Composite material

Patent metadata

Field	Value
Publication number	US-9370915-B2
Application number	US-201113313087-A
Country	US
Kind code	B2
Filing date	Dec 7, 2011
Priority date	Dec 7, 2010
Publication date	Jun 21, 2016
Grant date	Jun 21, 2016

Abstract

The invention relates to an aerogel composite material, a process and a composition for producing the composite material and the use of the composite material.

First claim

We claim:

1. A composite material comprising aerogel SiO 2 particles and a crosslinked binder, the aerogel particles fixed in the crosslinked binder, wherein the aerogel particles have an organo-modified surface with hydrophobic groups, and the crosslinked binder forms a matrix embedding the aerogel particles, and wherein a crosslinker is selected from the group consisting of aldehydes, isocyanates, epoxides, acrylates, acrylamides, esters and divinylsulfonates, and the binder is a polymer substituted with amino groups, and the binder and the crosslinked binder are hydrophilic, wherein the proportion of the aerogel particles in the composite material is 5 to 99% by volume.

2. The composite material according to claim 1 , wherein the aerogel particles have a D 50 value of 0.1 to 100 μm.

3. The composite material of claim 2 , wherein the aerogel particles have a D 50 value of 1-30 μm.

4. The composite material according to claim 1 , wherein the aerogel particles have a porosity of 50 to 99% by volume.

5. The composite material according to claim 1 , wherein the binder includes recurring polymerized units of vinylamine.

6. The composite material according to claim 1 , wherein the binder is a polyvinylamine.

7. The composite material according to claim 6 , wherein the binder has a molar mass of 10,000 to 500,000 g/mol.

8. The composite material according to claim 1 , wherein the crosslinker has groups that react with the amino groups of the binder.

9. The composite material according to claim 1 , wherein the crosslinker is glyoxal.

10. A shaped article comprising the composite material according to claim 1 and a foam material.

11. The shaped article according to claim 10 , wherein the foam material is selected from polyurethane or polystyrene.

12. The shaped article according to claim 10 , wherein the foam material is laminated to the composite material.

13. The composite material according to claim 1 , wherein the binder is present from 10 to 25 parts by weight, the crosslinker is present from 0.5 to 5 parts by weight, based upon 100 parts by weight of aerogel.

14. A process for producing the composite material according to claim 1 , which comprises mixing the aerogel particles, the binder and the crosslinker, performing the crosslinking by reacting the crosslinker with the amino groups of the binder, and the material obtained is either
a. subjected directly to a shaping operation and optionally curing, or
b. pelletized, stored and subjected to shaping and curing as or when required.

15. A composite material comprising amino functionalized aerogel particles and a crosslinked binder, wherein the amino functionalized aerogel particles include a surface with silane hydrophobic groups, and the crosslinked binder forms a matrix embedding the aerogel particles, and wherein the crosslinked binder is obtained from a polymer substituted with amino groups and a crosslinker selected from the group consisting of aldehydes, isocyanates, epoxides, acrylates, acrylamides, esters and divinylsulfonates, wherein the crosslinker also reacts with the amino functionalized aerogel particles to fix the aerogel particles to the crosslinked binder.

16. The composite material according to claim 15 , wherein the binder is a polyvinylamine, and the crosslinker is selected from glyoxal or ethylene glycol dimethyl ether.

17. A shaped article comprising the composite material according to claim 15 , which is admixed with expanded polystyrene in a volume ratio of composite material to polystyrene of 10:90 to 90:10 to form the shaped article.

18. The composite material according to claim 15 , wherein the aerogel particles have a D 50 value of 1-30 μm, and a porosity of 50 to 99% by volume.

Assignees

• Sandler Jan Kurt Walter
• Steinke Tobias Heinz
• Ulanova Tatiana
• Hahn Klaus
• Basf Se

Inventors

• Sandler Jan Kurt Walter
• Steinke Tobias Heinz
• Ulanova Tatiana
• Hahn Klaus

Classifications

• B32B5/30

  one layer {being formed of particles, e.g. chips,} granules, powder · CPC title

• B32B2264/102

  Oxide or hydroxide · CPC title

• Y10T428/249953

  Composite having voids in a component [e.g., porous, cellular, etc.] · CPC title

• C01B33/155

  Preparation of hydroorganogels or organogels · CPC title

• B32B2264/12

  Mixture of at least two particles made of different materials · CPC title