Sheet of glass with high energy transmission

Patent metadata

Field	Value
Publication number	US-9365447-B2
Application number	US-201314386438-A
Country	US
Kind code	B2
Filing date	Apr 3, 2013
Priority date	Apr 4, 2012
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

The invention concerns an ultra-clear glass sheet, i.e. a sheet of glass with high energy transmission, that can be used, in particular, in the solar and architectural fields. More specifically, the invention concerns a sheet of glass having a composition which comprises, in an amount expressed as percentages of the total weight of the glass: SiO 2 60-78%; Al 2 O 3 0-10%; B 2 O 3 0-5%; CaO 0-15%; MgO 0-10%; Na 2 O 5-20%; K 2 O 0-10%; BaO 0-5%; total iron (expressed in the form of Fe 2 O 3 ) 0.002-0.03%, the composition comprises a copper content of 0.001 to 0.15% by weight relative to the total weight of the glass, the copper content being expressed in the form of Cu as a percentage by weight relative to the total weight of the glass.

First claim

The invention claimed is:

1. A sheet of glass having a composition that comprises, in contents expressed as percentages of total weight of glass:

SiO 2
60-78%

Al 2 O 3
 0-10%

B 2 O 3
0-5%

CaO
 0-15%

MgO
 0-10%

Na 2 O
 5-20%

K 2 O
 0-10%

BaO
0-5%

Total iron
0.002-0.03%, 

(expressed in the form of Fe 2 O 3 )

wherein the composition further comprises a copper content from 0.001 to 0.15% by weight relative to the total weight of the glass, the copper content being expressed in the form of Cu as percentage by weight relative to the total weight of the glass, and
wherein a ratio of Cu/Total iron is such that the sheet of glass exhibits an increase in energy transmission (ΔET) of at least 0.1% relative to an otherwise identical sheet of glass having no copper.

2. The sheet of glass according to claim 1 , wherein the composition comprises a total iron content (expressed in the form of Fe 2 O 3 ) from 0.002 to 0.02 wt % relative to the total weight of the glass.

3. The sheet of glass according to claim 1 , wherein the composition comprises a copper content (expressed in the form of Cu) from 0.001 to 0.04 wt % relative to the total weight of the glass.

4. The sheet of glass according to claim 3 , wherein the composition comprises a copper content (expressed in the form of Cu) from 0.003 to 0.04 wt % relative to the total weight of the glass.

5. The sheet of glass according to claim 1 , wherein it has an energy transmission, measured for a thickness of 3.85 mm, of at least 90%.

6. The sheet of glass according to claim 1 , wherein the composition comprises a copper content (expressed in the form of Cu) from 0.012 to 0.05 wt % relative to the total weight of the glass.

7. The sheet of glass according to claim 1 , wherein it has a light transmission, measured for a thickness of 4 mm, of at least 90.3%.

8. The sheet of glass according to claim 1 , wherein it has a dominant wavelength below 510 nm.

9. The sheet of glass according to claim 1 , wherein the composition has a redox below 0.3.

10. The sheet of glass according to claim 1 , wherein the composition further comprises a content of SO 3 above 0.2 wt % relative to the total weight of the glass.

11. The sheet of glass according to claim 1 , wherein it is coated with at least one thin transparent and electrically conducting layer.

12. The sheet of glass according to claim 11 , wherein the thin transparent and electrically conducting layer comprises SnO 2 :F, SnO 2 :Sb, ITO (indium-tin oxide), ZnO:Al and/or ZnO:Ga.

13. The sheet of glass according to claim 11 , wherein the thin transparent and electrically conducting layer is on one or both sides of the sheet of glass, and the thin transparent and electrically conducting layer is on one or both sides of the sheet of glass, and the thin transparent and electrically conducting layer is one or more selected from an antireflective layer, and an antisoiling layer.

14. A solar photovoltaic module or mirror comprising at least one sheet of glass according to claim 1 , wherein the mirror, if present, is a solar mirror.

Assignees

• Agc Glass Europe

Inventors

• Dogimont Audrey
• Hennecker Sebastien
• Lambricht Thomas

Classifications

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title

• C03C3/087 Primary

  containing calcium oxide, e.g. common sheet or container glass · CPC title

• C03C4/0092

  for glass with improved high visible transmittance, e.g. extra-clear glass · CPC title

• C03C17/06

  with metals (C03C17/34, C03C17/44 take precedence) · CPC title

• C03C2217/948

  Layers comprising indium tin oxide [ITO] · CPC title