Catalyst and method of manufacture

Patent metadata

Field	Value
Publication number	US-9375710-B2
Application number	US-201414552409-A
Country	US
Kind code	B2
Filing date	Nov 24, 2014
Priority date	Sep 19, 2007
Publication date	Jun 28, 2016
Grant date	Jun 28, 2016

Abstract

Disclosed herein is a catalytic composition comprising a first catalyst composition portion that comprises a zeolite; and a second catalyst composition portion that comprises a catalytic metal disposed upon a porous inorganic substrate; the first catalyst composition portion and the second catalyst composition portion being in an intimate mixture.

First claim

The invention claimed is:

1. A catalytic system for the conversion of nitrogen oxides in exhaust gases comprising an intimate mixture comprised of:
a first catalyst composition comprised of particles of a ferrierite that contains no metal ions and is not doped with a metal, and
a second catalyst composition comprised of Ag on porous Al 2 O 3 particles,

wherein the ferrierite particles of the first catalyst composition are mixed with the particles of the second catalyst composition forming the intimate mixture in which the ferrierite particles are in contact with particles of the second catalyst composition in a weight ratio of ferrierite particles to second catalyst composition particles so that the catalyst system is capable of reducing the concentration of nitrogen oxide in the exhaust gases by between 15 weight percent to 90 weight percent at temperatures between 275° C. to 500° C.

2. The system as defined in claim 1 , wherein the ferrierite has a silicon to aluminum weight ratio in a range of from about 10 to about 30.

3. The system as defined in claim 1 , wherein the ferrierite has a surface area in a range of from about 200 m 2 /gm to about 500 m 2 /gm.

4. The system as defined in claim 1 , wherein the first catalyst composition is present in an amount in a range of from about 1 to about 80 weight percent, based upon the total weight of the first catalytic composition and the second catalytic composition.

5. The system as defined in claim 4 , wherein the first catalyst is present in an amount in a range from about 3.5 to about 8 weight percent, based upon the total weight of the first catalytic composition and the second catalytic composition.

6. The system as defined in claim 1 , wherein the mixture is supported on a monolith.

7. The system as defined in claim 1 , wherein the mixture is present as a washcoat on a substrate.

8. A catalytic system according to claim 1 , wherein the second catalyst composition is comprised of about 1 mol % Ag to about 5 mol % Ag on porous Al 2 O 3 particles.

9. A catalytic system according to claim 8 wherein the second catalyst composition is comprised of about 2 wt % Ag on porous Al 2 O 3 particles.

10. A catalytic system according to claim 1 , wherein the ferrierite particles are in contact with particles of the second catalyst composition in a weight ratio of 1:4 to 4:1.

11. A catalytic system for the conversion of nitrogen oxides in exhaust gases comprising an intimate mixture comprised of:
a first catalyst composition comprised of particles of a ferrierite that contains no metal ions and is not doped with a metal; and
a second catalyst composition comprised of Ag on porous Al 2 O 3 particles,

wherein the ferrierite particles of the first catalyst composition are mixed with the particles of the second catalyst composition forming the intimate mixture in which the ferrierite particles are in contact with particles of the second catalyst composition in a weight ratio of 1:4 to 4:1 so that the catalyst system is capable of reducing the concentration of nitrogen oxide in the exhaust gases by between 15 weight percent to 90 weight percent at temperatures between 275° C. to 500° C.

12. A catalytic system according to claim 11 , wherein the second catalyst composition comprised of about 1 mol % Ag to about 5 mol % Ag on porous Al 2 O 3 particles.

13. A catalytic system according to claim 12 , wherein the second catalyst composition comprised of 2 mol % Ag on porous Al 2 O 3 particles.

14. A catalytic system according to claim 13 , wherein the ferrierite particles are in contact with particles of the second catalyst composition in a weight ratio of 1:4.

15. A catalytic system according to claim 11 , wherein the catalyst system is capable of reducing the concentration of nitrogen oxide in the exhaust stream by between 15 weight percent to 90 weight percent at temperatures between 275° C. to 430° C.

16. A catalytic system according to claim 11 , wherein the catalyst system is capable of reducing the concentration of nitrogen oxide in the exhaust stream by between 15 weight percent to 90 weight percent at temperatures between 275° C. to 375° C.

Assignees

• Gen Electric

Inventors

• Hancu Dan
• Donald Jr Whisenhunt Wayne
• Benjamin Winkler Hale
• Benjamin Wood Rue
• Hrishikesh Keshavan

Classifications

• B01J35/393

  Metal or metal oxide crystallite size · CPC title

• B01J29/65

  of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively · CPC title

• B01D2257/404

  Nitrogen oxides other than dinitrogen oxide · CPC title

• B01D2255/104

  Silver · CPC title

• B01D2255/9205

  Porosity · CPC title