Electrode body, method for producing electrode body, and battery provided with electrode body

Patent metadata

Field	Value
Publication number	US-9356279-B2
Application number	US-201313956608-A
Country	US
Kind code	B2
Filing date	Aug 1, 2013
Priority date	Aug 3, 2012
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

In a (001) pole figure of the active material particles, where a plane parallel to the substrate is defined as the equatorial plane, a Lotgering factor f a (001) of an A plane and a Lotgering factor f h (001) of a B plane satisfy both Expressions (1) and (2) below, the A plane being an equatorial cross section perpendicular to a line that connects the center of the (001) pole figure and a first point of maximum XRD intensity of peaks attributed to (001) planes at the outer periphery of the equatorial plane, the B plane being an equatorial cross section perpendicular to a line that connects the center of the (001) pole figure and a second point of minimum XRD intensity of peaks attributed to the (001) planes at the outer periphery of the equatorial plane:

f a (001)>0.3   Expression (1)

f a (001)− f b (001)<1.0   Expression (2).

First claim

What is claimed is:

1. An electrode body, comprising:
a substrate; and
an orientation layer that is provided on at least one surface of the substrate, and includes active material particles having a crystal structure exhibiting highest ion conductivity in a direction perpendicular to a <001> direction, wherein:
in a (001) pole figure of the active material particles, where a plane parallel to the substrate is defined as an equatorial plane, a Lotgering factor f a (001) of an A plane and a Lotgering factor f b (001) of a B plane satisfy both Expressions (1) and (2) below, the A plane being an equatorial cross section perpendicular to a line that connects a center of the (001) pole figure and a first point of maximum XRD intensity of peaks attributed to (001) planes at an outer periphery of the equatorial plane, the B plane being an equatorial cross section perpendicular to a line that connects the center of the (001) pole figure and a second point of minimum XRD intensity of peaks attributed to the (001) planes at the outer periphery of the equatorial plane:
f a (001)>0.3   Expression (1)

f a (001)- f b (001)<1.0   Expression (2).

2. The electrode body according to claim 1 , wherein the active material particles are at least one type of active material particles selected from the group consisting of lithium cobalt oxide (LiCoO 2 ) particles, lithium nickel oxide (LiNiO 2 ) particles, lithium nickel manganese oxide (LiNi 1/2 Mn 1/2 O 2 ) particles and lithium nickel manganese cobalt oxide (LiNi 1/3 Mn 1/3 Co 1/3 O 2 ) particles.

3. The electrode body according to claim 1 , wherein
the electrode body is a positive electrode or negative electrode of a lithium battery.

4. A battery, comprising:
a positive electrode;
a negative electrode; and
an electrolyte layer interposed between the positive electrode and the negative electrode,
wherein at lest either one of the positive electrode and the negative electrode is provided with the electrode body according to claim 1 .

5. A method for producing an electrode body, comprising:
preparing a substrate and active material particles having a crystal structure that exhibits highest ion conductivity in a direction perpendicular to a <001> direction; and
layering a layer including the active material particles onto the substrate while applying a magnetic field in a direction substantially parallel to the substrate, and relatively rotating the direction of the magnetic field with respect to the substrate about an axis that is substantially perpendicular to the substrate, to thereby produce an electrode body in which the substrate has formed thereon an orientation layer configured such that, in a (001) pole figure relating to the active material particles, where a plane parallel to the substrate is defined as an equatorial plane, a Lotgering factor f a (001) of an A plane and a Lotgering factor f b (001) of a B plane satisfy both Expressions (1) and (2) below, the A plane being an equatorial cross section perpendicular to a line that connects a center of the (001) pole figure and a first point of maximum XRD intensity of peaks attributed to (001) planes at an outer periphery of the equatorial plane, the B plane being an equatorial cross section perpendicular to a line that connects the center of the (001) pole figure and a second point of minimum XRD intensity of peaks attributed to the (001) planes at the outer periphery of the equatorial plane:
f a (001)>0.3   Expression (1)

f a (001)− f b (001)<1.0   Expression (2).

6. The method for producing an electrode body according to claim 5 , wherein the electrode body is heated after being produced.

7. The method for producing an electrode body according to claim 5 , wherein the electrode body is produced by slipcasting.

8. The method for producing an electrode body according to claim 5 , wherein the electrode body is a positive electrode or negative electrode of a lithium battery.

Assignees

• Hozumi masato
• Saito Toshiya
• Yamada Hideto
• Suzuki Tohru
• Uchikoshi Tetsuo
• Sakka Yoshio
• Toyota Motor Co Ltd
• Nat Inst For Materials Science

Inventors

• Hozumi masato
• Saito Toshiya
• Yamada Hideto
• Suzuki Tohru
• Uchikoshi Tetsuo
• Sakka Yoshio

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/0485

  Casting · CPC title

• H01M4/0402 Primary

  Methods of deposition of the material · CPC title

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title