Rechargeable organosodium polymer battery

Patent metadata

Field	Value
Publication number	US-9350012-B2
Application number	US-201113390329-A
Country	US
Kind code	B2
Filing date	Sep 23, 2011
Priority date	Sep 23, 2011
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

Technologies are generally described for electrochemical cells and batteries containing electrochemical cells. An electrochemical cell may incorporate two types of conducting polymers each located at an electrode, a cation, a polycyclic aromatic hydrocarbon radical anion that contacts one of the conducting polymers, and an electrolyte. The polycyclic aromatic hydrocarbon radical anion may be a covalent substituent of one of the conducting polymers or may be in noncovalent contact with one of the conducting polymers. The polycyclic aromatic hydrocarbon radical anion may permit the use of cations other than lithium, e.g. an alkali metal cation such as sodium or alkali earth metal cation such as calcium. Such an electrochemical cell may provide alternative batteries to existing lithium ion batteries, permitting the use of cations that may be more abundant, more easily extracted, or more sustainable compared to known lithium supplies.

First claim

What is claimed is:

1. An electrochemical cell, comprising:
a first electrode that includes a first conductive polymer;
a fused polycyclic aromatic hydrocarbon radical anion configured to contact the first conductive polymer;
a second electrode that includes a second conductive polymer, wherein the first electrode and the second electrode are composed from a metal, an alloy, or a conductive oxide selected from one or more of: copper, aluminum, tin, lead, iron, chromium, cobalt, nickel, silver, gold, platinum, palladium, vanadium, manganese, titanium, tungsten, indium, zinc, cadmium, tin oxide, aluminum doped zinc oxide, and indium doped cadmium oxide, and wherein the first electrode and the second electrode are in a form of one of: a sheet, a wire, a plate, a foil, or a tape;
a cation; and
an electrolyte configured to conductively couple the first conductive polymer and the second conductive polymer, the fused polycyclic aromatic hydrocarbon radical anion, and the cation, wherein the electrolyte includes a liquid electrolyte, an anion, and an ionomer;
wherein the liquid electrolyte includes one or more of cycloalkylene carbonate and a cycloalkanone;
wherein the anion forms a salt of the ionomer with the cation, wherein the salt separates the first conductive polymer from the second conductive polymer;
wherein the first conductive polymer includes one or more of: a poly(fluorene), a polypyrene, a polyazepine, and a poly(phenylene ethynylene), or a combination thereof;
wherein the first conductive polymer is substituted by the fused polycyclic aromatic hydrocarbon radical anion;
wherein the fused polycyclic aromatic hydrocarbon radical anion includes an anthracene radical anion;
wherein the second conductive polymer includes one or more of: a poly(arylene ethynylene), a poly(phenylene ethynylene), and a polycarbazole, or a combination thereof;
wherein the ionomer contacts the first conductive polymer and the second conductive polymer and includes repeat units selected from one or more of: alkyl, alkyl ether, perfluoroalkyl, perfluoroalkyl ether, sulfonates, phosphates, and carboxylates; and
wherein the first conductive polymer and the second conductive polymer are one of oxidatively doped and reductively doped to conduct electricity.

2. The electrochemical cell of claim 1 , wherein the cation includes an alkali cation, an alkaline earth metal cation, or a mixture thereof.

3. The electrochemical cell of claim 2 , wherein the cation includes Na + .

4. The electrochemical cell of claim 1 , wherein the first conductive polymer includes a homopolymer, a block copolymer, a random copolymer, or a graft copolymer.

5. The electrochemical cell of claim 1 , wherein the cation includes Na + .

6. The electrochemical cell of claim 1 , wherein the electrolyte comprises one or more anions selected from a group consisting of fluoride, chloride, bromide, iodide, carboxylate, trifluoromethanesulfonate, bistrifluoromethanesulfonimidate, fluorosulfate, hexafluorophosphate, perchlorate, tetrafluoroborate, p-toluenesulfonate, and nitrate.

7. The electrochemical cell of claim 1 , wherein the ionomer comprises a polytetrafluoroethylene-perfluorosulfonic acid copolymer.

8. The electrochemical cell of claim 1 , wherein fused polycyclic aromatic hydrocarbon radical anion is in noncovalent contact with the first conductive polymer.

9. An electrochemical cell, comprising:
a first electrode formed from a first conductive polymer, the first conductive polymer being configured to contact a polycyclic aromatic hydrocarbon;
a fused polycyclic aromatic hydrocarbon radical anion configured to contact the first conductive polymer;
a second electrode formed from a second conductive polymer, the second conductive polymer being configured to contact the fused polycyclic aromatic hydrocarbon with a metal that corresponds to a metal cation;
a cation; and
an electrolyte configured to conductively couple the first conductive polymer, the second conductive polymer, the fused polycyclic aromatic hydrocarbon radical anion, and the cation, wherein the electrolyte includes a liquid electrolyte, an anion, and an ionomer;
wherein the liquid electrolyte includes one or more of cycloalkylene carbonate and a cycloalkanone;
wherein the anion forms a salt of the ionomer with the cation, wherein the salt separates the first conductive polymer from the second conductive polymer;
wherein the first conductive polymer includes one or more of: a poly(fluorene), a polypyrene, a polyazepine, and a poly(phenylene ethynylene), or a combination thereof;
wherein the first conductive polymer is substituted by the fused polycyclic aromatic hydrocarbon radical anion;
wherein the fused polycyclic aromatic hydrocarbon radical anion includes an anthracene radical anion;
wherein the second conductive polymer includes one or more of: a poly(arylene ethynylene), a poly(phenylene ethynylene), and a polycarbazole, or a combination thereof;
wherein the ionomer contacts the first conductive polymer and the second conductive polymer and includes repeat units selected from one or more of: alkyl, alkyl ether, perfluoroalkyl, perfluoroalkyl ether, sulfonates, phosphates, and carboxylates; and
wherein the first conductive polymer and the second conductive polymer are one of oxidatively doped and reductively doped to conduct electricity.

10. The electrochemical cell of claim 9 , wherein the cation includes Na + .

11. The electrochemical cell of claim 9 , wherein the ionomer comprises a polytetrafluoroethylene-perfluorosulfonic acid copolymer.

12. The electrochemical cell of claim 9 , wherein the electrolyte comprises one or more anions selected from a group consisting of fluoride, chloride, bromide, iodide, carboxylate, trifluoromethanesulfonate, bistrifluoromethanesulfonimidate, fluorosulfate, hexafluorophosphate, perchlorate, tetrafluoroborate, p-toluenesulfonate, and nitrate.

Assignees

• Casasanta Vincenzo
• Empire Technology Dev Llc

Inventors

• Casasanta Vincenzo

Classifications

• Y10T29/49108

  Electric battery cell making · CPC title

• H01M4/602 Primary

  Polymers · CPC title

• H01M4/60

  of organic compounds · CPC title

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title