Exhaust gas purification catalyst and production method thereof

Patent metadata

Field	Value
Publication number	US-9358527-B2
Application number	US-201214412132-A
Country	US
Kind code	B2
Filing date	Jul 9, 2012
Priority date	Jul 9, 2012
Publication date	Jun 7, 2016
Grant date	Jun 7, 2016

Abstract

An exhaust gas purification catalyst of the present invention includes a catalyst support and a plurality of bimetallic particles supported thereon wherein the bimetallic particles consist of gold and cobalt and have an average particle size of greater than 0 nm but 100 nm or less. A method of the present invention includes heating a mixed solution containing a gold salt, a cobalt salt, a solvent and an inorganic reducing agent to a temperature sufficient to reduce gold and cobalt, thereby producing bimetallic particles consisting of gold and cobalt, and supporting the produced bimetallic particles on the catalyst support.

First claim

The invention claimed is:

1. An exhaust gas purification catalyst, comprising a catalyst support and a plurality of bimetallic particles supported thereon, wherein said bimetallic particles consist of gold and cobalt and have an average particle size of greater than 0 nm but 100 nm or less.

2. The exhaust gas purification catalyst as claimed in claim 1 , wherein when said exhaust gas purification catalyst is analyzed using a scanning transmission electron microscope equipped with an energy dispersive X-ray analyzer (STEM-EDX) under condition in which the spot size of an electron beam is 1 nm or less, both gold and cobalt elements are detected at a majority of measurement points for randomly selected 5 or more metal particles.

3. The exhaust gas purification catalyst as claimed in claim 2 , wherein when said exhaust gas purification catalyst is analyzed using a scanning transmission electron microscope equipped with an energy dispersive X-ray analyzer (STEM-EDX) under condition in which the spot size of an electron beam is 1 nm or less, both gold and cobalt elements are detected at 70% or more of measurement points for randomly selected 10 or more metal particles.

4. The exhaust gas purification catalyst as claimed in claim 1 , wherein said bimetallic particles have an average particle size of greater than 0 nm but 20 nm or less.

5. The exhaust gas purification catalyst as claimed in claim 4 , wherein said bimetallic particles have an average particle size of greater than 0 nm but 10 nm or less.

6. The exhaust gas purification catalyst as claimed in claim 1 , wherein said bimetallic particles have an average gold content of greater than 0 atomic % but 70 atomic % or less.

7. The exhaust gas purification catalyst as claimed in claim 6 , wherein said bimetallic particles have an average gold content of 5 atomic % or more but 50 atomic % or less.

8. The exhaust gas purification catalyst as claimed in claim 7 , wherein said bimetallic particles have an average gold content of 10 atomic % or more but 25 atomic % or less.

9. A method for producing an exhaust gas purification catalyst comprising a catalyst support and a plurality of bimetallic particles supported thereon wherein said bimetallic particles consist of gold and cobalt and have an average particle size of greater than 0 nm but 100 nm or less, wherein said method comprises:
heating a mixed solution containing a gold salt, a cobalt salt, a solvent and an inorganic reducing agent to a temperature sufficient to reduce gold and cobalt, thereby producing bimetallic particles consisting of gold and cobalt, and
supporting the produced bimetallic particles on the catalyst support.

10. The method as claimed in claim 9 , wherein when said exhaust gas purification catalyst is analyzed using a scanning transmission electron microscope equipped with an energy dispersive X-ray analyzer (STEM-EDX) under condition in which the spot size of an electron beam is 1 nm or less, both gold and cobalt elements are detected at a majority of measurement points for randomly selected 5 or more metal particles.

11. The method as claimed in claim 10 , wherein when said exhaust gas purification catalyst is analyzed using a scanning transmission electron microscope equipped with an energy dispersive X-ray analyzer (STEM-EDX) under condition in which the spot size of an electron beam is 1 nm or less, both gold and cobalt elements are detected at 70% or more of measurement points for randomly selected 10 or more metal particles.

12. The method as claimed in claim 9 , wherein said bimetallic particles have an average particle size of greater than 0 nm but 20 nm or less.

13. The method as claimed in claim 12 , wherein said bimetallic particles have an average particle size of greater than 0 nm but 10 nm or less.

14. The method as claimed in claim 9 , wherein said heating step is performed at a temperature of 90° C. or more but 250° C. or less.

15. The method as claimed in claim 14 , wherein said heating step is performed at a temperature of greater than 100° C. but 200° C. or less.

16. The method as claimed in claim 9 , wherein said solvent is selected from the group consisting of tetraethylene glycol, ethylene glycol, n-propyl alcohol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, glycerin, propylene glycol, isoamyl alcohol, n-amyl alcohol, allyl alcohol, 2-ethoxy alcohol, 1,2-hexadecanediol, dimethylformamide, and combinations thereof.

17. The method as claimed in claim 9 , wherein said inorganic reducing agent is selected from the group consisting of sodium borohydride, ammonia borane, hydrazine, and combinations thereof.

18. The method as claimed in claim 17 , wherein said inorganic reducing agent is sodium borohydride.

19. The method as claimed in claim 9 , wherein said mixed solution further contains a protecting agent.

20. The method as claimed in claim 9 , further comprising a reduction step after said supporting step.

Assignees

• Nagata Naoto
• Hirata Hirohito
• Ono Kimiyasu
• Toyota Motor Co Ltd

Inventors

• Nagata Naoto
• Hirata Hirohito
• Ono Kimiyasu

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title