Novel biobased polyester
US-2024327659-A1 · Oct 3, 2024 · US
US9359525B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9359525-B2 |
| Application number | US-201013520124-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 28, 2010 |
| Priority date | Dec 31, 2009 |
| Publication date | Jun 7, 2016 |
| Grant date | Jun 7, 2016 |
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Water-free composition comprising at least one saturated or unsaturated, epoxy-modified polyester as binder, at least one acrylate polymer or polyurethane polymer as further binder, polymer microparticles, at least one polymer which comprises functional groups consisting of blocked isocyanates and amino resins, as crosslinking agent, at least one pigment, at least one organic solvent, and at least one auxiliary or additive, the solids of the composition being at least 50% by weight.
Opening claim text (preview).
What is claimed is: 1. A water-free coating composition comprising: a. a binder comprising at least one saturated or unsaturated, epoxy-modified polyester; b. a further binder comprising at least on acrylate polymer or polyurethane polymer; c. polymer microparticles; d. a crosslinking agent comprising at least one polymer comprising functional groups selected from the group consisting of blocked isocyanates and amino resins; e. at least one pigment; f. at least one organic solvent; and g. at least one auxiliary additive; wherein the solids of the composition are at least 50% by weight and the coating composition is water-free. 2. The water-free coating composition of claim 1 , wherein the polyester is present with a fraction of 5% to 20% by weight, based on the total weight of the composition, and the weight fractions of all of the constituents add up to 100% by weight. 3. The water-free coating composition of claim 2 , wherein the composition comprises b. 5% to 30% by weight of at least one acrylate polymer or polyurethane polymer as further binder, c. 5% to 20% by weight of polymer microparticles, d. 5% to 15% by weight of at least one polymer which comprises functional groups selected from the group consisting of blocked isocyanates and amino resins, as crosslinking agent, e. 5% to 49.5% by weight of at least one pigment, f. 30% to 50% by weight of at least one organic solvent, and g. 0.5% to 40% by weight of at least one auxiliary or additive, based in each case on the total weight of the composition. 4. The water-free coating composition of claim 1 , wherein the polyester has a weight-average molecular weight of 5000 to 20 000 g/mol. 5. The water-free coating composition of claim 1 , wherein the fraction of epoxy groups in the polyester is 5% to 15% by weight, based on the total weight of the polyester. 6. The water-free coating composition of claim 1 , having a viscosity which corresponds to a flow time of 24 s to 30 s from a Ford 4 Cup at 23° C. 7. A process of coating a substrate, the process comprising applying the water-free coating composition of claim 1 to a substrate as a coating material. 8. The process of claim 7 , wherein the coating material is used for producing a functional layer in a multicoat paint system, the multicoat paint system comprising a. at least one functional layer A, obtained from the water-free coating composition, b. at least one basecoat B of at least one basecoat material, and c. at least one clearcoat C of at least one clearcoat material. 9. A multicoat paint system comprising a. at least one functional layer A, obtained from the water-free coating composition of claim 1 , b. at least one basecoat B of at least one basecoat material, and c. at least one clearcoat C of at least one clearcoat material. 10. The multicoat paint system of claim 9 , wherein successively first functional layer A, then basecoat B, and subsequently clearcoat C are applied to a substrate and then functional layer A, basecoat B, and clearcoat C are jointly cured. 11. The multicoat paint system of claim 9 , wherein first layer A is applied to a substrate and cured and thereafter basecoat B and finally clearcoat C are applied to the substrate, and basecoat B and clearcoat C are then jointly cured. 12. A method of producing the multicoat paint system of claim 9 , the method comprising applying the water-free coating composition to a substrate, subsequently applying the at least one basecoat B, and then applying the at least one clearcoat C. 13. The method of claim 12 , wherein the water-free coating composition and also the basecoat B and the clearcoat C are jointly cured. 14. A method of coating a substrate, the method comprising applying the multicoat paint system of claim 9 to a substrate. 15. A substrate coated with the water-free coating composition of claim 1 . 16. A substrate coated with the multicoat paint system of claim 9 .
first layer from the substrate side · CPC title
with melamine · CPC title
from polyesters · CPC title
Acrylic polymers · CPC title
Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] · CPC title
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