Graphene oxide-based composite membranes

Patent metadata

Field	Value
Publication number	US-9353037-B2
Application number	US-201314083568-A
Country	US
Kind code	B2
Filing date	Nov 19, 2013
Priority date	Nov 19, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

Membranes are provided for energy efficient purification of alcohol by pervaporation. Such membranes include a nanofibrous scaffold in combination with a barrier layer. The barrier layer includes a graphene oxide. The membranes may, in embodiments, also include a substrate.

First claim

What is claimed is:

1. An article comprising:
a nanofibrous scaffold comprising fibers having a diameter of from about 1 nm to about 20,000 nm; and
a barrier layer comprising graphene oxide on at least a portion of a surface of the nanofibrous scaffold,
wherein the barrier layer has a thickness from about 5 nm to about 5000 nm.

2. The article of claim 1 , wherein the nanofibrous scaffold comprises a polymer selected from the group consisting of polyolefins, polysulfones, fluoropolymers, polyesters, polyamides, polycarbonates, polystyrenes, polynitriles, polyacrylates, polyacetates, polyalcohols, polysaccharides, proteins, polyalkylene oxides, polyurethanes, polyureas, polyimines, polyacrylic acids, polymethacrylic acids, polysiloxanes, poly(ester-co-glycol) copolymers, poly(ether-co-amide) copolymers, derivatives thereof and copolymers thereof.

3. The article of claim 1 , wherein the nanofibrous scaffold comprises a polymer selected from the group consisting of polyethylene, polypropylene, polyethersulfone, polyvinylidene fluoride, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, nylon 6, nylon 66, nylon 12, polystyrene, polyacrylonitrile, polymethyl methacrylate, polyvinyl acetate, polyvinyl alcohol, chitosan, cellulose, collagen, gelatin, polyethylene oxide, polyethylene glycol, polyvinyl chloride, polyethylene imine, polyvinylpyrrolidone, polydimethylsiloxane, derivatives thereof and copolymers thereof.

4. The article of claim 1 , wherein the nanofibrous scaffold has a thickness of from about 1 μm to about 500 μm.

5. The article of claim 1 , further comprising an additional barrier layer between the nanofibrous scaffold and the graphene oxide barrier layer, the additional barrier layer formed from a material selected from the group consisting of cellulose nanofibers, chitin nanofibers, and combinations thereof, wherein the additional barrier layer has a thickness from about 0.25 μm to about 2.5 μm.

6. The article of claim 1 , further comprising a substrate, wherein the nanofibrous scaffold is applied to at least a portion of the substrate.

7. The article of claim 6 , wherein the substrate comprises a polymer selected from the group consisting of polyolefins, polyesters, polyamides, polyurethanes, polysulfones, polyureas, fluorinated polymers, derivatives thereof and copolymers thereof.

8. The article of claim 7 , wherein the polymer is selected from the group consisting of polyethylene, polypropylene, polyethylene terephthalate, polytrimethylene terephthalate, polybutylene terephthalate, nylon 6, nylon 66, nylon 12, derivatives thereof, and copolymers thereof, polyetherketones, polystyrene, sulfonated polyetherketones, sulfonated polystyrene, glass, cellulose, derivatives thereof, and copolymers thereof.

9. The article of claim 6 , wherein the substrate is selected from the group consisting of polysulfones, cellulose acetates, fluoropolymers, polyamides, polyimides, and combinations thereof, and wherein the substrate has a pore size of from about 5 nm to about 500 nm.

10. A method for purifying an alcohol by pervaporation, the method comprising contacting the alcohol with the article of claim 1 .

11. The article of claim 1 , wherein the nanofibrous scaffold further comprises a zeolite.

12. The article of claim 1 , wherein the graphene oxide barrier layer further comprises a zeolite.

13. An article comprising:
a substrate;
a nanofibrous scaffold comprising fibers having a diameter of from about 1 nm to about 20,000 nm applied to a surface of the substrate; and
a barrier layer comprising graphene oxide on the nanofibrous scaffold on a surface opposite the surface applied to the substrate, wherein the barrier layer has a thickness from about 5 nm to about 5000 nm.

14. The article of claim 13 , wherein the substrate comprises a polymer selected from the group consisting of polyolefins, polyesters, polyamides, polyurethanes, polysulfones, polyureas, fluorinated polymers, derivatives thereof and copolymers thereof.

15. The article of claim 13 , wherein the nanofibrous scaffold comprises a polymer selected from the group consisting of polyolefins, polysulfones, fluoropolymers, polyesters, polyamides, polycarbonates, polystyrenes, polynitriles, polyacrylates, polyacetates, polyalcohols, polysaccharides, proteins, polyalkylene oxides, polyurethanes, polyureas, polyimines, polyacrylic acids, polymethacrylic acids, polysiloxanes, poly(ester-co-glycol) copolymers, poly(ether-co-amide) copolymers, derivatives thereof and copolymers thereof.

16. The article of claim 13 , wherein the nanofibrous scaffold has a thickness of from about 1 μm to about 500 μm and possesses voids with an effective diameter of from about 10 nm to about 200 μm.

17. The article of claim 13 , further comprising an additional barrier layer between the nanofibrous scaffold and the graphene oxide barrier layer, the additional barrier layer formed from a material selected from the group consisting of cellulose nanofibers, chitin nanofibers, and combinations thereof, wherein the additional barrier layer has a thickness from about 0.25 μm to about 2.5 μm.

18. A method for purifying an alcohol by pervaporation, the method comprising contacting the alcohol with the article of claim 13 .

19. The article of claim 13 , wherein the nanofibrous scaffold further comprises a zeolite.

20. The article of claim 13 , wherein the graphene oxide barrier layer further comprises a zeolite.

Assignees

• Univ New York State Res Found
• Univ New York State Res Found

Inventors

• Chu Benjamin
• Hsiao Benjamin S
• Mahajan Devinder
• Yeh Tsung-Ming

Classifications

• C07C31/08

  Ethanol · CPC title

• B01D71/48

  Polyesters · CPC title

• B01D69/10

  Supported membranes; Membrane supports · CPC title

• Y02P20/572

  Cross-Sectional Technologies · mapped topic

• B01D71/42

  Polymers of nitriles, e.g. polyacrylonitrile · CPC title