Polymer composition having a filler content and coextruded sheet obtainable therefrom

Patent metadata

Field	Value
Publication number	US-9359489-B2
Application number	US-201214237063-A
Country	US
Kind code	B2
Filing date	Aug 7, 2012
Priority date	Aug 8, 2011
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

The present invention relates to a polymer composition containing polycarbonate with a weight-average molecular weight Mw of from 24,000 to 33,000 and 5.0 wt. % to 20.0 wt. % (based on the total amount of the composition) of glass hollow spheres with an alkalinity of less than 1.0 meq/g. The present invention furthermore provides coextruded sheets in which the coextruded layer contains this polymer composition, and shaped articles produced therefrom, in particular containers and pieces of luggage, very particularly suitcases. Sheets which are obtainable with the polymer composition according to the invention have a high mechanical stability, a high scratch resistance, pleasant haptic properties and an excellent homogeneous external visual impression. The present invention furthermore relates to a process for the preparation of these polymer compositions and a process for production of the sheets according to the invention.

First claim

The invention claimed is:

1. A polymer composition P) comprising a polycarbonate with a weight-average molecular weight Mw of from 24,000 to 33,000 and a melt volume rate of from 8 to 16 cm 3 /10 min, optionally a further polycarbonate with a weight-average molecular weight Mw of from 24,000 to 33,000, and 5.0 wt. % to 20.0 wt. % (based on the total amount of the composition) of glass hollow spheres with an alkalinity of less than 1.0 meq/g and additives, the polymer composition containing no further thermoplastic polymers.

2. The polymer composition according to claim 1 , wherein the additives are selected from at least one of the group of single-proton or multi-proton acids, heat or processing stabilizers, UV absorbers, phenolic antioxidants, mould release agents, antistatics, inorganic pigments, organic dyestuffs, flameproofing agents, IR absorbers and optical brighteners.

3. The polymer composition according to claim 1 , wherein the polymer contains the glass hollow spheres in an amount of from 8.0 wt. % to 15.0 wt. %.

4. The polymer composition according to claim 1 , wherein the glass hollow spheres have a compressive strength of from 500 bar to 2,500 bar.

5. The polymer composition according to claim 1 , wherein the composition contains 0.000 wt. % to 0.050 wt. % of a single-proton or multi-proton acid.

6. A process for the production of extruded sheets which comprises utilizing the polymer composition according to claim 1 to produce the extruded sheets.

7. A sheet comprising two layers A) and B), wherein layer A) contains a polymer composition according to claim 1 and layer B) contains polycarbonate with a melt volume rate (MVR) of from 3 to 9 cm 3 /10 min, wherein the polycarbonate in layer A) has a melt volume rate (MVR) of from 8 to 16 cm 3 /10 min.

8. The sheet according to claim 7 , wherein the thermoplastic in layer B) is a polycarbonate or copolycarbonate with an average molecular weight (weight-average) of from 26,000 to 33,000 g/mol.

9. The sheet according to claim 7 , wherein the layer thickness of layer A) is 50 μm to 300 μm and the layer thickness of the sheet comprising layer A) and B) is 1 mm to 8 mm and the sheet is produced by means of coextrusion.

10. A shaped article comprising the sheet according to claim 7 .

11. The shaped article according to claim 10 , wherein the article is a container or a piece of luggage.

12. A process for the preparation of the polymer composition P) according to claim 1 , which comprises mixing the polycarbonate with the glass hollow spheres on a twin-screw extruder, wherein the glass hollow spheres are introduced directly into the melt, which has a melt temperature of from 320° C. to 380° C. via a lateral intake, and the extruder speed is 300 rpm to 500 rpm and the polycarbonate has a melt volume rate (MVR) of from 8 to 16 cm 3 /10 min.

13. The process according to claim 12 , wherein the extruder speed is 360 to 500 rpm and the melt temperature of from 330° C. to 355° C.

Assignees

• Blaschke Ulrich
• Hähnsen Heinrich
• Schwarz Peter
• Kraner Klaus
• Thiem Hans-Jürgen
• Wagner Michael
• Covestro Deutschland Ag

Inventors

• Blaschke Ulrich
• Hähnsen Heinrich
• Schwarz Peter
• Kraner Klaus
• Thiem Hans-Jürgen
• Wagner Michael

Classifications

• C08K7/28 Primary

  Glass · CPC title

• B32B2305/30

  Fillers, e.g. particles, powders, beads, flakes, spheres, chips · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• Y10T428/24967

  Absolute thicknesses specified · CPC title

• C08K5/1345

  Carboxylic esters of phenolcarboxylic acids · CPC title