Inkjet composition for forming transparent film and preparation method thereof

Patent metadata

Field	Value
Publication number	US-9383489-B2
Application number	US-201013502325-A
Country	US
Kind code	B2
Filing date	Oct 22, 2010
Priority date	Oct 26, 2009
Publication date	Jul 5, 2016
Grant date	Jul 5, 2016

Abstract

The present invention relates to an inkjet composition for forming transparent films, which is highly economical and environmentally friendly and has excellent physical properties, including excellent transmittance, chemical resistance, heat resistance, adhesion, jetting stability and storage stability.

First claim

The invention claimed is:

1. An inkjet composition for forming transparent films, comprising:
based on the total weight of the composition,
(a) 1-23.1 wt % of an epoxy group-containing binder polymer;
(b) 1-23.1 wt % of a compound of the following formula 1; and
(c) 75.9-90 wt % of a solvent,
wherein the inkjet composition is used for an inkjet process,
wherein the inkjet composition has a viscosity of 11-13 cP,
wherein the inkjet composition contains neither a pigment nor a coloring agent,
wherein the epoxy group-containing binder polymer (a) is a copolymer of a monomer having an epoxy group with at least one selected from the group consisting of an acrylic monomer having an epoxy group, an acrylic monomer having an ethylenic double bond at the side chain, a (meth)acrylic ester monomer, a styrene monomer, and a silane monomer having an ethylenic unsaturated bond,
wherein the weight ratio of the epoxy group-containing binder polymer (a) to the compound of formula 1 (b) is 1:0.5 to 1:1, and
wherein the solid content of the binder polymer (a) and the compound of formula 1 (b) is 95-99 wt % based on the total solid content of the inkjet composition:

wherein at least two of R 1 , R 2 and R 3 are amine groups, the remainder of R 1 , R 2 and R 3 is hydrogen,
wherein the amine groups are each independently substituted with substituents selected from the group consisting of a C 1 -C 30 linear or branched alkyl, a C 1 -C 30 linear or branched alkoxy, a C 3 -C 30 linear or branched allyl, a C 2 -C 30 linear or branched alkenyl, a C 2 -C 30 linear or branched vinyl, a carboxyl group (COO—), an ether group (—CH 2 OR), an alcohol group (—CH 2 OH), a substituted or unsubstituted C 3 -C 20 cycloalkyl, a substituted or unsubstituted C 6 -C 40 aryl, a substituted or unsubstituted C 7 -C 15 aralkyl, and a C 7 -C 15 alkylaryl substituted or unsubstituted with hydrocarbon,
and when the substituents of the amine groups are substituted with different substituents, the different substituents are selected from the group consisting of a C 1 -C 30 alkyl group, a C 6 -C 40 aryl group, a C 3 -C 40 heterocyclic group, and a halogen group.

2. The inkjet composition of claim 1 , wherein the compound of formula 1 is a compound of the following formula 2:

wherein R 4 to R 9 are each independently selected from the group consisting of a C 1 -C 30 linear or branched alkyl, a C 1 -C 30 linear or branched alkoxy, a C 3 -C 30 linear or branched allyl, a C 2 -C 30 linear or branched alkenyl, a C 2 -C 30 linear or branched vinyl, a carboxyl group (COO—), an ether group (—CH 2 OR), an alcohol group (CH 2 OH), a substituted or unsubstituted C 3 -C 20 cycloalkyl, a substituted or unsubstituted C 6 -C 40 aryl, a substituted or unsubstituted C 7 -C 15 aralkyl, and a C 7 -C 15 alkylaryl substituted or unsubstituted with hydrocarbon,
and when R 4 to R 9 are substituted with different substituents, the substituents are selected from the group consisting of a C 1 -C 30 alkyl group, a C 6 -C 40 aryl group, a C 3 -C 40 heterocyclic group, and a halogen group.

3. The inkjet composition of claim 1 , wherein the inkjet composition has a three-dimensional network structure.

4. The inkjet composition of claim 1 , wherein the content of the monomer, having the epoxy group, in the copolymer, is 5-50 wt % based on the total weight of the copolymer.

5. The inkjet composition of claim 1 , wherein the epoxy group-containing binder polymer (a) has a weight-average molecular weight of 1,000-100,000.

6. The inkjet composition of claim 1 , wherein the solvent (c) has a boiling point of 150˜250° C.

7. A transparent film formed using the inkjet composition of claim 1 .

8. The transparent film of claim 7 , wherein the transparent film has a light transmittance of 98% or higher at 380-780 nm after curing.

9. An electronic device comprising the transparent film of claim 7 as an overcoat.

10. A color filter comprising the transparent film of claim 7 as a white pattern.

11. A method for manufacturing a transparent film, the method comprising forming the transparent film with the inkjet composition of claim 1 using an inkjet process.

12. A method for preparing an inkjet composition for forming transparent films, the method comprising mixing (a) 1-23.1 wt % of a binder polymer containing an epoxy group, (b) 1-23.1 wt % of a compound of the following formula 1 and (c) 75.9-90 wt % of a solvent, based on the total weight of the composition,
wherein the inkjet composition has a viscosity of 11-13 cP,
wherein the inkjet composition contains neither a pigment nor a coloring agent,
wherein the epoxy group-containing binder polymer (a) is a copolymer of a monomer having an epoxy group with at least one selected from the group consisting of an acrylic monomer having an epoxy group, an acrylic monomer having an ethylenic double bond at the side chain, a (meth)acrylic ester monomer, a styrene monomer, and a silane monomer having an ethylenic unsaturated bond,
wherein the weight ratio of the epoxy group-containing binder polymer (a) to the compound of formula 1 (b) is 1:0.5 to 1:1, and
wherein the solid content of the binder polymer (a) and the compound of formula 1 (b) is 95-99 wt % based on the total solid content of the inkjet composition:

wherein at least two of R 1 , R 2 and R 3 are amine groups, the remainder of R 1 , R 2 and R 3 is hydrogen,
wherein the amine groups are each independently substituted with substituents selected from the group consisting of a C 1 -C 30 linear or branched alkyl, a C 1 -C 30 linear or branched alkoxy, a C 3 -C 30 linear or branched allyl, a C 2 -C 30 linear or branched alkenyl, a C 2 -C 30 linear or branched vinyl, a carboxyl group (COO—), an ether group (—CH 2 OR), an alcohol group (—CH 2 OH), a substituted or unsubstituted C 3 -C 20 cycloalkyl, a substituted or unsubstituted C 6 -C 40 aryl, a substituted or unsubstituted C 7 -C 15 aralkyl, and a C 7 -C 15 alkylaryl substituted or unsubstituted with hydrocarbon, and
wherein when the substituents of the amine groups are substituted with different substituents, the different substituents are selected from the group consisting of a C 1 -C 30 alkyl group, a C 6 -C 40 aryl group, a C 3 -C 40 heterocyclic group, and a halogen group.

Assignees

• Kim Mun-Ho
• Lee Seung-Hee
• Kim Han-Soo
• Kim Mi-Kyoung
• Lg Chemical Ltd

Inventors

• Kim Mun-Ho
• Lee Seung-Hee
• Kim Han-Soo
• Kim Mi-Kyoung

Classifications

• C09D133/068

  containing glycidyl groups · CPC title

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title

• C09D11/30

  Inkjet printing inks · CPC title

• C09D163/00

  Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins · CPC title

• C08G59/3209

  obtained by polymerisation of unsaturated mono-epoxy compounds · CPC title