Method of separating and recovering metals and system for separating and recovering metals

Patent metadata

Field	Value
Publication number	US-9353452-B2
Application number	US-201414323066-A
Country	US
Kind code	B2
Filing date	Jul 3, 2014
Priority date	Jul 5, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

According to one embodiment, a method of separating and recovering metals whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising: a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit; a first electrolysis step of electrolyzing the first metal; a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step; a second electrolysis step of electrolyzing the second metal; and a second recovery step of recovering a precipitated substance subsequent to the first recovery step.

First claim

What is claimed is:

1. A method of separating and recovering metals, whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising:
a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit;
a first electrolysis step of electrolyzing the first metal;
a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step;
a second electrolysis step of electrolyzing the second metal;
a second recovery step of recovering a precipitated substance subsequent to the first recovery step; and
a salt addition step of adding a salt of the second metal to the molten salt after a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step, and before the first recovery step is performed.

2. The method of separating and recovering metals according to claim 1 , wherein
the first recovery step is performed after a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step and before the concentration of the second metal ion reaches an equilibrium.

3. The method of separating and recovering metals according to claim 1 , wherein
the first recovery step is performed after the concentration of the second metal ion reaches an equilibrium in the detection step.

4. The method of separating and recovering metals according to claim 1 , further comprising:
a preliminary recovery step of recovering a precipitated substance before a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step.

5. The method of separating and recovering metals according to claim 1 , wherein
in the detection step, the concentration change detection unit detects a concentration change of each of the first metal ion and the second metal ion in the molten salt by measuring a potential change of the anode.

6. The method of separating and recovering metals according to claim 1 , wherein
in the detection step, the concentration change detection unit detects a concentration change of each of the first metal ion and the second metal ion in the molten salt by performing component analysis of the molten salt.

7. A method of separating and recovering metals, whereby a mixture containing at least a first metal and a second metal, the second metal having a higher standard electrode potential than that of the first metal, is connected to an anode in a molten salt, and the first metal and the second metal are precipitated on a cathode in the molten salt by electrolysis, the method of separating and recovering metals comprising:
a detection step of detecting a concentration change in each of a first metal ion and a second metal ion in the molten salt by a concentration change detection unit;
a first electrolysis step of electrolyzing the first metal;
a first recovery step of recovering a precipitated substance according to a detection in which a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step;
a second electrolysis step of electrolyzing the second metal;
a second recovery step of recovering a precipitated substance subsequent to the first recovery step; and
a salt addition step of adding a salt of the second metal to the molten salt after the first recovery step is performed and before the concentration of the second metal ion reaches an equilibrium in the detection step.

8. The method of separating and recovering metals according to claim 7 , further comprising:
a preliminary recovery step of recovering a precipitated substance before a concentration decrease of the first metal ion, which is predefined in the concentration change detection unit, is detected in the detection step.

9. The method of separating and recovering metals according to claim 7 , wherein
in the detection step, the concentration change detection unit detects a concentration change of each of the first metal ion and the second metal ion in the molten salt by measuring a potential change of the anode.

10. The method of separating and recovering metals according to claim 5 , wherein
in the detection step, the concentration change detection unit detects a concentration change of each of the first metal ion and the second metal ion in the molten salt by performing component analysis of the molten salt.

Assignees

• Toshiba Kk

Inventors

• Takahashi Yuya
• Nakamura Hitoshi
• Kanamura Shohei
• Yamada Akira
• Mizuguchi Koji
• Oomori Takashi

Classifications

• C25C3/34

  of metals not provided for in groups C25C3/02 - C25C3/32 · CPC title

• C25C7/06 Primary

  Operating or servicing · CPC title

• C25C3/26

  of titanium, zirconium, hafnium, tantalum or vanadium · CPC title