Methods for preparing composites of activated carbon/zinc oxide and activated carbon/zinc oxide/nickel oxide for desulfurization of fuels

Patent metadata

Field	Value
Publication number	US-9352297-B2
Application number	US-201314092295-A
Country	US
Kind code	B2
Filing date	Nov 27, 2013
Priority date	Nov 27, 2013
Publication date	May 31, 2016
Grant date	May 31, 2016

Abstract

Activated carbon\nickel oxide\zinc oxide (AC\NiO\ZnO) and activated carbon\zinc oxide (AC\ZnO) were prepared and used as adsorbents for removal of thiophene, benzothiophene (BT) and dibenzothiophene (DBT) as sulfur compounds from hydrocarbon materials such as diesel fuel. The materials exhibited an efficient and economical way for removing sulfur compounds due to its low-energy consumption, ambient operation temperature and atmospheric pressure. A simple regeneration method of the spent adsorbents.

First claim

The invention claimed is:

1. A method for obtaining an activated carbon/NiO/ZnO material, comprising:
dispersing an activated carbon in a solvent and sonicating to form a first mixed solution;
mixing a nickel salt solution with the first mixed solution to form a second mixed solution;
heating and stirring the second mixed solution to precipitate a first precipitate;
dispersing the first precipitate in a solvent and mixing with a zinc salt solution to form a second mixture;
heating and stirring the second mixture to precipitate a second precipitate;
calcining the second precipitate to form an activated carbon/NiO/ZnO material having a surface area in the range of 20-45 m 2 /g, a pore volume in the range of 0.05-1 cm 3 /g, and an adsorption average pore width in the range of 500-600 Å.

2. The method of claim 1 in which the solvent is deionized water.

3. The method of claim 1 in which the activated carbon is powdered activated carbon.

4. The method of claim 1 in which the pH of the second mixture is maintained within the range of 8-9 during heating and stirring.

5. An activated carbon/NiO/ZnO material in which the material has a surface area of about 38.9 m 2 /g, a pore volume of about 0.507 cm 3 /g, and an adsorption average pore width of about 521 Å.

6. A method for obtaining an activated carbon/ZnO material, comprising:
dispersing an activated carbon in a solvent and sonicating to form a first mixed solution;
mixing a zinc salt solution with the first mixed solution to form a second mixed solution;
heating and stirring the second mixed solution to precipitate a precipitate;
calcining the precipitate to form an activated carbon/ZnO material having a surface areain the range of 10-20 m 2 /g, a pore in the range of 0.05-1 cm 3 /g, and an adsorption average pore width in the range of 700-900 Å.

7. The method of claim 6 in which the solvent is deionized water.

8. The method of claim 6 in which the activated carbon is powdered activated carbon.

9. The method of claim 6 in which the pH of the second mixed solution is maintained within the range of 8-9 during heating and stirring.

10. An activated carbon/ZnO material in which the material has a surface area of about 15.2 m 2 /g, a pore volume of about 0.304 cm 3 /g, and an adsorption average pore width of about 801 Å.

11. A method for desulfurizing a hydrocarbon composition, comprising:
contacting an activated carbon/NiO/ZnO material with the hydrocarbon composition to absorb one or more sulfur compounds present in the hydrocarbon composition on the activated carbon/NiO/ZnO material.

12. The method of claim 11 wherein the hydrocarbon composition is a mixture of an aromatic-containing compound and an alkane.

13. The method of claim 12 wherein the aromatic-containing compound is toluene and the alkane is hexane.

14. The method of claim 11 wherein the sulfur compounds are selected from the group consisting of dibenzothiopene, benzothiopene, and thiopene.

15. The method of claim 11 wherein the activated carbon/NiO/ZnO material is contacted with the hydrocarbon composition for 50 minutes.

Assignees

• Univ King Fahd Pet & Minerals
• King Abdulaziz City Sci & Tech

Inventors

• Alhooshani Khalid R
• Al Swat Abdullah A
• Saleh Tawfik A
• Siddiqui Mohammad N

Classifications

• B01J20/20 Primary

  comprising free carbon; comprising carbon obtained by carbonising processes · CPC title

• B01J20/06

  comprising oxides or hydroxides of metals not provided for in group B01J20/04 · CPC title

• B01J20/3085

  Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title

• B01J20/28059

  being less than 100 m2/g · CPC title

• B01J20/3078

  Thermal treatment, e.g. calcining or pyrolizing · CPC title