Conducting plates for fuel cell elements

Patent metadata

Field	Value
Publication number	US-9368807-B2
Application number	US-201313866274-A
Country	US
Kind code	B2
Filing date	Apr 19, 2013
Priority date	Jun 30, 2006
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

The present invention relates to a fuel cell element having an active core interposed between a first and second conducting plate, wherein at least the first conducting plate is made from an alloy having, in percentages by weight, 24.0 to 27.0% nickel; 13.5 to 16.0% chromium; 1.90 to 2.35% titanium; 1.0 to 1.5% molybdenum; 0.10 to 0.50% vanadium; at most 0.08% carbon; at most 2.0% manganese; at most 1.0% silicon; at most 0.35% aluminum; at most 0.03% sulphur; and at most 0.01% boron, the balance consisting of iron and impurities.

First claim

What is claimed is:

1. A fuel cell element comprising:
a first conducting plate and a second conducting plate, wherein said first conducting plate has at least one face with an arithmetic roughness Sa of 0.12 μm or higher and a maximum height amplitude St of less than 4 μm,
an active core comprising an anode, a cathode, and an electrolyte interposed between said anode and said cathode,
said active core being interposed between said first and second conducting plates,
wherein at least said first conducting plate comprises at least one alloy having, in percentages by weight:
24.0 to 27.0% nickel;
13.5 to 16.0% chromium;
1.90 to 2.35% titanium;
1.0 to 1.5% molybdenum;
0.10 to 0.50% vanadium;
at most 0.08% carbon;
at most 2.0% manganese;
at most 1.0% silicon;
at most 0.35% aluminium;
at most 0.03% sulphur; and
at most 0.01% boron,
the balance consisting of iron and impurities.

2. The fuel cell element according to claim 1 , wherein the alloy contains:
24.0 to 25.5% nickel;
14.0 to 16.0% chromium;
2.00 to 2.30% titanium;
1.2 to 1.5% molybdenum;
0.10 to 0.50% vanadium;
at most 0.06% carbon;
at most 2.0% manganese;
at most 0.3% silicon;
at most 0.25% aluminium;
at most 0.01% sulphur;
and at most 0.01% boron,
the balance consisting of iron and impurities.

3. The fuel cell element according to claim 1 wherein the electrolyte is a proton exchange membrane.

4. The fuel cell element according to claim 1 , wherein said face has a developed surface area Sdr of greater than 0.2%.

5. The fuel cell element according to claim 1 , wherein said first conducting plate can be obtained by a manufacturing process comprising the surfacing of a sheet containing said alloy, said process comprising the following steps in succession:
(a) a semi-finished product chosen from a thin slab or a hot-rolled sheet is cold rolled;
(b) the sheet obtained in step (a) is continuously annealed, at a temperature between 900 and 1200° C. for a time ranging from 10 seconds to 30 minutes, in an oxidizing atmosphere; and
(c) the annealed sheet obtained from step (b) is pickled by bringing it into contact with at least one mineral acid at a temperature of between 40 and 100° C.,
wherein the manufacturing process further includes at least the following steps:
said sheet having a thickness of 0.05 to 0.5 mm, in particular 0.1 to 0.2 mm, undergoes a first deformation by means of a first tool in order to obtain a corrugated blank; and
said corrugated blank undergoes a second, tangential deformation by means of a second tool.

6. The fuel cell element according to claim 1 , wherein said first and second conducting plates include channels for the flow of feed gases and the discharge of water.

7. The fuel cell element according to claim 1 wherein the alloy has a percentage by weight of chromium of less than 16.0%.

8. A fuel cell containing at least one fuel cell element according to claim 1 .

9. A method for supplying electricity to a vehicle, or a telecommunication means comprising the step of providing the fuel cell according to claim 8 .

10. The fuel cell according to claim 8 wherein the fuel cell is a photon exchange membrane fuel cell (PEMFC) type.

Assignees

• Air Liquide
• Arcelormittal Stainless & Nickel Alloys
• Aperam Alloys Imphy

Inventors

• Claude Eric
• Bosquet Richard
• Platen Gilles
• Roussel Claude

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M4/80

  Porous plates, e.g. sintered carriers · CPC title

• Y02P70/56

  Cross-Sectional Technologies · mapped topic

• C22C38/50

  with titanium or zirconium · CPC title

• C22C38/06

  containing aluminium · CPC title