Dual-refluxed heavies removal column in an LNG facility

Patent metadata

Field	Value
Publication number	US-9377239-B2
Application number	US-94074907-A
Country	US
Kind code	B2
Filing date	Nov 15, 2007
Priority date	Nov 15, 2007
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

A liquefied natural gas facility employing a heavies removal column having multiple reflux streams. The reflux streams can have different compositions and can be operable to reduce the critical pressure of the fluids within the heavies removal column in order to permit the column to operate at higher pressures without adversely affecting the horsepower requirements of plant compressor/driver systems.

First claim

What is claimed is:

1. A method comprising:
cooling a predominantly methane stream in a refrigeration cycle to form a cooled predominantly methane stream;
separating the cooled predominantly methane stream in a first distillation column to produce a first bottoms stream, a first overhead stream, and a predominately liquid bottoms stream, wherein the first bottoms stream, the first overhead stream and the predominantly liquid bottoms stream are separate streams upon expulsion from the first distillation column, wherein the first bottoms stream and the predominantly liquid bottoms stream are each routed from the first distillation column to a heat exchanger;
introducing a first reflux stream comprising at least about 85 mole percent methane into the first distillation column; and
heating the predominantly liquid bottoms stream in the heat exchanger to provide an at least partially vaporized stream, which is introduced into the first distillation column;
heating the first bottoms stream in the heat exchanger before being introduced into a second distillation column;
separating the first bottoms stream in the second distillation column to withdrawal a natural gas liquids stream and produce a second overhead stream;
dividing the second overhead stream into first and second portions;
cooling the second portion of the second overhead stream in the heat exchanger via indirect heat exchange with the first bottoms stream and the predominantly liquid bottoms stream to produce a two-phase stream;
separating vapor and liquids of the two-phase stream in a separator;
introducing the liquids from the separator as a second reflux stream into the first distillation column at a lower elevation than the first reflux stream; wherein the second reflux stream is introduced into the first distillation column at a lower elevation than the cooled predominantly methane stream;
combining the vapor from the separator with the first portion of the second overhead stream to provide a heavies removal zone exit stream; and
combining the heavies removal zone exit stream with a methane-rich vapor stream to provide a combined methane compressor inlet stream, which is routed to a methane compressor.

2. The method of claim 1 , wherein the temperature of the cooled predominantly methane stream when introduced into the first distillation column is less than about −50° F.

3. The method of claim 1 , wherein the first bottoms stream is not fractionated between the first distillation column and the second distillation column.

4. The method of claim 1 , further comprising, cooling at least a portion of the first overhead stream in a methane refrigeration cycle to produce a cooled first overhead stream, wherein the first reflux stream comprises at least a portion of the cooled first overhead stream.

5. The method of claim 1 , wherein the average molecular weight of the second reflux stream is at least about 10 percent greater than the average molecular weight of the first reflux stream.

6. The method of claim 1 , wherein the first reflux stream has an average molecular weight less than about 24 grams per mole.

7. The method of claim 1 , wherein the second reflux stream has an average molecular weight less than about 52 grams per mole.

8. The method of claim 1 , wherein the second reflux stream comprises at least about 15 mole percent of ethane and/or ethylene and less than about 60 mole percent of propane and heavier components.

9. The method of claim 1 , wherein the overhead operating temperature of the first distillation column is in the range of from about −200° F. to about −75° F. and the overhead operating pressure of the first distillation column is in the range of from about 20 barg to about 70 barg.

10. The method of claim 1 , wherein the refrigeration cycle is part of a cascade LNG process employing sequential propane, ethylene, and methane refrigeration cycles.

11. The method of claim 1 , further comprising vaporizing liquefied natural gas product produced from the first overhead stream and heavies removal zone exit stream.

Assignees

• Mock Jon M
• Wilkes Michael A
• Conocophillips Co

Inventors

• Mock Jon M
• Wilkes Michael A

Classifications

• F25J2270/02

  Internal refrigeration with liquid vaporising loop · CPC title

• F25J3/0238

  separation of CnHm with 2 carbon atoms or more · CPC title

• F25J2200/04

  in a dual pressure main column system · CPC title

• F25J2245/02

  Recycle of a stream in general, e.g. a by-pass stream · CPC title

• F25J2205/04

  in the feed line, i.e. upstream of the fractionation step · CPC title