Non-aqueous compositions of dispersed carbon-coated metal particles

Patent metadata

Field	Value
Publication number	US-9359517-B2
Application number	US-201414514463-A
Country	US
Kind code	B2
Filing date	Oct 15, 2014
Priority date	Oct 15, 2014
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

A non-aqueous composition contains dispersed carbon-coated metal particles in an organic diluent in an amount of at least 10 weight %. The dispersed carbon-coated metal particles have a median diameter equal to or less than 0.6 μm, and are dispersed using a particle dispersing agent that has a weight average molecular weight (M w ) of at least 2,000 and up to and including 100,000 and comprises nitrogen-containing units. The median diameter of the dispersed particles is determined using a dynamic light scattering method. Moreover, when the non-aqueous composition contains up to and including 25 weight % of the dispersed carbon-coated metal particles, it exhibits no visual settling when subjected to a settling test of at least 24 hours at 20° C. Such non-aqueous compositions can include photocurable components and are useful to prepare photocurable and photocured electrically-conductive patterns and layers in various articles, including touch screen devices having touch screen displays.

First claim

The invention claimed is:

1. A non-aqueous composition comprising dispersed carbon-coated non-magnetic metal particles in an organic diluent in an amount of at least 10 weight % based on the total weight of the non-aqueous composition, the dispersed carbon-coated non-magnetic metal particles having a median diameter equal to or less than 0.6 μm, and being dispersed with a particle dispersing agent that has a weight average molecular weight (M w ) of at least 2,000 and up to and including 100,000 and comprises nitrogen-containing units, the median diameter being determined using a dynamic light scattering method,
wherein, when the non-aqueous composition contains up to and including 25 weight % of the dispersed carbon-coated non-magnetic metal particles, it exhibits no visual settling when subjected to a settling test of at least 24 hours at 20° C.

2. The non-aqueous composition of claim 1 , wherein the dispersed carbon-coated non-magnetic metal particles are dispersed carbon-coated silver particles or dispersed carbon-coated copper particles, or a mixture of both dispersed carbon-coated silver particles and dispersed carbon-coated copper particles.

3. The non-aqueous composition of claim 1 , wherein the weight ratio of the particle dispersing agent to the dispersed carbon-coated non-magnetic metal particles is at least 1:100 and up to and including 30:100.

4. The non-aqueous composition of claim 1 , wherein the dispersed carbon-coated non-magnetic metal particles are present in an amount of at least 15 weight % and up to and including 70 weight %, based on the total weight of the non-aqueous composition.

5. The non-aqueous composition of claim 1 , wherein the particle dispersing agent has an M w of at least 2,000 and up to and including 50,000.

6. The non-aqueous composition of claim 1 , further comprising dispersed carbon black in an amount of up to and including 20 weight %, based on the total weight of the non-aqueous composition.

7. The non-aqueous composition of claim 1 , wherein the particle dispersing agent is an organic polymer comprising ester units.

8. The non-aqueous composition of claim 1 , wherein the particle dispersing agent is an organic polymer that comprises units chosen from at least one of the following classes (i) through (iv):
(i) pyridine units;
(ii) imine units;
(iii) imide units; and
(iv) amine units.

9. The non-aqueous composition of claim 1 , wherein the dispersed carbon-coated non-magnetic metal particles are dispersed carbon-coated silver particles that are present at a concentration is at least 15 weight % and up to and including 60 weight % based on the total weight of the non-aqueous composition, and the dispersed carbon-coated silver particles have a median diameter of less than 0.5 μm as determined using a dynamic light scattering method.

10. The non-aqueous composition of claim 1 further comprising a photocurable component.

11. The non-aqueous composition of claim 1 , wherein the organic diluent is an organic solvent medium that comprises at least one of 2-ethoxyethanol, 2-(2-methoxyethoxy)ethanol, 2-(2-ethoxyethoxy)ethanol, 1-methoxy-2-propanol, 4-heptanone, 3-heptanone, 2-heptanone, cyclopentanone, cyclohexanone, diethyl carbonate, 2-ethoxyethyl acetate, N-butyl butyrate, and methyl lactate.

12. A non-aqueous photocurable composition comprising:
dispersed carbon-coated non-magnetic metal particles in an amount of at least 10 weight % based on the total weight of the non-aqueous photocurable composition, and the dispersed carbon-coated non-magnetic metal particles having a median diameter equal to or less than 0.6 μm, and being dispersed with a particle dispersing agent that has a weight average molecular weight (M W ) of at least 2,000 and up to and including 100,000 and comprises nitrogen-containing units, the median diameter being determined using a dynamic light scattering method,
an organic diluent,
a UV-curable component, and
if needed, a UV photoinitiator,
wherein, when the non-aqueous photocurable composition contains up to and including 25 weight % of the dispersed carbon-coated non-magnetic metal particles, it exhibits no visual settling when subjected to a settling test of at least 24 hours at 20° C.

13. The non-aqueous photocurable composition of claim 12 , wherein the dispersed carbon-coated non-magnetic metal particles are dispersed carbon-coated silver particles or dispersed carbon coated-copper particles, or a mixture of both dispersed carbon-coated silver particles and dispersed carbon-coated copper particles.

14. The non-aqueous photocurable composition of claim 12 , wherein the dispersed carbon-coated non-magnetic metal particles are present in an amount of at least 15 weight % and up to and including 60 weight %, based on the total weight of the non-aqueous photocurable composition, and the dispersed carbon-coated non-magnetic metal particles have a median diameter of less than 0.5 μm as determined using a dynamic light scattering method.

15. The non-aqueous photocurable composition of claim 12 , further comprising dispersed carbon black in an amount of up to and including 20 weight %, based on the total weight of the non-aqueous photocurable composition.

16. The non-aqueous photocurable composition of claim 12 , wherein the particle dispersing agent is an organic polymer that comprises units chosen from at least one of the following classes (i) through (iv):
(i) pyridine units;
(ii) imine units;
(iii) imide units; and
(iv) amine units.

17. The non-aqueous photocurable composition of claim 12 , wherein the organic diluent is an organic solvent medium that comprises at least one of 2-ethoxyethanol, 2-(2-methoxyethoxy)ethanol, 2-(2-ethoxyethoxy)ethanol, 1-methoxy-2-propanol, 4-heptanone, 3-heptanone, 2-heptanone, cyclopentanone, cyclohexanone, diethyl carbonate, 2-ethoxyethyl acetate, N-butyl butyrate, and methyl lactate.

18. The non-aqueous photocurable composition of claim 12 , wherein the organic diluent comprises at least one UV-curable component.

19. The non-aqueous photocurable composition of claim 12 , wherein the UV-curable component is an acid-catalyzed photocurable component and the non-aqueous photocurable composition further comprises a photoacid generator.

20. The non-aqueous photocurable composition of claim 12 , wherein the UV-curable component is a free radically photocurable component, and the non-aqueous photocurable composition further comprises a free radical photoinitiator.

Assignees

• Kosydar Karen M
• Slater Gary L
• Brick Mary Christine
• Landry-Coltrain Christine Joanne
• Reczek James Albert
• Eastman Kodak Co

Inventors

• Kosydar Karen M
• Slater Gary L
• Brick Mary Christine
• Landry-Coltrain Christine Joanne
• Reczek James Albert

Classifications

• C09D179/08 Primary

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C09D179/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title

• C09D179/02

  Polyamines · CPC title

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title