Industrial gear lubricating oil composition used for resisting micro-pitting

Patent metadata

Field	Value
Publication number	US-9347016-B2
Application number	US-201214116090-A
Country	US
Kind code	B2
Filing date	May 4, 2012
Priority date	May 6, 2011
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

Provided is a micropitting corrosion resistant industrial gear lubricant composition, comprising: (A) at least a highly refined mineral oil, or synthetic oil or any combination of the above components; (B) at least a micropitting corrosion resistant additive; (C) at least an anti-wear additive; (D) at least a metal passivation additive; and (E) at least an anti-oxidation additive.
The lubricant composition has excellent high and low temperature performance and meets 68, 100, 150, 220, 320, 460 and 680 industrial gear oil viscosity level requirement. The lubricant composition has excellent micropitting corrosion resistance, anti-wear performance and anti-oxidation performance, passes FVA 54 micropitting corrosion resistant test, FAG FE-8 bearing wear test and SKF EMCOR bearing corrosion test, and is suitable for many large-scale industrial transmission gears and some automobile transmission gears, especially suitable for a gear transmission system for wind power generation.

First claim

What is claimed is:

1. A micropitting corrosion resistant industrial gear lubricant composition, comprising:
(A) a highly refined mineral oil, or synthetic oil, and combinations thereof in an amount of 88.00-98.79 wt. % based on the composition;
(B) a micropitting corrosion resistant additive in an amount of 0.2-5.0 wt. % based on the composition-comprising a m-diphosphonate selected from the group consisting of diisopropyl m-diphosphonate, isopropyl isoctyl m-diphosphonate, diisohexyl m-diphosphonate, and diisooctyl m-diphosphonate;
(C) an anti-wear additive in an amount of 0.5-3.0 wt. % based on the composition selected from the group consisting of trialkyl phosphate, triaryl phosphate, trialkyl thiophosphate, triaryl thiophosphate, and mixtures thereof;
(D) a metal passivation additive in an amount of 0.01-1.0 wt. % based on the composition selected from the group consisting of benzotriazole dialkylamine formaldehyde condensate, thiadiazole alkylthiol hydrogen peroxide condensate, and mixtures thereof;
(E) an antioxidant additive in an amount of 0.5-3.0 wt. % based on the composition selected from the group consisting of 2,6-di-tert-butyl-4-methylphenol, a condensate of N-phenyl-α-naphthylamine, dialkyldiphenylamine, dialkyl dithiocarbamate, and mixtures thereof.

2. The micropitting corrosion resistant industrial gear lubricant composition according to claim 1 , wherein the component (A) is selected from the group consisting of a highly solvent-refined mineral oil, isomerized, dewaxed and hydrogenated highly refined mineral oil, poly(α-olefin) synthetic oil, ester synthetic oil, and combinations thereof in an amount of 88.00-98.48 wt. % based on the composition.

3. The micropitting corrosion resistant industrial gear lubricant composition according to claim 1 , further comprising dialkyl dithiophosphate and a dialkylphosphate amine salt.

4. The micropitting corrosion resistant industrial gear lubricant composition according to claim 1 , wherein the component (C) is selected from the group consisting of tricresyl phosphate or triphenyl thiophosphate, tributyl phosphate, tributyl thiophosphate, trioctyl phosphate, trioctyl thiophosphate, tri-dodecyl phosphate, tri-dodecyl thiophosphate, and mixtures thereof, and is in an amount of 0.6-3.0 wt. % based on the composition.

5. The micropitting corrosion resistant gear lubricant composition according to claim 1 , wherein the component (D) is selected from the group consisting of benzotriazole di-n-butylamine formaldehyde condensate, benzotriazole dioctylamine formaldehyde condensate, thiadiazole dodecylthiol hydrogen peroxide condensate, thiadiazole octadecylthiol hydrogen peroxide condensate, and mixtures thereof, and is in an amount of 0.02-1.0 wt. % based on the composition.

6. The micropitting corrosion resistant gear lubricant composition according to claim 1 , wherein the component (E) is selected from the group consisting of 2,6-di-tert-butyl-4-methyl phenol, condensate of N-phenyl-α-naphthylamine and di-n-butyl diphenylamine, condensate of N-phenyl-α-naphthylamine and butyl octyl diphenylamine, condensate of N-phenyl-α-naphthylamine and butyl nonyl diphenylamine, condensate of N-phenyl-α-naphthylamine and dioctyl diphenylamine, condensate of N-phenyl-α-naphthylamine and dinonyl diphenylamine, di-n-butyl dithiocarbamate, or di-n-octyl dithiocarbamate, di-n-dodecyl dithiocarbamate, and mixtures thereof, and is in an amount of 0.6-3.0 wt. % based on the composition.

7. The micropitting corrosion resistant industrial gear lubricant composition according to claim 1 , further comprising dialkyl dithiophosphate.

8. The micropitting corrosion resistant industrial gear lubricant composition according to claim 7 , wherein the dialkyl dithiophsphate is selected from the group consisting of diisopropyl dithiophosphate, isopropyl isooctyl dithiophosphate, diisohexyl dithiophosphate, diisooctyl dithiophosphate, and mixtures thereof; and wherein the component (B) is contained in an amount of 0.3-5.0 wt. % based on the composition.

9. The micropitting corrosion resistant industrial gear lubricant composition according to claim 1 , further comprising a dialkylphosphate amine salt.

10. The micropitting corrosion resistant industrial gear lubricant composition according to claim 9 , wherein the dialkylphosphate amine salt is selected from the group consisting of diisopropyl phosphate stearylamine salt, isopropyl isooctyl phosphate stearylamine salt, diisohexyl phosphate stearylamine salt, diisooctyl phosphate stearylamine salt, and mixtures thereof; and wherein the component (B) is contained in an amount of 0.3-5.0 wt. % based on the composition.

11. The micropitting corrosion resistant industrial gear lubricant composition according to claim 3 , wherein:
the dialkyl dithiophsphate is selected from the group consisting of diisopropyl dithiophosphate, isopropyl isooctyl dithiophosphate, diisohexyl dithiophosphate, diisooctyl dithiophosphate, and mixtures thereof;
the dialkylphosphate amine salt is selected from the group consisting of diisopropyl phosphate stearylamine salt, isopropyl isooctyl phosphate stearylamine salt, diisohexyl phosphate stearylamine salt, diisooctyl phosphate stearylamine salt, and mixtures thereof;
and the component (B) is contained in an amount of 0.3-5.0 wt. % based on the composition.

Assignees

• Fu Xisheng
• Hua Xiuling
• Zhang Jie
• Petrochina Co Ltd

Inventors

• Fu Xisheng
• Hua Xiuling
• Zhang Jie

Classifications

• C10M2223/04

  Phosphate esters · CPC title

• C10M2223/06

  having phosphorus-to-carbon bonds · CPC title

• C10N2040/04

  Oil-bath; Gear-boxes; Automatic transmissions; Traction drives · CPC title

• C10M2219/066

  Thiocarbamic type compounds · CPC title

• C10M2207/026

  with tertiary alkyl groups · CPC title