Method for producing CO2, N2 and/or SO2 for quantitative analysis from a sample

Patent metadata

Field	Value
Publication number	US-9377446-B2
Application number	US-201414151100-A
Country	US
Kind code	B2
Filing date	Jan 9, 2014
Priority date	Mar 31, 2008
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

The invention relates to a device for producing CO 2 , N 2 and/or SO 2 from a sample for a quantitative analysis of the sample, comprising a reactor structure and metals acting in an oxidizing manner or metal oxides in the reactor. According to the invention, the reactor structure has at least two zones through which the sample can flow, which is to say a first zone with reactor metal and reservoir metal, or only reactor metal, and following the first zone, a second zone with reactor metal and reservoir metal, or only reservoir metal, wherein both metals can form oxides, and wherein the ratio of the reactor metal to the reservoir metal in the first zone is greater than in the second zone.

First claim

The invention claimed is:

1. A method for forming at least one of CO 2 , N 2 and/or SO 2 from a sample contained in a gas stream for quantitative analysis, the method comprising:
providing a reactor structure having a first and a second zone, the first zone having disposed therein one of reactor metal or a combination of reactor metal and reservoir metal, the second zone having disposed therein one of reservoir metal or a combination of reservoir metal and reactor metal, wherein the ratio of the surface areas of reactor metal to reservoir metal is higher in the first zone relative to the second zone;
prior to performing quantitative analysis, oxidizing the reactor metal and the reservoir metal by flowing an oxygen-containing gas stream through the first and second zones;
flowing the sample-containing gas stream through the first and second zones in succession to form at least one of CO 2 , N 2 and/or SO 2 by reaction of the sample, wherein the first zone is maintained at a higher temperature relative to the second zone and wherein at least one metal in the second zone is a continuous extension of at least one corresponding metal in the first zone;
directing the gas stream from an exit of the second zone to an analyzer for measurement of at least one of CO 2 , N 2 and/or SO 2 .

2. The method of claim 1 , wherein the sample is an organic sample or a derivative of an organic sample.

3. The method of claim 1 , further comprising a step of separating components of the sample by gas chromatography prior to flowing the sample-containing gas stream into the reactor structure.

4. The method of claim 1 , wherein the analyzer is a mass spectrometer.

5. The method of claim 4 , wherein the mass analyzer is configures to perform an isotope ratio analysis of at least one of CO 2 , N 2 and/or SO 2 in the gas stream.

6. The method of claim 3 , further comprising a step of adding oxygen-containing gas to the gas stream after separation by gas chromatography but prior to flowing the gas stream through the first zone.

7. The method of claim 1 , wherein the analyzer measures CO 2 in the gas stream.

8. The method of claim 1 , wherein the analyzer measures N 2 in the gas stream.

9. The method of claim 1 , wherein the analyzer measures SO 2 in the gas stream.

10. The method of claim 1 , wherein the first zone is maintained between 800° C. and 1200° C. in the first zone, and between room temperature and 800° C. in the second zone.

11. The method of claim 10 , wherein the first zone is maintained between 900° C. and 1100° C. in the first zone.

12. The method of claim 1 , wherein the reactor metal is nickel.

13. The method of claim 1 , wherein the reservoir metal is copper.

Assignees

• Thermo Fisher Scient Bremen

Inventors

• Krummen Michael

Classifications

• Y10T436/17

  Nitrogen containing · CPC title

• Y10T436/25

  including sample preparation · CPC title

• G01N1/4022

  by thermal techniques; Phase changes · CPC title

• Y10T436/186

  Sulfur dioxide · CPC title

• G01N31/12

  using combustion (G01N25/20 takes precedence) · CPC title