sieve synthesis mixture with said plough shear mixer/dryer/reactor so as to decrease the water content of said molecular sieve synthesis mixture inside said plough shear mixer/dryer/reactor by at least 5 wt % and produce a partially dried mixture.

3. The process of claim 2 , wherein said removing step (d) is conducted after formation of said crystals of said molecular sieve material.

4. The process of claim 3 and further comprising the step of:
(e) mixing said partially dried mixture comprising said crystals of said molecular sieve material with an additional particulate material to produce a product mixture.

5. The process of claim 4 , wherein said additional particulate material is a catalyst formulation component.

6. The process of claim 5 , wherein said catalyst formulation component is a binder or matrix material.

7. The process of claim 4 , wherein said mixing step (e) is conducted in said plough shear mixer/dryer/reactor.

8. The process of claim 4 , wherein said mixing step (e) is conducted in a mixer separate from said plough shear mixer/dryer/reactor.

9. The process of claim 4 and further comprising the step of:
(f) extruding said recovered product mixture into a shaped body.

10. The process of claim 2 , wherein said removing step (d) is conducted by applying heat to said molecular sieve synthesis mixture.

11. The process of claim 2 , wherein said removing step (d) is conducted by reducing the pressure in said plough shear mixer/dryer/reactor.

12. The process of claim 1 and further comprising the step of:
(d) calcining said molecular sieve crystals without subjecting said recovered molecular sieve crystals to an initial filtration and/or washing step.

13. The process of claim 1 , wherein said plough shear mixer/dryer/reactor has a capacity of at least 5 liters.

14. The process of claim 1 , wherein said plough shear mixer/dryer/reactor comprises at least one blade located on a shaft rotatable about an axis oriented at no more than 10 degrees from horizontal.

15. The process of claim 1 , wherein said molecular sieve material comprises ZSM-5 or MCM-41.

Assignees

• Lai Wenyih Frank
• Kay Robert Ellis
• Mccarthy Stephen J
• Exxonmobil Chem Patents Inc

Inventors

• Lai Wenyih Frank
• Kay Robert Ellis
• Mccarthy Stephen J

Classifications

• C01B39/48

  using at least one organic template directing agent · CPC title

• C01B39/026

  After-treatment · CPC title

• B01J29/00

  Catalysts comprising molecular sieves {(molecular sieves per se C01B)} · CPC title

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• B01J29/0308

  Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 · CPC title