Process for preparing polyethylene blend comprising metallocene produced resins and chromium produced resins

Patent metadata

Field	Value
Publication number	US-9376557-B2
Application number	US-201214003164-A
Country	US
Kind code	B2
Filing date	Mar 2, 2012
Priority date	Mar 4, 2011
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.942 to 0.970 g/cm 3 and an HLMI of from 0.5 to 150 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a chromium catalyst in a reactor. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product. The homogeneous polyethylene product can include at least 25% by weight of the first polyethylene resin.

First claim

The invention claimed is:

1. A process for preparing a polyethylene product, said process comprising:
(a) producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor, said first polyethylene resin having a density of from 0.942 to 0.970 g/cm 3 and a High Load Melt Index (HLMI) of from 0.5 to 150 g/10 min, with the HLMI being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 21.6 kg and with the density being determined with the ASTM D-1505 standardized test at a temperature of 23° C., wherein said first polyethylene resin has a bimodal molecular weight distribution;
(b) separately producing a second polyethylene resin in the presence of a chromium catalyst in the reactor, and
(c) physically blending together said first polyethylene resin and said second polyethylene resin to produce a polyethylene product;
wherein the polyethylene product comprises at least 33% by weight of the first polyethylene resin.

2. The process according to claim 1 , wherein the metallocene catalyst used for the production of the first polyethylene resin comprises a bis tetrahydroindenyl compound of the general formula (IndH4)2R 4 MQ 2 wherein each Ind is the same or different and is indenyl or substituted indenyl, R 4 is a bridge which comprises a C 1-20 alkylene group, a dialkyl germanium or silicon or siloxane, or an alkyl phosphine or amine group, which bridge is substituted or unsubstituted, M is a Group IVB transition metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen.

3. The process according to claim 1 , wherein the second polyethylene resin has an HLMI of between 0.5 and 150 g/10 min.

4. The process according to claim 1 , wherein the second polyethylene resin has monomodal molecular weight distribution.

5. The process according to claim 1 , wherein the second polyethylene resin has a density of from 0.920 to 0.960 g/cm 3 .

6. The process according to claim 1 , wherein said first polyethylene resin and said second polyethylene resin are each produced under slurry conditions.

7. The process according to claim 1 , wherein said first polyethylene resin and said second polyethylene resin are each produced in a loop reactor.

8. The process according to claim 1 , wherein step (c) is performed in a device for continuously melting and blending said first polyethylene resin and said second polyethylene resin.

9. The process according to claim 8 , wherein said device is an extruder, a mixer, or combinations thereof.

10. The process according to claim 1 , wherein the second polyethylene resin has a density that is equal to or lower than the density of the first polyethylene resin.

11. A process for preparing a polyethylene product, said process comprising:
(a) producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor, said first polyethylene resin having a density of from 0.942 to 0.970 g/cm 3 and a High Load Melt Index (HLMI) of from 0.5 to 150 g/10 min, with the HLMI being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 21.6 kg and with the density being determined with the ASTM D-1505 standardized test at a temperature of 23° C., wherein said first polyethylene resin has a bimodal molecular weight distribution;
(b) separately producing a second polyethylene resin in the presence of a chromium catalyst in a reactor, wherein the second polyethylene resin has a density ranging from 0.920 to 0.960 g/cm 3 , an HLMI of from 0.5 to 150 g/10 min, and a monomodal molecular weight distribution;
(c) physically blending together said first polyethylene resin and said second polyethylene resin to produce a homogenous polyethylene product, wherein the homogenous polyethylene product has a density ranging from 0.920 to 0.960 g/cm 3 , an HLMI of from 2 to 300 g/10 min, and a multimodal molecular weight distribution;
wherein the homogenous polyethylene product comprises at least 33% by weight of the first polyethylene resin;
wherein the homogenous polyethylene product exhibits a higher stress crack resistance than the second polyethylene resin, wherein the stress crack resistance is measured by ISO 16770, specimen D, at 23° C., 11.44 MPa, and 2% Igepal, FNCT, and wherein the homogenous polyethylene product has a multimodal molecular weight distribution.

12. The process of claim 11 , wherein the homogenous polyethylene product comprises at least 40% by weight of the first polyethylene resin.

13. The process of claim 1 , wherein the polyethylene product comprises at least 40% by weight of the first polyethylene resin.

14. The process according to claim 1 ,
wherein the polyethylene product comprises at most 67% by weight of the second polyethylene resin.

15. The process of claim 14 , wherein the polyethylene product comprises at most 60% by weight of the second polyethylene resin.

16. The process according to claim 1 ,
wherein the second polyethylene resin has a density ranging from 0.920 to 0.960 g/cm 3 , an HLMI of from 0.5 to 150 g/10 min, and a monomodal molecular weight distribution;
wherein the polyethylene product is a homogenous polyethylene product, wherein the homogenous polyethylene product has a density ranging from 0.920 to 0.960 g/cm 3 , an HLMI of from 2 to 300 g/10 min, and a multimodal molecular weight distribution;
wherein the homogenous polyethylene product comprises at most 67% by weight of the second polyethylene resin;
wherein the homogenous polyethylene product exhibits a higher stress crack resistance than the second polyethylene resin, wherein the stress crack resistance is measured by ISO 16770, specimen D, at 23° C., 11.44 MPa, and 2% Igepal, FNCT, and wherein the homogenous polyethylene product has a multimodal molecular weight distribution.

17. The process of claim 16 , wherein the polyethylene product comprises at most 60% by weight of the second polyethylene resin.

Assignees

• Dewachter Daan
• Damme Eric
• Total Res & Technology Feluy

Inventors

• Dewachter Daan
• Damme Eric

Classifications

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title

• C08F110/02

  Ethene · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title