Method of making a hydroprocessing catalyst with a single step metal and chelant incorporation, the catalyst, and the use of the catalyst

Patent metadata

Field	Value
Publication number	US-9376637-B2
Application number	US-201113208181-A
Country	US
Kind code	B2
Filing date	Aug 11, 2011
Priority date	Aug 13, 2010
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

A hydroprocessing catalyst composition that comprises a metal-incorporated support having incorporated therein a metal component and a chelating agent, and, further comprising a polar additive. The catalyst composition is prepared by incorporating in a single step at least one metal component and a chelating agent into a support material to form a metal-incorporated support followed by drying the metal-incorporated support and thereafter incorporating therein a polar additive.

First claim

That which is claimed is:

1. A method of making a composition, wherein said method consists essentially of the following steps:
providing a shaped support;
incorporating a solution, consisting essentially of a metal component at a concentration of said solution so as to provide the desired metal content in the final composition and a chelating agent, into said shaped support to provide a metal-incorporated support;
drying said metal-incorporated support at a drying temperature not to exceed 300° C. so as to provide a dried metal-incorporated support having a volatiles content in the range of from 1 to 20 wt % LOI thereby creating an available pore volume;
incorporating a polar additive without a metal component into the available pore volume of said dried metal-incorporated support in an amount sufficient to fill at least 75% of the available pore volume with said polar additive to thereby provide an additive impregnated composition;
treating said additive impregnated composition by exposing said additive impregnated composition to a gaseous atmosphere containing hydrogen at a hydrogen partial pressure in the range of from 1 bar to 70 bar at a temperature ranging upwardly to 250° C. and for a hydrogen treatment time period in the range of from 0.1 hour to 100 hours to provide a hydrogen treated additive impregnated composition; and
sulfiding said hydrogen treated additive impregnated composition to provide an activated additive impregnated composition.

2. A method as recited in claim 1 , wherein said step of drying said metal-incorporated support is conducted at a drying temperature not to exceed 250° C.

3. A method as recited in claim 1 , wherein said chelating agent is selected from the group of compounds consisting of aminocarboxylic acids, polyamines, aminoalcohols, oximes, and polyethyleneimines.

4. A method as recited in claim 1 , wherein said polar additive is a heterocompound having polarity and a dipole moment of at least 0.45.

5. A method as recited in claim 1 , wherein said additive impregnated composition comprises a Group 9 or Group 10 metal component selected from the group consisting of cobalt and nickel present in an amount in the range of from 0.5 wt. % to 20 wt. %, and a Group 6 metal component selected from the group consisting of molybdenum and tungsten present in an amount in the range of from 5 wt. % to 50 wt. %, wherein the weight percents are based on the weight of the dry support material with the metal component as the element regardless of its actual form.

6. A method as recited in claim 1 , wherein said shaped support comprises a porous refractory oxide selected from the group of refractory oxides consisting of silica, alumina, titania, zirconia, silica-alumina, silica-zirconia, titania-alumina, zirconia-alumina, silica-titania and combinations of two or more thereof; and wherein said shaped support has a surface area (as determined by the BET method) in the range of from 50 m 2 /g to 450 m 2 /g, a mean pore diameter in the range of from 50 to 200 angstroms (Å), and a total pore volume exceeding 0.55 cc/g.

7. A method as recited in claim 6 , wherein at least 90% of the available pore volume of the pores of said dried metal-incorporated support provided by drying of said metal-incorporated support is filled with said polar additive.

8. A method as recited in claim 1 , wherein dipole moment of the polar additive is in the range from 0.6 to 4.

Assignees

• Gabrielov Alexei Grigorievich
• Ganja Ed
• Torrisi Salvatore Philip
• Shell Oil Co

Inventors

• Gabrielov Alexei Grigorievich
• Ganja Ed
• Torrisi Salvatore Philip

Classifications

• C10G2300/1077

  Vacuum residues · CPC title

• C10G45/08 Primary

  in combination with chromium, molybdenum, or tungsten metals, or compounds thereof · CPC title

• B01J31/38

  of titanium, zirconium or hafnium · CPC title

• C10G2400/04

  Diesel oil · CPC title

• B01J27/188

  with chromium, molybdenum, tungsten or polonium · CPC title