Toner, method for producing the toner, two-component developer, and image forming apparatus

Patent metadata

Field	Value
Publication number	US-9348245-B2
Application number	US-201314373984-A
Country	US
Kind code	B2
Filing date	Mar 7, 2013
Priority date	Mar 13, 2012
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

A toner, including: a crystalline resin; a non-crystalline resin; and a colorant, wherein the toner has a sea-island structure which includes a sea containing the crystalline resin and an island containing the non-crystalline resin and the colorant, wherein the island is 1.0 μm or less in domain diameter, and wherein the toner is 1.7×10 4 Pa or less in storage elastic modulus at 160° C.

First claim

The invention claimed is:

1. A toner, comprising:
a crystalline resin;
a non-crystalline resin; and
a colorant,
wherein
the toner has a sea-island structure which comprises a sea comprising the crystalline resin and an island comprising the non-crystalline resin and the colorant,
the island is 1.0 μm or less in domain diameter, and
the toner is 1.7×10 4 Pa or less in storage elastic modulus at 160° C.,
and wherein the crystalline resin comprises, in a backbone thereof, a urethane bond, a urea bond, or both thereof.

2. The toner according to claim 1 , wherein the toner has a degree of crystallinity of 15% or more.

3. The toner according to claim 1 , wherein the non-crystalline resin is poorly soluble in ethyl acetate, where the “poorly soluble” means that when 40 parts by mass of the non-crystalline resin is added to and mixed with 100 parts by mass of ethyl acetate, a mixture of the non-crystalline resin and the ethyl acetate yields a white turbidity at 50° C., or even when the mixture becomes a transparent solution without yielding a white turbidity at 50° C., the mixture yields a white turbidity after the mixture is allowed to stand for 12 hours at 50° C.

4. The toner according to claim 1 , wherein the non-crystalline resin has a weight-average molecular weight of 100,000 to 500,000.

5. The toner according to claim 1 , wherein the toner further comprises a block copolymer containing a crystalline block and a non-crystalline block.

6. The toner according to claim 5 , wherein the block copolymer is poorly soluble in ethyl acetate, where the “poorly soluble” means that when 40 parts by mass of the block copolymer is added to and mixed with 100 parts by mass of ethyl acetate, a mixture of the block copolymer and the ethyl acetate yields a white turbidity at 50° C., or even when the mixture becomes a transparent solution at 50° C. without yielding a white turbidity, the mixture yields a white turbidity after the mixture is allowed to stand for 12 hours at 50° C.

7. The toner according to claim 5 , wherein the block copolymer has a glass transition temperature of 30° C. or less.

8. The toner according to claim 5 , wherein a content of the block copolymer in a total of the resins is 5% by mass to 20% by mass.

9. The toner according to claim 5 , wherein a mass ratio of the non-crystalline block to the crystalline block in the block copolymer is 1/9 or more but 9 or less.

10. The toner according to claim 5 , wherein the non-crystalline resin is a non-crystalline polyester, and the block copolymer contains a crystalline polyester block and a non-crystalline polyester block.

11. The toner according to claim 1 , wherein the crystalline resin is a crystalline polyester.

12. The toner according to claim 1 ,
wherein the crystalline resin contains a first crystalline resin and a second crystalline resin which is greater in weight-average molecular weight than the first crystalline resin, and
wherein the second crystalline resin is obtained by elongating the first crystalline resin.

13. A two-component developer, comprising:
a toner; and,
a carrier,
wherein the toner comprises:
a crystalline resin,
a non-crystalline resin, and
a colorant,
wherein
the toner has a sea-island structure which comprises a sea containing the crystalline resin and an island comprising the non-crystalline resin and the colorant,
the island is 1.0 μm or less in domain diameter, and
the toner is 1.7×10 4 Pa or less in storage elastic modulus at 160° C.,
and wherein the crystalline resin comprises, in a backbone thereof, a urethane bond, a urea bond, or both thereof.

14. An image forming apparatus, comprising:
an electrostatic latent image bearing member;
a charging unit configured to charge a surface of the electrostatic latent image bearing member;
an exposure unit configured to expose the charged surface of the electrostatic latent image bearing member to light, to thereby form an electrostatic latent image;
a developing unit configured to develop the electrostatic latent image with a toner to form a visible image;
a transfer unit configured to transfer the developed visible image onto a recording medium to form an unfixed image; and,
a fixing unit configured to fix the unfixed image on the recording medium,
wherein the image forming apparatus comprises the toner, and wherein the toner comprises:
a crystalline resin;
a non-crystalline resin; and
a colorant,
wherein the toner has a sea-island structure which comprises a sea comprising the crystalline resin and an island comprising the non-crystalline resin and the colorant,
the island is 1.0 μm or less in domain diameter, and
the toner is 1.7×10 4 Pa or less in storage elastic modulus at 160° C.,
and wherein the crystalline resin comprises, in a backbone thereof, a urethane bond, a urea bond, or both thereof.

Assignees

• Morita Tatsuya
• Suzuki Kazumi
• Sakashita Shingo
• Shiba Masana
• Nemoto Taichi
• Yamauchi Yoshitaka
• Miyaake Azumi
• Takahashi Rintaro
• Ricoh Co Ltd

Inventors

• Morita Tatsuya
• Suzuki Kazumi
• Sakashita Shingo
• Shiba Masana
• Nemoto Taichi
• Yamauchi Yoshitaka
• Miyaake Azumi
• Takahashi Rintaro

Classifications

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title

• G03G9/08755

  Polyesters · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08788

  Block polymers · CPC title

• G03G9/08757

  Polycarbonates · CPC title