Method of preparing core-shell structured nanoparticle having hard-soft magnetic heterostructure

Patent metadata

Field	Value
Publication number	US-9362034-B2
Application number	US-201314348507-A
Country	US
Kind code	B2
Filing date	Jan 9, 2013
Priority date	Feb 3, 2012
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

The present invention relates to a core-shell structured nanoparticle having hard-soft heterostructure, magnet prepared from the nanoparticle, and preparing method thereof. The core-shell structured nanoparticle having hard-soft magnetic heterostructure of present invention has some merits such as independence from resource supply problem of rare earth elements and low price and can overcome physical and magnetic limitations possessed by the conventional ferrite mono-phased material.

First claim

The invention claimed is:

1. A method of preparing a core-shell structured nanoparticle having hard-soft heterostructure by using a sol-gel method, which comprises the following steps:
(i) obtaining a solution of slurry state comprising ferrite nanopowder and at least one selected from metal complex compound, metal salt, metal compound and metal nanoparticle;
(ii) altering the solution into a viscous gel by evaporating its solvent; and
(iii) forming a nanoparticle by heating the gel.

2. A method of preparing a core-shell structured nanoparticle having hard-soft heterostructure by using a reverse micelle method, which comprises the following steps:
(i) obtaining and mixing a solution comprising metal salt, ferrite nanopowder, surfactant, hydrocarbon as a non-polar solvent, and distilled water; and
(ii) forming a nanoparticle by drying the solution rapidly.

3. The method according to claim 1 , further comprising performing thermal reduction of the prepared nanoparticle when a shell of the prepared nanoparticle is composed of a metal compound.

4. The method according to claim 1 , wherein the solution of slurry state comprises ferrite nanopowder and at least one metal complex compound selected from iron-oleate (Fe-oleate) and iron-dodecanoate (Fe-dodecanoate).

5. The method according to claim 2 , wherein the surfactant is at least one selected from sodium bis(2-ethylhexyl) sulfosuccinate, polyoxyethylene nonylphenyl ether, nonyl phenol ethosylate, and sodium dioctylsulfosuccinate.

6. The method according to claim 2 , wherein the hydrocarbon is at least one selected from cyclohexane, trimethylpentane including isooctane, heptanes, octane, decane, carbon tetrachloride, and benzene.

7. A method of preparing a sintered magnet, comprising the following steps:
(i) performing magnetic field molding of the core-shell structured nanoparticle having hard-soft magnetic heterostructure; and
(ii) sintering the molded body,
wherein the core-shell structured nanoparticle is one where a soft magnetic shell surrounds a hard magnetic core, which comprises at least one ferrite selected from barium ferrite, strontium ferrite, and cobalt ferrite, and
wherein the steps of (i) and (ii) are carried out simultaneously.

Assignees

• Lg Electronics Inc
• Univ Sogang Ind Univ Coop Foun

Inventors

• Kim Jongryoul
• Kim Jinbae
• Kang Namseok
• Cho Sanggeun

Classifications

• H01F1/08 Primary

  pressed, sintered, or bound together · CPC title

• H01F1/0579

  with exchange spin coupling between hard and soft nanophases, e.g. nanocomposite spring magnets · CPC title

• H01F1/113

  in a bonding agent · CPC title

• H01F1/0315 Primary

  Ferrites · CPC title

• H01F41/0266

  Moulding; Pressing (H01F41/0273 takes precedence; hard magnetic particles H01F1/06, H01F1/11) · CPC title