Method for making semiconducting single wall carbon nanotubes
US-9136117-B2 · Sep 15, 2015 · US
US9362080B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9362080-B2 |
| Application number | US-201514599992-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 19, 2015 |
| Priority date | Jan 20, 2014 |
| Publication date | Jun 7, 2016 |
| Grant date | Jun 7, 2016 |
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An electron emission device includes a number of second electrodes intersected with a number of first electrodes to define a number of intersections. The first electrode includes a carbon nanotube layer and a semiconductor layer coated on the carbon nanotube layer. An insulating layer is sandwiched between the first electrode and the second electrode at each of the number of intersections, wherein the semiconductor layer is sandwiched between the insulating layer and the carbon nanotube layer.
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What is claimed is: 1. An electron emission device, the electron emission device comprising: a plurality of first electrodes substantially parallel to each other and extending along a first direction, wherein each of the plurality of first electrodes comprises a carbon nanotube composite structure comprising a carbon nanotube layer and a semiconductor layer coated on the carbon nanotube layer; a plurality of second electrodes substantially parallel to each other and extending along a second direction, wherein the plurality of second electrodes intersect with the plurality of first electrodes to define a plurality of intersections; and an insulating layer sandwiched between one of the plurality of first electrodes and one of the plurality of second electrodes at each of the plurality of intersections, wherein each semiconductor layer is sandwiched between the insulating layer and the carbon nanotube layer. 2. The electron emission device of claim 1 , wherein the first direction is perpendicular to the second direction, and a portion of the plurality of first electrodes at each of the plurality of intersections is an electron emission surface. 3. The electron emission device of claim 1 , wherein each insulating layer at the plurality of intersections are in contact with each other to form a continuous structure. 4. The electron emission device of claim 1 , wherein each semiconductor layer in the plurality of first electrodes are spaced apart from each other. 5. The electron emission device of claim 1 , wherein the carbon nanotube layer comprises a first surface and a second surface opposite to the first surface, and the semiconductor layer is attached on the second surface. 6. The electron emission device of claim 5 , wherein the carbon nanotube layer comprises a plurality of carbon nanotubes, and the semiconductor layer is coated on the plurality of carbon nanotubes exposed from the second surface. 7. The electron emission device of claim 5 , wherein the semiconductor layer is attached on the second surface via van der Waals force. 8. The electron emission device of claim 5 , wherein a plurality of through holes are defined in the carbon nanotube layer, and the semiconductor layer extends into the plurality of through holes. 9. The electron emission device of claim 1 , wherein the carbon nanotube layer is a free-standing structure. 10. The electron emission device of claim 1 , wherein the carbon nanotube layer comprises a plurality of carbon nanotubes joined end to end by van der Waals force. 11. The electron emission device of claim 1 , wherein the carbon nanotube layer comprises a carbon nanotube film or a carbon nanotube wire. 12. The electron emission device of claim 1 , further comprising an electron collection layer sandwiched between each semiconductor layer and the insulating layer. 13. The electron emission device of claim 12 , wherein a material of the electron collection layer is selected from the group consisting of gold, platinum, scandium, palladium, hafnium, carbon nanotube, and graphene. 14. The electron emission device of claim 12 , wherein the electron collection layer comprises a carbon nanotube film. 15. The electron emission device of claim 14 , wherein the carbon nanotube film is a free-standing structure. 16. The electron emission device of claim 12 , wherein the electron collection layer comprises a graphene layer. 17. The electron emission device of claim 12 , wherein a thickness of the electron collection layer range from about 0.1 nanometers to about 10 nanometers. 18. An electron emission display, comprising: a substrate; an electron emission device on the substrate, wherein the electron emission device comprises: a plurality of first electrodes substantially parallel to each other, wherein each of the plurality of first electrodes comprises a carbon nanotube composite structure comprising a carbon nanotube layer and a semiconductor layer coated on the carbon nanotube layer; a plurality of second electrodes substantially parallel to each other, wherein the plurality of second electrodes intersect with the plurality of first electrodes to define a plurality of intersections; and an insulating layer sandwiched between one of the plurality of first electrodes and one of the plurality of second electrodes at each of the plurality of intersections, wherein each semiconductor layer is sandwiched between the insulating layer and the carbon nanotube layer; an anode structure spaced from the electron emission device, wherein the anode structure comprises an anode and a phosphor layer coated on the anode, and the phosphor layer faces to the plurality of first electrodes. 19. The electron emission device of claim 18 , wherein the phosphor layer faces to each carbon nanotube layer in the plurality of first electrodes.
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