Lubricating oil composition

Patent metadata

Field	Value
Publication number	US-9347019-B2
Application number	US-201113304873-A
Country	US
Kind code	B2
Filing date	Nov 28, 2011
Priority date	Nov 30, 2010
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

A low sulphated ash lubricating oil composition comprises an ashless aromatic amine antioxidant and an overbased magnesium detergent which exhibits improved thermal oxidation stability.

First claim

What is claimed is:

1. A lubricating oil composition having a sulphated ash content of less than 0.6 mass % as determined by ASTM D874, the composition comprising:
(A) an oil of lubricating viscosity in a major amount;
(B) an antioxidant component, as an additive in a minor amount, comprising one or more oil-soluble or oil-dispersible ashless aromatic amine antioxidants selected from the group consisting of diaryl amine and aryl diamine antioxidants, present in an amount of 0.75 mass % to 2.0 mass %, based on the total mass of the lubricating oil composition; and,
(C) a detergent component, as an additive comprising oil-soluble or oil-dispersible overbased magnesium sulfonate detergent, oil-soluble or oil-dispersible overbased magnesium salicylate detergent, or combination of oil-soluble or oil-dispersible overbased magnesium sulfonate detergent and oil-soluble or oil-dispersible overbased magnesium salicylate detergent, having a TBN of at least 300 mg KOH/g as determined by ASTM D2896, in an amount providing the lubricating oil composition with at least 0.05 mass % of magnesium, based on the total mass of the lubricating oil composition, wherein greater than 45 mass % of the metal content of the detergent component (C), based on the total mass of metal in the detergent component, comprises magnesium derived from the overbased magnesium detergent; and wherein the mass to mass ratio, in the lubricating oil composition, of the mass of ashless aromatic amine antioxidant (B) to the mass of magnesium provided by the detergent component (C) is greater than or equal to 11:1.

2. A lubricating oil composition as claimed in claim 1 , wherein the sulphated ash content is less than 0.55 mass % as determined by ASTM D874.

3. A lubricating oil composition as claimed in claim 1 , wherein the ashless aromatic amine antioxidant is present in an amount of at least 0.8 mass %, based on the total mass of the lubricating oil composition.

4. A lubricating oil composition as claimed in claim 1 , wherein the overbased magnesium detergent is selected from one or more magnesium sulphonates, magnesium salicylates and magnesium phenates, preferably one or more magnesium salicylates.

5. A lubricating oil composition as claimed in claim 4 , wherein the overbased magnesium detergent is one or more magnesium salicylate.

6. A lubricating oil composition as claimed in claim 1 , wherein greater than or equal to 50 mass % of the total metal content of the detergent component (C) comprises magnesium derived from the overbased magnesium detergent.

7. A lubricating oil composition as claimed in claim 1 , wherein the overbased magnesium detergent provides the composition with at least 0.06 mass % of magnesium, based on the total mass of the composition.

8. A lubricating oil composition as claimed in claim 1 , further comprising one or more co-additives in a minor amount, other than additive components (B) and (C), selected from ashless dispersants, metal detergents, corrosion inhibitors, antioxidants, pour point depressants, antiwear agents, friction modifiers, demulsifiers, antifoam agents and viscosity modifiers.

9. A lubricating oil composition as claimed in claim 1 , wherein the detergent component (C) consists essentially of one or more metal containing detergent components.

10. A lubricating oil composition as claimed in claim 9 , wherein the metal containing detergent component consists essentially of said one or more overbased magnesium detergents.

11. A method of lubricating a spark-ignited or compression-ignited internal combustion engine comprising operating the engine with a lubricating oil composition as claimed in claim 1 .

Assignees

• Shaw Robert W
• Head James L
• Corradi Marco
• Rostami Shamsedin
• Infineum Int Ltd

Inventors

• Shaw Robert W
• Head James L
• Corradi Marco
• Rostami Shamsedin

Classifications

• C10N2030/10

  Inhibition of oxidation, e.g. anti-oxidants · CPC title

• C10N2030/08

  Resistance to extreme temperature · CPC title

• C10N2030/43

  Sulfur free or low sulfur content compositions · CPC title

• C10N2030/42

  Phosphor free or low phosphor content compositions · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title