Structured film containing beta-nucleating agent and method of making the same

Patent metadata

Field	Value
Publication number	US-9358714-B2
Application number	US-201113324130-A
Country	US
Kind code	B2
Filing date	Dec 13, 2011
Priority date	Dec 13, 2011
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

A structured film of a semi-crystalline polyolefin and a beta-nucleating agent is disclosed. The structured film has a backing and upstanding posts attached to the backing. At least a portion of the film typically includes beta-spherulites. In some embodiments, the backing is microporous while the upstanding posts have lower porosity. A method of making a structured film is also disclosed. The method includes extruding a melt of a polyolefin and a beta-nucleating agent in the presence of a tool to provide the structured film having upstanding posts on a backing and cooling at least a portion of the structured film to a temperature sufficient to form beta-spherulites. In some embodiments, the method further includes stretching the structured film containing beta-spherulites to provide micropores in the backing.

First claim

What is claimed is:

1. A structured film comprising a semi-crystalline polyolefin and a beta-nucleating agent, the structured film comprising a backing and upstanding posts attached to the backing, wherein the backing has a length dimension, a width dimension, and a thickness dimension, wherein the thickness dimension is the smallest dimension, wherein the backing has a first surface having the length dimension and the width dimension, and wherein the upstanding posts have base portions attached to the first surface of the backing and free ends distal from the backing.

2. The structured film of claim 1 , wherein the backing is microporous, and wherein the upstanding posts have lower porosity than the backing.

3. The structured film of claim 1 , wherein the backing has a greater opacity than the upstanding posts.

4. The structured film of claim 1 , wherein the semi-crystalline polyolefin is substantially free of cavitating agents and substantially free of diluents that phase separate below a melting temperature of the semi-crystalline polyolefin.

5. The structured film of claim 1 , wherein the semi-crystalline polyolefin comprises at least one of propylene homopolymer, a copolymer of propylene and other olefins, or a blend of a polypropylene homopolymer and a different polyolefin.

6. The structured film of claim 1 , further comprising a colorant.

7. The structured film of claim 1 , wherein the structured film is a mechanical fastener.

8. The structured film of claim 1 , wherein the structured film is a coextruded film having side-by-side first and second lanes, wherein the first lanes comprise the semi-crystalline polyolefin and the beta-nucleating agent, and wherein the second lanes comprise a different polymer composition.

9. A structured film of a semi-crystalline polyolefin comprising a backing and upstanding posts attached to the backing, wherein the backing has a length dimension, a width dimension, and a thickness dimension, wherein the thickness dimension is the smallest dimension, wherein the backing has a first surface having the length dimension and the width dimension, wherein the upstanding posts have base portions attached to the first surface of the backing and free ends distal from the backing, and wherein at least the upstanding posts comprise beta-spherulites of the semi-crystalline polyolefin.

10. The structured film of claim 9 , wherein the backing is microporous, and wherein the upstanding posts have lower porosity than the backing.

11. The structured film of claim 9 , wherein the backing has a greater opacity than the upstanding posts.

12. The structured film of claim 9 , wherein the semi-crystalline polyolefin is substantially free of cavitating agents and substantially free of diluents that phase separate below a melting temperature of the semi-crystalline polyolefin.

13. The structured film of claim 9 , wherein the semi-crystalline polyolefin comprises at least one of propylene homopolymer, a copolymer of propylene and other olefins, or a blend of a polypropylene homopolymer and a different polyolefin.

14. The structured film of claim 9 , further comprising a colorant.

15. A method of making the structured film of claim 1 , the method comprising:
extruding a melt of a polyolefin and a beta-nucleating agent in the presence of a tool to provide the structured film having upstanding posts on a backing; and
cooling at least a portion of the structured film to a temperature sufficient to form beta-spherulites.

16. The method of claim 15 , further comprising stretching the structured film containing beta-spherulites to provide porosity in the backing.

17. The method of claim 16 , wherein the stretching is carried out at a temperature in a range from 50° C. to 90° C.

18. The method of claim 16 , wherein the stretching is monoaxial.

19. The method of claim 16 , wherein stretching is carried out to provide a total stretch ratio of up to 3:1.

20. The method of claim 16 , wherein the stretching provides an increase in opacity of at least 15 percent.

Assignees

• Chandrasekaran Neelakandan
• 3M Innovative Properties Co

Inventors

• Chandrasekaran Neelakandan

Classifications

• Y10T428/24612

  Composite web or sheet · CPC title

• B32B27/08

  of synthetic resin · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B2274/00

  Thermoplastic elastomer material · CPC title

• B29K2105/04

  cellular or porous · CPC title