Renewable olefins from a mixture of acetic acid and propionic acid
US-9212106-B2 · Dec 15, 2015 · US
US9381494B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9381494-B2 |
| Application number | US-201414248799-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 9, 2014 |
| Priority date | Dec 31, 2013 |
| Publication date | Jul 5, 2016 |
| Grant date | Jul 5, 2016 |
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A photocatalytic film structure is provided. The photocatalytic film includes a plurality of micron particles; a plurality of nano particles; and a plurality of block bodies, wherein the volume of each of the block bodies is greater than that of each of the nano particles, and each of the micron particles, the nano particles and the block bodies contains zinc oxide and a doping metal, and wherein the amount of the doping metal is 1 to 5 wt % of the photocatalytic film, and the plurality of micron particles and micron particles take up 10 to 50% of the volume of the photocatalytic film.
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What is claimed is: 1. A photocatalytic film structure, comprising: a plurality of micron particles; a plurality of nano particles; and a plurality of block bodies, wherein a volume of each of the block bodies is greater than that of each of the nano particles; each of the micron particles, the nano particles and the block bodies contains zinc oxide and a doping metal; an amount of the doping metal is 1 to 5 wt % of the photocatalytic film structure; and the plurality of micron particles and the plurality of nano particles take up 10 to 50% of the volume of the photocatalytic film structure, and wherein the photocatalytic film structure has a thickness ranging from 20 to 70 μm. 2. The photocatalytic film structure of claim 1 , wherein the plurality of micron particles have a particle diameter ranging from 5 to 45 μm. 3. The photocatalytic film structure of claim 1 , wherein the plurality of nano particles have a particle diameter ranging from 95 to 195 nm. 4. The photocatalytic film structure of claim 1 , which has porosity ranging from 1 to 20%. 5. The photocatalytic film structure of claim 1 , wherein the doping metal is at least one element selected from the group consisting of Al and Ag. 6. The photocatalytic film structure of claim 1 , wherein the zinc oxide takes up 95 to 99 wt % of the photocatalytic film structure. 7. The photocatalytic film structure of claim 1 , which is formed on a substrate. 8. The photocatalytic film structure of claim 7 , wherein the substrate is one selected from the group consisting of a metal, an alloy, ceramics and glass. 9. The photocatalytic film structure of claim 7 , wherein the sizes of some of the block bodies in a direction parallel to a surface of the substrate are greater than the sizes in a direction perpendicular to the surface of the substrate.
Nanoparticles · CPC title
characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title
using molten compounds · CPC title
of metal substrates · CPC title
making use of flames, plasmas or lasers · CPC title
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