Dielectric material with non-linear dielectric constant

Patent metadata

Field	Value
Publication number	US-9349498-B2
Application number	US-201414581325-A
Country	US
Kind code	B2
Filing date	Dec 23, 2014
Priority date	Dec 14, 2009
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

Provided is a composition comprising a polymeric material, a filler material dispersed in the polymeric material, the filler material comprising inorganic particles and a discontinuous arrangement of conductive material wherein at least a portion of the conductive material is in durable electrical contact with the inorganic particles, and conductive material dispersed in the polymeric material.

First claim

What is claimed is:

1. A composition comprising:
an elastomeric material;
a filler material dispersed in the elastomeric material, the filler material comprising inorganic particles and a discontinuous arrangement of conductive material, wherein at least a portion of the conductive material is in durable electrical contact with the inorganic particles; and
conductive material dispersed in the elastomeric material;
wherein the volume ratio of the inorganic particles to conductive material is about 6 to about 12; and wherein the inorganic particles are modified with nanosilica particles.

2. The composition of claim 1 wherein the conductive material is selected from the group consisting of carbon black, carbon nanotubes, clusters of carbon particles, graphite, insulating particles having conductive coatings, metals such as silver, gold, palladium, and aluminum, and alloys of such metals, and combinations thereof.

3. The composition of claim 1 wherein the conductive material in durable electrical contact with the inorganic particles and the conductive material dispersed in the elastomeric material are different materials.

4. The composition of claim 1 wherein the combined amount of conductive material in the composition is between about 40 and about 70 vol% of the amount of conductive material needed to attain the composition's percolation threshold.

5. The composition of claim 1 further comprising a relative dielectric constant value that changes in a non-linear manner upon a change in applied voltage.

6. The composition of claim 1 wherein the volume loading of the inorganic particles in the composition is about 20 to about 40 volume percent.

7. The composition of claim 1 wherein the elastomeric material comprises silicone.

8. The composition of claim 1 wherein the filler material comprises nanosilica-modified barium titanate.

9. The composition of claim 8 wherein the conductive material comprises carbon.

10. The composition of claim 1 further comprising silicone oil.

Assignees

• 3M Innovative Properties Co

Inventors

• Lottes Andrew C
• Somasiri Nanayakkara L D
• Baran Jr Jimmie R
• Veeraraghavan Badri
• Huynh Paul V
• Ghosh Dipankar

Classifications

• H01B1/24 Primary

  the conductive material comprising carbon-silicon compounds, carbon or silicon · CPC title

• H01B3/28

  natural or synthetic rubbers · CPC title

• H02G15/064

  with devices for relieving electrical stress · CPC title

• H01B3/004

  with conductive additives or conductive layers · CPC title

• H01B1/22

  the conductive material comprising metals or alloys · CPC title