Compositions comprising at least one compound containing a carbamoyl sulfonate group and use of the same as tanning agents

Patent metadata

Field	Value
Publication number	US-9376729-B2
Application number	US-201113814053-A
Country	US
Kind code	B2
Filing date	Jul 28, 2011
Priority date	Aug 6, 2010
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

Aqueous composition containing
a) at least one compound containing carbamoylsulphonate groups and b) at least one nonionic alkoxylated polyol containing ester groups and having an HLB value of at least 13 (b1) and/or alkylglycoside (b2).

First claim

What is claimed is:

1. Aqueous composition comprising:
a) at least one compound containing carbamoylsulphonate groups; and
b) at least one of:
b1) at least one nonionic alkoxylated polyol containing ester groups and having an HLB value of at least 13; and
b2) at least one alkylglycoside.

2. The aqueous composition according to claim 1 , wherein the component a) is a reaction product of organic polyisocyanates and at least one of bisulphite and disulphite.

3. The aqueous composition according to claim 1 , containing
5 to 50 wt % of the component a) compound containing carbamoylsulphonate groups, and
0.05 to 5 wt % of the compound of component b)
all based on the composition.

4. The aqueous composition according to claim 2 , wherein the organic polyisocyanate is a polyisocyanate having an NCO functionality of 1.8 to 4.2 and a molecular weight of <800 g/mol.

5. The aqueous composition according to claim 2 , wherein the organic polyisocyanate has a molecular weight of less than 400 g/mol and NCO groups attached to aliphatics or cycloaliphatics.

6. The aqueous composition according to claim 1 , wherein the compound of component b1) is the reaction product of a polyol with at least one alkylene oxide of 2 to 6 carbon atoms in an amount of 10 to 60 mol equivalents, based on the polyol and subsequent reaction with at least one carboxylic acid of 6 to 30 carbon atoms.

7. The aqueous composition according to claim 6 , wherein the polyol is a polyol from the group consisting of glycerol, trimethylolpropane, pentaerythritol, dipentaerythritol and polyols derived from mono- and polysaccharides.

8. The aqueous composition according to claim 1 , wherein the compound of component b2) comprises alkylmonoglucosides, alkyldiglucosides, alkyl-triglucosides, or higher homologues and mixtures thereof, the hydroxyl groups of which are partially substituted with C 6 -C 18 -alkyl groups.

9. The aqueous composition according to claim 1 , further comprising products from the groups of synthetic tanning agents.

10. The aqueous composition according to claim 1 , further comprising component c) a carboxylic acid.

11. Leathers and furs treated with a composition according to claim 1 .

12. Compounds containing carbamoylsulphonate groups, said compounds being a reaction product of at least one organic isocyanate with at least one bisulphite and/or disulphite, and at least one carboxylic acid, in the presence of at least one of a nonionic alkoxylated polyol containing ester groups and having an HLB of at least 13 (b1) and an alkyl glycoside (b2).

13. The aqueous composition according to claim 2 , wherein:
the composition contains
10 to 40 wt % of the component a) compound containing carbamoylsulphonate groups, and
0.1 to 2 wt % of the compound of component b)

all based on the composition; and
component c) a carboxylic acid; and

the organic polyisocyanate is a polyisocyanate having an NCO functionality of 1.8 to 2.5 and a molecular weight <400 g/mol.

14. The aqueous composition according to claim 13 , wherein:
the polyol is at least one of a polyol derived from and a polyols with sorbitan core scaffold;
the carboxylic acid is selected from the group consisting of citric acid, lactic acid, tartaric acid, and combinations thereof;
the organic polyisocyanate is selected from the group consisting of 1,4-diisocyanatobutane, 1,6-diisocyanatohexane (HDI), 1,5-diisocyanato-2,2-dimethylpentane, 2,2,4- or 2,4,4-trimethyl-1,6-diisocyanatohexane (TMHI), 1,3- and 1,4-diisocyanatohexane, 1,3- and 1,4-diisocyanatocyclohexane (CHDI) and also any desired mixtures of these isomers, 1-isocyanato-2-isocyanatomethylcyclopentane, 1,2-, 1,3- and 1,4-bis(isocyanatomethyl)-cyclohexane and also any desired mixtures of isomers, 1,2-, 1,3- and 1,4-bis(isocyanatoethyl)cyclohexane and also any desired mixtures of these isomers, 1,2-, 1,3- and 1,4-bis(isocyanato-n-propyl)cyclohexane and also any desired mixtures of these isomers, 1-isocyanatopropyl-4-isocyanatomethylcyclohexane and isomers, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (IPDI), 1-isocyanato-1-methyl-4-isocyanatomethylcyclohexane (IMCI), 2,4′- and 4,4′-diisocyanatodicyclohexylmethane (H 12 MDI) and isomers, dimeryl diisocyanate (DDI), bis(isocyanatomethyl)bicyclo[2.2.1]heptane (NBDI), bis(isocyanatomethyl)tricyclo[5.2.1.0 2,6 ]decane (TCDDI) and isomers and any desired mixtures of such diisocyanates and xylylenediisocyanates of the formulae

and
the composition further comprises at least one of resin tanning agents, polymeric retanning agents, vegetable tanning agents, fatliquoring agents, filers, and buffers.

Assignees

• REINERS JüRGEN
• Tysoe Christopher
• Wiechmann Jan-Dieter
• Krüger Claudia
• Grosch Rafael
• Heinzelmann Franz
• Ebbinghaus Michael
• Kleban Martin
• Lanxess Deutschland Gmbh

Inventors

• REINERS JüRGEN
• Tysoe Christopher
• Wiechmann Jan-Dieter
• Krüger Claudia
• Grosch Rafael
• Heinzelmann Franz
• Ebbinghaus Michael
• Kleban Martin

Classifications

• C08G18/284 Primary

  Compounds containing ester groups, e.g. oxyalkylated monocarboxylic acids · CPC title

• C08G18/706

  the liquid medium being water · CPC title

• C14C3/08 Primary

  by organic agents · CPC title

• C14C3/28

  Multi-step processes · CPC title

• C14C3/20

  sulfonated · CPC title