Applying biaxially oriented polyester onto a metal substrate

Patent metadata

Field	Value
Publication number	US-9358766-B2
Application number	US-201414271870-A
Country	US
Kind code	B2
Filing date	May 7, 2014
Priority date	Sep 13, 2005
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

The invention is a laminating process which is directed toward economical production methods for scalable amounts of production which develop properties suitable for a broad based product line. In particular, the product is capable of important key components of commercial properties such as adhesion, scratch resistance, chemical inertness, and bending without failure.

First claim

We claim:

1. A method of laminating a biaxially oriented polyester film onto a metal substrate to create desirable simultaneous commercial properties comprising:
a. creating a biaxially oriented polyester film on a film manufacturing line,
b. wherein said biaxially oriented polyester film has desirable commercial properties,
c. increasing the surface energy of at least one major side of said metal substrate to a bonding level on a metal lamination line,
d. preheating said metal substrate to at least 200° F.,
e. pressing said biaxially oriented polyester film onto said at least one major side by use of a roll,
f. thereby creating a metal polymer laminate,
g. wherein said biaxially oriented polyester film is primarily thermoplastic polyester by weight,
h. wherein said biaxially oriented polyester film comprises at least one layer,
i. wherein said biaxially oriented polyester film comprises at least one of PET, PBT, PETG, and PETI,
j. post treating said metal polymer laminate by heating said metal polymer laminate to at least a bonding temperature of said biaxially oriented polyester film to said metal substrate, wherein said bonding temperature is below a melting temperature of a layer of said biaxially oriented polyester film that is contacting said metal substrate,
k. wherein said post treating of said metal polymer laminate preserves crystallinity in said biaxially oriented film according to a predetermined criterion, and
l. cooling said metal polymer laminate,
whereby said metal polymer laminate has said desirable simultaneous commercial properties after said cooling comprising:
m. bonding of said biaxially oriented polyester film onto said metal substrate of at least 43 ounces per inch,
n. a pencil hardness of at least 2B, and
o. successfully passing metal can pack testing for at least thirty days.

2. The processing steps according to claim 1 wherein any said bond between said biaxially oriented polyester film and said metal substrate is created by use of an amorphous polyester.

3. The processing steps according to claim 2 wherein said bond between said biaxially oriented polyester film and said metal substrate is created by use of a PETI or PETG in a film layer in contact with said metal substrate.

4. The processing steps according to claim 1 wherein any said biaxially oriented polyester film is trimmed to substantially match the width of said metal substrate prior to being pressed against said metal substrate.

5. The processing steps according to claim 1 wherein said metal lamination line is either a continuous operation or a batch operation.

Assignees

• Toray Plastics America Inc
• Velliky James E
• Loen Mark V

Inventors

• Loen Mark V
• Velliky James E
• Moritz Jan K

Classifications

• B32B2307/406

  Bright, glossy, shiny surface · CPC title

• B32B27/36

  comprising polyesters · CPC title

• B32B2310/0445

  using gas or flames (B32B2310/0427 takes precedence) · CPC title

• B32B2305/30

  Fillers, e.g. particles, powders, beads, flakes, spheres, chips · CPC title

• B32B2307/714

  Inert, i.e. inert to chemical degradation, corrosion · CPC title