Functionalized olefin copolymers with monoamine terminated polyether lubricating oil compositions

Patent metadata

Field	Value
Publication number	US-9347015-B2
Application number	US-201213720689-A
Country	US
Kind code	B2
Filing date	Dec 19, 2012
Priority date	Dec 29, 2011
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

A reaction product, useful as a viscosity index improver in a lubricating oil, reacting: a) an oil soluble ethylene-alpha olefin copolymer comprising from 10 to less than 80 weight % ethylene and greater than 20 up to 90 weight % of at least one C 3 to C 28 alpha olefin, having a number average molecular weight from 5,000 to 120,000 and grafted with 0.5 to 5 weight % of an ethylenically unsaturated acylating agent, with b) a hydrocarbyl substituted poly(oxyalkylene) monoamine of the formula: R 1 —(O—CHR 2 —CHR 3 )x-A wherein: R 1 is a hydrocarbyl group having from 1 to 35 carbon atoms; R 2 and R 3 are each independently hydrogen, methyl, or ethyl and each R 2 and R 3 are independently selected in each —O—CHR 2 —CHR 3 — unit; A is amino, —CH 2 amino or N-alkyl amino having 1 to 10 carbon atoms; and x is an integer from 2 to 45.

First claim

What is claimed is:

1. An oil soluble reaction product, useful as a lubricating oil additive, comprising the product of:
a) an oil soluble ethylene-alpha olefin copolymer comprising from 10 to less than 80 weight % ethylene and greater than 20 up to 90 weight % of at least one C 3 to C 28 alpha olefin, having a number average molecular weight from about 5,000 to 120,000 and grafted with 0.5 to 5 weight % of an ethylenically unsaturated acylating agent having at least one carboxylic acid group or anhydride group, with
b) a hydrocarbyl substituted poly(oxyalkylene) monoamine of the formula:
R 1 —(O—CHR 2 —CHR 3 ) x -A

wherein
R 1 is a hydrocarbyl group having from about 1 to about 35 carbon atoms;
R 2 and R 3 are each independently hydrogen, methyl, or ethyl and each R 2 and R 3 are independently selected in each —O—CHR 2 —CHR 3 — unit;
A is amino, —CH 2 amino or N-alkyl amino having about 1 to 10 carbon atoms; and
x is an integer from about 2 to about 45.

2. The oil soluble reaction product of claim 1 wherein the oil soluble olefin copolymer comprises from 35 to less than 60 weight % ethylene and greater than 40 up to 65 weight % of at least one C 3 to C 28 alpha olefins.

3. The oil soluble reaction product of claim 2 wherein the oil soluble ethylene-alpha olefin copolymer comprises from 45 to less than 55 weight % ethylene and greater than 45 up to 55 weight % of at least one C 3 to C 12 alpha olefins.

4. The oil soluble reaction product of claim 3 wherein the at least one C 3 to C 28 alpha olefins is selected from the group comprising C 3 to C 8 alpha olefins.

5. The oil soluble reaction product of claim 1 wherein the oil soluble ethylene-alpha olefin copolymer comprises from 10 to less than 20 weight % ethylene and greater than 80 up to 90 weight % of propylene.

6. The oil soluble reaction product of claim 1 wherein the oil soluble ethylene-alpha olefin copolymer further comprises a nonconjugated diene or triene.

7. The oil soluble reaction product of claim 1 wherein the oil soluble ethylene-alpha olefin copolymer is grafted with 0.6 to 3 weight % of an ethylenically unsaturated acylating agent having at least one carboxylic acid group or anhydride group.

8. The oil soluble reaction product of claim 1 wherein the ethylenically unsaturated acylating agents selected from the group consisting of acrylic, methacrylic, cinnamic, crotonic, maleic, fumaric and itaconic reactants or a mixture thereof.

9. The oil soluble reaction product of claim 8 wherein the ethylenically unsaturated acylating agent is maleic anhydride.

10. The oil soluble reaction product of claim 1 wherein A is —CH 2 amino.

11. The oil soluble reaction product of claim 1 wherein the hydrocarbyl substituted poly(oxyalkylene) monoamine R 1 is selected from the group consisting of alkyl, aryl, alkyaryl, arylalkyl, and arylalkylaryl.

12. The oil soluble reaction product of claim 11 wherein R 1 is alkyl from 1-10 carbon atoms.

13. The oil soluble reaction product of claim 12 wherein R 1 is selected from the group consisting of methyl, ethyl, propyl and butyl.

14. The oil soluble reaction product of claim 11 wherein R 1 is selected from the group consisting phenyl, naphthyl, alkylnapthyl and substituted phenyl having one to three substituents selected from alkyl, aryl, alkylaryl, arylalkyl.

15. The oil soluble reaction product of claim 11 wherein R 1 is selected from the group consisting of phenyl, alkylphenyl, naphthyl and alkylnaphthyl.

Assignees

• Ruhe Jr William Raymond
• Patel Pritesh A
• Chevron Oronite Co

Inventors

• Ruhe Jr William Raymond
• Patel Pritesh A

Classifications

• C10M2203/1025

  used as base material · CPC title

• C10M2223/045

  Metal containing thio derivatives · CPC title

• C10M2205/022

  Ethene · CPC title

• C10M2219/046

  Overbased sulfonic acid salts · CPC title

• C10M2217/06

  Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound · CPC title