Battery with hybrid electrocatalysts

Patent metadata

Field	Value
Publication number	US-9362568-B2
Application number	US-201414336854-A
Country	US
Kind code	B2
Filing date	Jul 21, 2014
Priority date	Feb 18, 2011
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

Aspects of the present disclosure are directed to electrodes and implementations such as batteries. As may be implemented in accordance with one or more embodiments, an apparatus includes a nanocarbon substrate having at least one of graphene and carbon nanotubes, and a hybrid electrode including a cobalt oxide/carbon nanotube (CoO/CNT) catalyst and a Ni—Fe-layered double hydride (LDH) catalyst. The catalysts and substrate facilitate transfer of charge carriers. Various aspects are directed to a battery type device having an anode and a single or split cathode with the respective catalysts on the cathode to facilitate oxygen reduction and oxygen evolution reactions for discharging and charging the battery type device.

First claim

What is claimed is:

1. An apparatus comprising:
a nanocarbon substrate including at least one of graphene and carbon nanotubes (CNTs); and
a hybrid electrode including a cobalt oxide/carbon nanotube (CoO/CNT) catalyst and a Ni—Fe-layered double hydride (LDH) catalyst, the electrode being configured and arranged to facilitate transfer of charge carriers with the nanocarbon substrate.

2. The apparatus of claim 1 , further including an anode configured and arranged with the hybrid electrode in a battery, the hybrid electrode being configured and arranged as a cathode having:
the CoO/CNT catalyst on a first cathode substrate and configured and arranged to power a load connected between the first cathode and anode, by catalyzing an oxygen reduction reaction (ORR) and discharging energy stored in the battery, and
the Ni—Fe-LDH catalyst on a second cathode substrate and configured and arranged to store charge in the battery via a power source, connected between the second cathode substrate and the anode, by catalyzing an oxygen evolution reaction (OER) and storing energy in the battery.

3. The apparatus of claim 2 , wherein the first and second cathode substrates are separated from one another and the anode is between the first and second cathode substrates.

4. The apparatus of claim 1 , wherein the hybrid electrode is configured and arranged with the nanocarbon substrate to provide battery discharging and charging by:
catalyzing an ORR via the CoO/CNT catalyst during discharge of stored energy from the battery; and
catalyzing an OER via the Ni—Fe-LDH during charging of the battery.

5. The apparatus of claim 1 , wherein the hybrid electrode is configured and arranged with the nanocarbon substrate to provide battery discharging and charging by:
catalyzing an ORR during discharge of stored energy from the battery; and
catalyzing an OER during charging of the battery.

6. The apparatus of claim 1 , wherein the hybrid electrode is configured and arranged with the nanocarbon substrate to:
discharge energy by catalyzing an ORR via the CoO/CNT catalyst; and
store energy by catalyzing an OER via the Ni—Fe-LDH.

7. The apparatus of claim 1 , wherein the CoO/CNT catalyst includes CoO nanocrystals on N-doped CNTs.

8. The apparatus of claim 1 , wherein the Ni—Fe-LDH catalyst includes stacked Ni—Fe-LDH nanoplates having a thickness of about 10 atomic layers.

9. The apparatus of claim 1 , wherein the nanocarbon substrate includes carbon paper, and the CoO/CNT catalyst is on the carbon paper.

10. The apparatus of claim 1 , wherein the nanocarbon substrate includes graphene and CNTs.

11. The apparatus of claim 1 , wherein the nanocarbon substrate includes oxidized regions of the at least one of graphene and CNTs.

12. The apparatus of claim 1 , wherein the respective electrodes are configured and arranged to facilitate transfer of charge carriers with the nanocarbon substrate via covalent bonds implemented with at least one of the CoO/CNT catalyst and the Ni—Fe-LDH catalyst.

13. The apparatus of claim 1 , wherein the hybrid electrode includes a plurality of graphene sheets with nanocrystals thereupon being stacked in layers that form an electrochemical pseudo-capacitor electrode.

14. The apparatus of claim 1 , further including a charge-passing material that is a separator configured and arranged to pass charge with the hybrid electrode.

15. A battery apparatus comprising:
an anode;
an electrolyte;
a first cathode having a first substrate and a hybrid cobalt oxide/carbon nanotube (CoO/CNT) catalyst configured and arranged with the anode and the electrolyte to facilitate an oxygen reduction reaction (ORR) for discharging stored energy; and
a second cathode having a second substrate and a hybrid Ni—Fe-layered double hydride (LDH) catalyst configured and arranged with the anode and the electrolyte to facilitate an oxygen evolution reaction (OER) for storing energy.

16. The battery apparatus of claim 15 , wherein the first cathode is configured and arranged to power a load connected between the first cathode and the anode, further including a circuit configured and arranged to disconnect or interrupt a circuit path between the first cathode and the anode that passes via the load while the second cathode is operating to store the energy.

17. The battery apparatus of claim 15 , wherein the first and second substrates are carbon-based substrates.

18. The battery apparatus of claim 15 , wherein the anode is between the first and second cathodes and the electrolyte includes a first electrolyte portion between the first cathode and the anode, and a second electrolyte portion between the second cathode and the anode.

19. A method comprising:
storing energy by facilitating an oxygen evolution reaction (OER) using a first cathode having a substrate and a hybrid Ni—Fe-layered double hydride (LDH) catalyst, by passing charge carriers between the first cathode and an anode via an electrolyte; and
discharging the stored energy and powering a load by facilitating an oxygen reduction reaction (ORR) using a second cathode having a substrate and a hybrid cobalt oxide/carbon nanotube (CoO/CNT) catalyst, by passing charge carriers between the second cathode and the anode via an electrolyte.

20. The method of claim 19 , further including, while storing the energy, electrically insulating the second cathode from the anode by disconnecting a circuit connection between the second cathode and the anode.

Assignees

• Univ Leland Stanford Junior

Inventors

• Dai Hongjie

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• H01M12/005

  Electricity · mapped topic

• H01M12/08

  composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type · CPC title

• Y10S977/734

  Fullerenes, i.e. graphene-based structures, such as nanohorns, nanococoons, nanoscrolls or fullerene-like structures, e.g. WS2 or MoS2 chalcogenide nanotubes, planar C3N4, etc. · CPC title

• H01M12/06

  with one metallic and one gaseous electrode · CPC title