Ultrasonic Probes With Gas Outlets for Degassing of Molten Metals
US-2015135901-A1 · May 21, 2015 · US
US9382598B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9382598-B2 |
| Application number | US-201414156520-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 16, 2014 |
| Priority date | Apr 9, 2010 |
| Publication date | Jul 5, 2016 |
| Grant date | Jul 5, 2016 |
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Methods for degassing and for removing impurities from molten metals are disclosed. These methods can include operating an ultrasonic device in a molten metal bath, and adding a purging gas into the molten metal bath through the tip of the ultrasonic device.
Opening claim text (preview).
What is claimed is: 1. An ultrasonic device comprising: an ultrasonic transducer; an elongated probe attached to the ultrasonic transducer, the probe comprising a tip; and a gas delivery system, the gas delivery system comprising: a gas inlet, a gas flow path through the probe, and a gas outlet at the tip of the probe; wherein: the probe comprises a ceramic; and a length to diameter ratio of the probe is in a range from about 5:1 to about 25:1. 2. The ultrasonic device of claim 1 , wherein the probe is a unitary part. 3. The ultrasonic device of claim 2 , wherein the probe comprises a Sialon, a Silicon carbide, a Boron carbide, a Boron nitride, a Silicon nitride, an Aluminum nitride, an Aluminum oxide, a Zirconia, or a combination thereof. 4. The ultrasonic device of claim 2 , wherein the probe comprises a Sialon. 5. The ultrasonic device of claim 1 , wherein the probe is secured to the ultrasonic transducer with an attachment nut. 6. The ultrasonic device of claim 1 , wherein the probe has a radius of curvature of at least about ½-inch on an attachment side of the probe. 7. The ultrasonic device of claim 1 , wherein: the probe comprises a Sialon; the probe is generally cylindrical; and the ultrasonic device further comprises a booster between the ultrasonic transducer and the probe. 8. The ultrasonic device of claim 7 , wherein the length to diameter ratio is in a range from about 7:1 to about 22:1. 9. The ultrasonic device of claim 7 , wherein a ratio of the cross-sectional area of the tip of the probe to the cross-sectional area of the gas outlet is in a range from about 60:1 to about 750:1. 10. A method for reducing an amount of a dissolved gas and/or an impurity in a molten metal bath, the method comprising: (a) operating the ultrasonic device of claim 1 in the molten metal bath; and (b) introducing a purging gas through the gas delivery system and into the molten metal bath at a rate in a range from about 0.1 to about 150 L/min. 11. The method of claim 10 , wherein: the dissolved gas comprises oxygen, hydrogen, sulfur dioxide, or a combination thereof; the impurity comprises an alkali metal; the molten metal bath comprises aluminum, copper, zinc, steel, magnesium, or a combination thereof; the purging gas comprises nitrogen, helium, neon, argon, krypton, xenon, chlorine, or a combination thereof; or any combination thereof. 12. The method of claim 10 , wherein the purging gas is introduced into the molten metal bath at a rate in a range from about 10 to about 500 mL/hr of purging gas per kg/hr of output from the molten metal bath. 13. The method of claim 10 , wherein: the dissolved gas comprises hydrogen; the molten metal bath comprises aluminum, copper, or a combination thereof; and the purging gas comprises argon, nitrogen, or a combination thereof. 14. An ultrasonic device comprising: an ultrasonic transducer; an elongated probe comprising a tip; a booster between the ultrasonic transducer and the elongated probe; and a gas delivery system, the gas delivery system comprising: a gas inlet in the booster, a gas flow path through the probe, and a gas outlet at the tip of the probe; wherein: the probe comprises a ceramic; and a length to diameter ratio of the probe is in a range from about 5:1 to about 25:1. 15. The ultrasonic device of claim 14 , wherein the probe comprises a Sialon, a Silicon carbide, a Boron carbide, a Boron nitride, a Silicon nitride, an Aluminum nitride, an Aluminum oxide, a Zirconia, or a combination thereof. 16. The ultrasonic device of claim 14 , wherein the probe is a unitary, generally cylindrical probe comprising a Sialon. 17. The ultrasonic device of claim 16 , wherein the probe is secured to the ultrasonic transducer with an attachment nut. 18. The ultrasonic device of claim 16 , wherein: a ratio of the cross-sectional area of the tip of the probe to the cross-sectional area of the gas outlet is in a range from about 60:1 to about 750:1; and the length to diameter ratio is in a range from about 7:1 to about 22:1. 19. A method for reducing an amount of a dissolved gas and/or an impurity in a molten metal bath, the method comprising: (a) operating the ultrasonic device of claim 14 in the molten metal bath; and (b) introducing a purging gas through the gas delivery system and into the molten metal bath. 20. The method of claim 19 , wherein: the dissolved gas comprises oxygen, hydrogen, sulfur dioxide, or a combination thereof; the molten metal bath comprises aluminum, copper, zinc, steel, magnesium, or a combination thereof; and the purging gas comprises nitrogen, helium, neon, argon, krypton, xenon, chlorine, or a combination thereof. 21. The method of claim 19 , wherein: the dissolved gas comprises hydrogen; the molten metal bath comprises aluminum, copper, or a combination thereof; and the purging gas comprises argon, nitrogen, or a combination thereof. 22. The method of claim 19 , wherein the purging gas is introduced into the molten metal bath at a rate in a range from about 1 to about 50 L/min. 23. An ultrasonic device comprising: an ultrasonic transducer; an elongated probe comprising a tip; a booster between the ultrasonic transducer and the elongated probe; and a gas delivery system, the gas delivery system comprising: a gas inlet in the booster, a gas flow path through the probe, and a gas outlet at the tip of the probe; wherein a length to diameter ratio of the probe is in a range from about 5:1 to about 25:1. 24. The ultrasonic device of claim 23 , wherein the probe comprises stainless steel, titanium, niobium, a ceramic, or a combination thereof. 25. The ultrasonic device of claim 23 , wherein the probe comprises a Sialon. 26. The ultrasonic device of claim 23 , wherein: a ratio of the cross-sectional area of the tip of the probe to the cross-sectional area of the gas outlet is in a range from about 60:1 to about 750:1; and the length to diameter ratio is in a range from about 7:1 to about 22:1. 27. A method for reducing an amount of a dissolved gas and/or an impurity in a molten metal bath, the method comprising: (a) operating the ultrasonic device of claim 23 in the molten metal bath; and (b) introducing a purging gas through the gas delivery system and into the molten metal bath at a rate in a range from about 0.1 to about 150 L/min.
Treatment with gases (C21C7/072, C22B9/05 take precedence) · CPC title
Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title
using inert or reactive gases (C22B21/066 and C22B21/068 take precedence) · CPC title
Injection assemblies therefor (features relating to gas injection, provided on closures of the sliding gate type B22D41/42; provided on pouring nozzles B22D41/58; provided on closures of the stopper-rod type B22D41/186) · CPC title
by vibration · CPC title
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