X-ray imaging panel with thermally-sensitive adhesive and methods of making thereof
US-9223034-B2 · Dec 29, 2015 · US
US9358763B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9358763-B2 |
| Application number | US-201214233025-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 13, 2012 |
| Priority date | Jul 15, 2011 |
| Publication date | Jun 7, 2016 |
| Grant date | Jun 7, 2016 |
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Provided is a method of manufacturing a translucent rigid substrate laminate, which method can improve position precision while increasing production efficiency. Further provided is a translucent rigid substrate bonding apparatus that contributes to improvement of the position precision while increasing production efficiency of a plate-shaped product. In the method of manufacturing a translucent rigid substrate laminate and the translucent rigid substrate bonding apparatus according to the present invention, when translucent rigid substrates are bonded in a predetermined positional relationship by interposing a photo-curable fixing agent including (A) polyfunctional (meth)acrylate, (B) monofunctional (meth)acrylate and (C) a photopolymerization initiator therebetween, only the fixing agent present in outer peripheral portions of both translucent rigid substrates is cured for provisional fastening.
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What is claimed is: 1. A method of manufacturing a translucent rigid substrate laminate, comprising: 1) a process of preparing a first translucent rigid substrate; 2) a process of preparing a second translucent rigid substrate; 3) a process of applying a photo-curable fixing agent including (A) polyfunctional (meth)acrylate, (B) monofunctional (meth)acrylate and (C) a photopolymerization initiator to a first surface of the first translucent rigid substrate and/or a first surface of the second translucent rigid substrate; 4) a process of allowing the first surface of the first translucent rigid substrate and the first surface of the second translucent rigid substrate to face each other so that the both surfaces are parallel to each other in a predetermined positional relationship in a surface direction; 5) a process of applying a given pressure to the first surface of the first translucent rigid substrate and the first surface of the second translucent rigid substrate while maintaining the positional relationship to bond the both translucent rigid substrates; 6) a process of irradiating light for curing only an outer peripheral portion of the fixing agent spreading between the both translucent rigid substrates to form a provisionally fastened translucent rigid substrate laminate; 7) a full fastening process of curing the uncured fixing agent present in the provisionally fastened translucent rigid substrate laminate to form a fully fastened translucent rigid substrate laminate; and 8) a process of repeating the processes 1) to 7) at least once by regarding the fully fastened translucent rigid substrate laminate as the first translucent rigid substrate to form a fully fastened translucent rigid substrate laminate in which at least three translucent rigid substrates are bonded, and wherein the full fastening process 7) is a stand-still process of allowing the uncured fixing agent present in the provisionally fastened translucent rigid substrate laminate to stand for curing to form the fully fastened translucent rigid substrate laminate. 2. A method of manufacturing a plate-shaped product, comprising: 9) a process of dividing a translucent rigid substrate laminate obtained by using the method according to claim 1 in a thickness direction to form a desired number of divided translucent rigid substrate laminates; 10) a process of performing desired shape processing on each of the divided translucent rigid substrate laminates; and 11) a process of heating the divided translucent rigid substrate laminate after the shape processing to delaminate the bonded divided translucent rigid substrates from each other and form a plurality of plate-shaped products. 3. The method of manufacturing a plate-shaped product according to claim 2 , further comprising: a process of bringing the divided translucent rigid substrate laminates into contact with a delaminating agent under temperature and time conditions required to reduce adhesion strength of an exposed portion of the outer edge of the fixing agent interposed between the divided translucent rigid substrates between the processes 9) and 10). 4. The method of manufacturing a translucent rigid substrate laminate according to claim 1 , wherein the light is spot-irradiated to the outer peripheral portion of the fixing agent spreading between the both translucent rigid substrates only at two to six positions in the process 6) of forming the provisionally fastened translucent rigid substrate laminate. 5. The method of manufacturing a translucent rigid substrate laminate according to claim 1 , wherein the process 6) of forming the provisionally fastened translucent rigid substrate laminate is a process of irradiating light for curing only the outer peripheral portion of the fixing agent spreading between the both translucent rigid substrates while maintaining the pressure to form the provisionally fastened translucent rigid substrate laminate. 6. A method of manufacturing a translucent rigid substrate laminate, comprising: 1) a process of preparing a first translucent rigid substrate; 2) a process of preparing a second translucent rigid substrate; 3) a process of applying a photo-curable fixing agent including (A) polyfunctional (meth)acrylate, (B) monofunctional (meth)acrylate and (C) a photopolymerization initiator to a first surface of the first translucent rigid substrate and/or a first surface of the second translucent rigid substrate; 4) a process of allowing the first surface of the first translucent rigid substrate and the first surface of the second translucent rigid substrate to face each other so that the both surfaces are parallel to each other in a predetermined positional relationship in a surface direction; 5) a process of applying a given pressure to the first surface of the first translucent rigid substrate and the first surface of the second translucent rigid substrate while maintaining the positional relationship to bond the both translucent rigid substrates; 6) a process of irradiating light for curing only an outer peripheral portion of the fixing agent spreading between the both translucent rigid substrates to form a provisionally fastened translucent rigid substrate laminate; 7′) a process of repeating the processes 1) to 6) at least once by regarding the provisionally fastened translucent rigid substrate laminate as the first translucent rigid substrate to form a provisionally fastened translucent rigid substrate laminate in which at least three translucent rigid substrates are bonded; and 8′) a full fastening process of curing the uncured fixing agent present in the provisionally fastened translucent rigid substrate laminate obtained in the process 7′) to form a fully fastened translucent rigid substrate laminate, and wherein the full fastening process 8′) is a stand-still process of allowing the uncured fixing agent present in the provisionally fastened translucent rigid substrate laminate obtained in the process 7′) to stand for curing to form the fully fastened translucent rigid substrate laminate. 7. The method of manufacturing a translucent rigid substrate laminate according to claim 6 , further comprising: 8″) a process of repeating the processes 1) to 6) at least once by regarding the fully fastened translucent rigid substrate laminate obtained in the process 8′) as the first translucent rigid substrate to form a complex translucent rigid substrate laminate; and 8′″) a full fastening process of curing the uncured fixing agent present in the complex translucent rigid substrate laminate obtained in the process 8″) to form a fully fastened translucent rigid substrate laminate having an increased lamination number. 8. The method of manufacturing a translucent rigid substrate laminate according to claim 7 , wherein the full fastening process 8′″) is an irradiation process of irradiating light for curing the uncured fixing agent present in the complex translucent rigid substrate laminate obtained in the process 8″) to form the fully fastened translucent rigid substrate laminate having the increased lamination number. 9. The method of manufacturing a translucent rigid substrate laminate according to claim 7 , wherein the full fastening process 8′″) is a stand-still process of allowing the uncured fixing agent present in the complex translucent rigid substrate laminate obtained in the process 8″) to stand to form the fully fastened translucent rigid substrate laminate having the increased lamination number. 10. The method of manufacturing a translucent rigid substrate laminate according to claim 6 , wherein the light is spot-irradiated to the outer peripheral portion of the fixing agent spreading between the both translucent rigid substrates only at
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