Dispersion of hardphase particles in an infiltrant

Patent metadata

Field	Value
Publication number	US-9364936-B2
Application number	US-201113271415-A
Country	US
Kind code	B2
Filing date	Oct 12, 2011
Priority date	Oct 12, 2011
Publication date	Jun 14, 2016
Grant date	Jun 14, 2016

Abstract

Composite materials for use with a drill bit for drilling a borehole in earthen formations. The composite material comprises a first pre-infiltrated hardphase constituent and a second pre-infiltrated hardphase constituent. The second pre-infiltrated hardphase constituent is a carbide which comprises at least 0.5 weight % of a binder and at least about 1% porosity. The composite material further comprises an infiltrant.

First claim

What is claimed is:

1. A composite material comprising:
a product of heating a mixture to a temperature above a melting point of an infiltrant and below a melting point of a second binder, wherein the mixture comprises:
a first pre-infiltrated hardphase constituent comprising a first porous carbide having a first binder disposed therein;
at least a second partially sintered pre-infiltrated hardphase constituent, wherein the second pre-infiltrated hardphase constituent comprises a second porous carbide and at least about 15 weight % to about 25 weight % of the second binder wherein the second pre-infiltrated hardphase constituent comprises at least about 1% porosity, wherein the second pre-infiltrated hardphase constituent has a smaller average particle size than the first pre-infiltrated hardphase constituent; and
the infiltrant, wherein the melting point of the infiltrant is below the melting point of the second binder;
wherein the composite material comprises a disintegrated particulate structure of the second pre-infiltrated hardphase constituent, wherein the disintegrated particulate structure comprises a plurality of particulates formed from the disintegrated second pre-infiltrated hardphase constituent directly embedded in the infiltrant, and wherein the plurality of particulates have a size of 20% or less of the second pre-infiltrated hardphase constituent, and wherein the composite material comprises a plurality of localized uniform hard phase regions disposed within the interstitial spaces between the larger first pre-infiltrated hardphase constituent in the infiltrant, wherein the plurality of localized uniform hard phase regions are formed from the disintegrated particulate structures of the second pre-infiltrated hard phase constituent.

2. The composite material of claim 1 , further comprising a third pre-infiltrated hardphase constituent.

3. The composite material of claim 1 , wherein the first pre-infiltrated hardphase constituent has an average particle size of about 50 μm to about 1200 μm.

4. The composite material of claim 1 , wherein the first pre-infiltrated hardphase constituent has an average particle size of about 300 μm to about 900 μm.

5. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent has a particle size of about 1 μm to about 300 μm.

6. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent has a particle size of about 5 μm to about 100 μm.

7. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent has a particle size of from about 15 μm to about 60 μm.

8. The composite material of claim 1 , wherein the plurality of particulates have a size of 10% or less of the second pre-infiltrated hardphase constituent.

9. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent comprises at least one of: boron carbide, silicon carbide, titanium carbide, tantalum carbide, chromium carbide, vanadium carbide, zirconium carbide hafnium carbide, molybdenum carbide, niobium carbide, tungsten carbide, cemented tungsten carbide, partially sintered cemented tungsten carbide, spherical cast carbide, or crushed cast carbide.

10. The composite material of claim 9 , wherein the second pre-infiltrated hardphase constituent is a partially sintered cemented tungsten carbide.

11. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent comprises about 17 weight percent of the second binder.

12. The composite material of claim 1 , wherein the second binder comprises at least one of Al, Ni, Co, Cr, Cu, and Fe.

13. The composite material of claim 12 , wherein the second binder is Ni.

14. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent is 83WC-17Ni.

15. The composite material of claim 1 , wherein the infiltrant comprises at least one of Al, Co, Cr, Ni, Fe, Mn, Zn, or Cu.

16. The composite material of claim 1 , wherein the first binder is selected from the group consisting of: Al, Co, Cr, Ni, Cu, and Fe.

17. The composite material of claim 16 , wherein the second binder is Co.

18. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent comprises about 1% to about 50% porosity.

19. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent comprises about 1% to about 10% porosity.

20. The composite material of claim 1 , wherein the second pre-infiltrated hardphase constituent comprises about 1% to about 5% porosity.

21. A composite material comprising:
a product of heating a mixture to a temperature above a melting point of an infiltrant and below a melting point of a second binder, wherein the mixture comprises:
a first pre-infiltrated hardphase constituent comprising a first porous carbide having a first binder disposed therein;
at least a second partially sintered pre-infiltrated hardphase constituent; wherein the second pre-infiltrated hardphase constituent comprises a second porous carbide and at least about 15 weight % to about 25 weight % of the second binder, wherein the second binder comprises nickel, wherein the second pre-infiltrated hardphase constituent comprises at least about 1% porosity, wherein the second pre-infiltrated hardphase constituent has a smaller average particle size than the first pre-infiltrated hardphase constituent; and
the infiltrant, wherein the infiltrant comprises copper, wherein the melting point of the infiltrant is below the melting point of the second binder,
wherein the composite material comprises a disintegrated particulate structure of the second pre-infiltrated hardphase constituent, wherein the disintegrated particulate structure comprises a plurality of particulates formed from the disintegrated second pre-infiltrated hardphase constituent directly embedded in the infiltrant, wherein the composite material comprises a plurality of localized uniform hard phase regions disposed within the interstitial spaces between the larger first pre-infiltrated hardphase constituent in the infiltrant, wherein the plurality of localized uniform hard phase regions are formed from the disintegrated particulate structures of the second pre-infiltrated hard phase constituent, and wherein the plurality of particulates have a size of 20% or less of the second pre-infiltrated hardphase constituent.

22. The composite material of claim 21 , wherein the first pre-infiltrated hardphase constituent has an average particle size of about 300 μm to about 900 μm, and wherein the second pre-infiltrated hardphase constituent has a particle size of about 1 μm to about 300 μm.

23. The composite material of claim 21 , wherein the plurality of particulates have a size of 10% or less of the second pre-infiltrated hardphase constituent.

24. The composite material of claim 21 , wherein the second pre-infiltrated hardphase constituent comprises at least one of: boron carbide, silicon carbide, titanium carbide, tantalum carbide, chromium carbide, vanadium carbide, zirconium carbide hafnium carbide, molybdenum carbide, niobium carbide, tungsten carbide, cemented tungsten carbide, partially sintered cemented tungsten carbide, spherical cast carbide, or crushed cast carbide.

25. The composite material of claim 24 , wherein the first pre-infiltrated hardphase constituent comprises at least one of: silicon carbide, diamond, tit

Assignees

• Sreshta Harold A
• Nat Oilwell Dht Lp

Inventors

• Sreshta Harold A

Classifications

• C22C1/1036

  starting from a melt · CPC title

• B24D18/0009

  using moulds or presses · CPC title

• C22C1/00

  Making non-ferrous alloys (by electrothermic methods C22B4/00; by electrolysis C25C1/24, C25C3/36) · CPC title

• B24D3/06 Primary

  metallic {or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements} · CPC title

• B24D99/005

  Segments of abrasive wheels · CPC title