Thermoplastic composition, method of producing the same, and articles made therefrom

Patent metadata

Field	Value
Publication number	US-9376562-B2
Application number	US-201113989925-A
Country	US
Kind code	B2
Filing date	Dec 21, 2011
Priority date	Dec 22, 2010
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

A thermoplastic composition comprising from 60 percent to 99 percent by weight of one or more thermoplastic polymers; and from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked methylmethacrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size of equal to or less than 1.0 micron; and wherein an article produced from the scratch-resistant thermoplastic composition has a hardness of greater than F is provided. Also provided are a method of making the thermoplastic composition, articles made from the polycarbonate composition, and a method of making the articles.

First claim

We claim:

1. A thermoplastic composition comprising:
from 60 percent to 99 percent by weight of one or more polycarbonates; and
from 40 percent to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked (meth)acrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers;
wherein the crosslinked (meth)acrylate polymer has a volume average particle size in the range of from 185 to 237 nm, and, wherein the crosslinked (meth)acrylate polymer has a Tg from 90° C. and to 115° C. (measured by DSC, second heat); and
wherein an article produced from the thermoplastic composition has a hardness of greater than F; and wherein the crosslinked (meth)acrylate polymer is free of chain transfer agents.

2. The thermoplastic composition according to claim 1 , wherein the crosslinked (meth)acrylate polymer is substantially free of co-monomer.

3. The thermoplastic composition according to claim 1 , wherein the crosslinked (meth)acrylate polymer is obtained by an emulsion polymerization reaction.

4. The thermoplastic composition according to claim 1 , wherein the additive comprises (A) from greater than zero to less than or equal to 0.5 percent by weight EGDMA or (B) from greater than zero to less than or equal to 0.1 percent by weight TMPTA.

5. The thermoplastic composition according to claim 1 , wherein the crosslinked (meth)acrylate polymer has a Mw from 2.7×10 5 to 1.5×10 6 g/mol.

6. The thermoplastic composition according to claim 1 , wherein the thermoplastic composition has a hardness of H or greater.

7. An article comprising:
a thermoplastic composition comprising the melt blending product of:
from 60 to 99 percent by weight of one or more polycarbonates and from 40 to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked (meth)acrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers;

wherein the crosslinked (meth)acrylate polymer has a volume average particle size in the range of from 185 to 237 nm, and, wherein the crosslinked (meth)acrylate polymer has a Tg from 90° C. and to 115° C. (measured by DSC, second heat); and wherein the article has a hardness greater than F; and wherein the crosslinked (meth)acrylate polymer is free of chain transfer agents.

8. A method for forming an article comprising:
selecting a thermoplastic composition comprising the melt blending product of:
from 60 to 99 percent by weight of one or more polycarbonates, and from 40 to 1 percent by weight of an additive comprising a crosslinked (meth)acrylate polymer, wherein the crosslinked (meth)acrylate polymer comprises at least 99.5 percent by weight derived from methyl methacrylate units, and from greater than zero to less than 0.5 percent by weight derived from one or more multifunctional crosslinking monomers; wherein the crosslinked (meth)acrylate polymer has a volume average particle size in the range of from 185 to 237 nm, and, wherein the crosslinked (meth)acrylate polymer has a Tg from 90° C. and to 115° C. (measured by DSC, second heat); and

forming said thermoplastic composition into said article wherein the article has a hardness of greater than F; and wherein the crosslinked (meth)acrylate polymer is free of chain transfer agents.

Assignees

• Nelliappan Veera
• Lundquist Eric G
• Saint-Gerard Yannick
• Rohm & Haas

Inventors

• Nelliappan Veera
• Lundquist Eric G
• Saint-Gerard Yannick

Classifications

• C08L33/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08F2222/1013

  Chemistry & Metallurgy · mapped topic

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F20/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title