Dust suppressing aggregate

Patent metadata

Field	Value
Publication number	US-9353020-B2
Application number	US-201214115377-A
Country	US
Kind code	B2
Filing date	May 4, 2012
Priority date	May 5, 2011
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

A dust suppressing aggregate includes a core particle and a dust suppressing agent. The dust suppressing agent comprises polycarbodiimide and is disposed about the core particle for suppressing dusting of the core particle. A method of forming the dust suppressing aggregate includes the steps of reacting isocyanates in the presence of a catalyst to form the polycarbodiimide and encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent. A system for producing the dust suppressing aggregate includes the core particle, the isocyanates, and the catalyst.

First claim

What is claimed is:

1. A dust suppressing aggregate comprising:
A. a core particle comprising fertilizer; and
B. a dust suppressing agent disposed about said core particle and comprising polycarbodiimide comprising the reaction product of isocyanates in the presence of a catalyst.

2. A dust suppressing aggregate as set forth in claim 1 wherein said dust suppressing agent is present in an amount of from 0.1 to 7.5 parts by weight based on 100 parts by weight of said core particle.

3. A dust suppressing aggregate as set forth in claim 1 having a dust reduction gradient of greater than 20%.

4. A dust suppressing aggregate as set forth in claim 1 having a dissolution gradient equal to or less than 30 after 1 day of aging in water at 38° C.

5. A dust suppressing aggregate as set forth in claim 1 wherein said isocyanates comprise polymeric diphenylmethane diisocyanate and has an NCO content of about 31.5 weight percent.

6. A dust suppressing aggregate as set forth in claim 1 wherein said isocyanates comprise 4,4′-diphenylmethane diisocyanate and has an NCO content of about 33.5 weight percent.

7. A dust suppressing aggregate as set forth in claim 1 wherein said isocyanates are further defined as a first isocyanate comprising polymeric diphenylmethane diisocyanate and having an NCO content of about 31.5 weight percent and a second isocyanate comprising 4,4′-diphenylmethane diisocyanate and having an NCO content of about 33.5 weight percent and said dust suppressing agent comprising a polycarbodiimide comprising the reaction product of said first and second isocyanates in the presence of the catalyst.

8. A dust suppressing aggregate as set forth in claim 7 wherein said first isocyanate and said second isocyanate react in a weight ratio of 4:1 to 1:4 to form said polycarbodiimide.

9. A dust suppressing aggregate as set forth in claim 1 wherein said core particle comprises monoammonium phosphate and/or urea.

10. A method of forming a dust suppressing aggregate comprising a core particle comprising fertilizer and a dust suppressing agent disposed about the core particle, said method comprising the steps of:
A. reacting isocyanates in the presence of a catalyst to form a polycarbodiimide; and
B. encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent.

11. A method as set forth in claim 10 wherein the dust suppressing agent is present in an amount of from 0.1 to 7.5 parts by weight based on 100 parts by weight of the core particle.

12. A method as set forth in claim 10 further comprising the step of heating the core particle to a temperature of greater than about 120° F. prior to the step of encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent.

13. A method as set forth in claim 10 further comprising the step of heating the core particle to a temperature of greater than about 150° F. prior to the step of encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent.

14. A method as set forth in claim 10 further comprising the step of heating at least one of the isocyanates and the catalyst to a temperature of greater than about 120° F. prior to the step of reacting the isocyanates in the presence of the catalyst to form the polycarbodiimide.

15. A method as set forth in claim 10 wherein the step of reacting the isocyanates in the presence of the catalyst to form the polycarbodiimide is conducted simultaneous with the step of encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent.

16. A method as set forth in claim 10 wherein the steps of reacting an isocyanates in the presence of a catalyst to form a polycarbodiimide and encapsulating the core particle with the polycarbodiimide to form the dust suppressing agent are conducted in about 40 minutes or less.

17. A method as set forth in claim 10 further comprising the step of spray applying at least one of the isocyanates and the catalyst onto the core particle.

18. A system for producing a dust suppressing aggregate including a core particle comprising fertilizer and a dust suppressing agent comprising polycarbodiimide comprising the reaction product of isocyanates in the presence of a catalyst and disposed about said core particle, wherein the dust suppressing agent is present in an amount of from 0.1 to 7.5 parts by weight based on 100 parts by weight of the core particle, said system comprising:
A. said isocyanates;
B. said catalyst for chemically reacting said isocyanates to produce the polycarbodiimide that minimizes dust while having minimal impact on dissolution of said core particle; and
C. said core particle comprising fertilizer.

19. A system as set forth in claim 18 wherein said isocyanates comprise polymeric diphenylmethane diisocyanate having an NCO content of about 31.5 weight percent.

20. A system as set forth in claim 18 wherein said catalyst is a phosphorous compound.

Assignees

• Neff Raymond
• Gershanovich Alexander
• Mente Donald C
• Kumar Rajesh
• Basf Se

Inventors

• Neff Raymond
• Gershanovich Alexander
• Mente Donald C
• Kumar Rajesh

Classifications

• C05C9/00 Primary

  Fertilisers containing urea or urea compounds · CPC title

• C05G5/38

  layered or coated with wax or resins · CPC title

• C05G3/20

  for preventing the fertilisers being reduced to powder; Anti-dusting additives · CPC title

• C08G18/08

  Processes · CPC title

• C05G5/37

  layered or coated with a polymer · CPC title