Adhesive film, adhesive composition for the same, and display apparatus including the same

Patent metadata

Field	Value
Publication number	US-9346986-B2
Application number	US-201314141410-A
Country	US
Kind code	B2
Filing date	Dec 26, 2013
Priority date	Dec 27, 2012
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

An adhesive film, an adhesive composition for the same, and a display apparatus including the same. The adhesive film includes a urethane functional group, has a glass transition temperature (Tg) of about 30° C. or less, a loss modulus of about 4×10 4 dyn/cm 2 to about 8×10 4 dyn/cm 2 upon frequency sweep testing under conditions of a strain of 3%, 60° C. and 1 rad/s, and tan δ of about 0.2 to 0.55 upon frequency sweep testing under conditions of a strain of 3%, 60° C. and 1 rad/s.

First claim

What is claimed is:

1. An adhesive film comprising a cured product of an adhesive composition comprising:
a urethane(meth)acrylate copolymer comprising a urethane functional group; and
a (meth)acrylic copolymer of a monomer mixture comprising an alkyl(meth)acrylate containing a C 1 to C 20 alkyl group, an alicyclic(meth)acrylate containing an alicyclic group and a monomer containing a hydroxyl group,
wherein the adhesive film has a glass transition temperature (Tg) of about −20° C. or lower, a loss modulus of about 4×10 4 dyn/cm 2 to about 8×10 4 dyn/cm 2 upon frequency sweep testing under conditions of a strain of 3%, 60° C. and 1 rad/s, and tan δ of about 0.2 to 0.55 upon frequency sweep testing under conditions of a strain of 3%, 60° C. and 1 rad/s.

2. The adhesive film according to claim 1 , wherein the adhesive film has a storage modulus of about 4×10 4 dyn/cm 2 or more upon frequency sweep testing under conditions of a strain of 3%, 60° C. and 1 rad/s.

3. The adhesive film according to claim 1 , further comprising:
a non-curable compound.

4. The adhesive film according to claim 3 , wherein the non-curable compound has a structure represented by Formula 1-1 or 1-2:
A1-(—CH 2 O—) n1 -(—CH 2 —) m1 -A2-(—CH 2 O—) n2 -(—CH 2 —) m2 -A3-(—CH 2 O—) n3 -(—CH 2 —) m3 -A4  Formula 1-1

A1-(—CH 2 O—) n1 -(—CH 2 —) m1 -A2-(—CH 2 O—) n2 -(—CH 2 —) m2 -A3-(—CH 2 O—) n3 -(—CH 2 —) m3 -A4-(—CH 2 O—) n4 -(—CH 2 —) m4 -A5  Formula 1-2

wherein n1, n2, n3, n4, m1, m2, m3 and m4 are independently an integer from 0 to 10, and n1 and m1 are not both 0, n2 and m2 are not both 0, n3 and m3 are not both 0, and n4 and m4 are not both 0; and
in Formula 1-1, A1 and A4 are each independently represented by Formula (a), and A2 and A3 are each independently represented by one of Formula (b), (c) or (d), and
in Formula 1-2, A1 and A5 are each independently represented by Formula (a), and A2, A3 and A4 are each independently represented by one of Formula (b), (c) or (d):

wherein R 1 , R 2 , R 3 , R 4 and R 5 are the same or different and are independently selected from the group consisting of hydrogen, a linear or branched C 1 to C 10 alkyl group, a hydroxyl group, a C 1 to C 10 alkyl group substituted with a hydroxyl group, and -(—CH 2 —) s -O-[—CH 2 —CH 2 O—] t -CH 2 CH 2 OH where s is an integer from 0 to 5 and t is an integer from 0 to 5; and at least one of R 1 , R 2 , R 3 , R 4 and R 5 is a hydroxyl group, a C 1 to C 10 alkyl group substituted with a hydroxyl group, or -(—CH 2 —) s -O-[—CH 2 —CH 2 O—] t -CH 2 CH 2 OH where s is an integer from 0 to 5 and t is an integer from 0 to 5.

5. The adhesive film according to claim 4 , wherein the non-curable compound comprises at least one of the structures represented by Formulae 1a to 1e:

wherein R is hydrogen, a hydroxyl group or methyl group, and n is an integer from 0 to 5.

6. The adhesive film according to claim 3 , wherein the non-curable compound is present in an amount of about 0.1 wt % to about 15 wt % in the adhesive film.

7. The adhesive film according to claim 1 , wherein the urethane(meth)acrylate copolymer is a monofunctional (meth)acrylate comprising a single (meth)acrylate functional group.

8. The adhesive film according to claim 1 , wherein the urethane(meth)acrylate copolymer is present in an amount of about 11 wt % to about 40 wt % in the adhesive composition in terms of solid content.

9. The adhesive film according to claim 1 , wherein the monomer mixture of the (meth)acrylic copolymer further comprises a monomer containing a carboxylic acid group, a (meth)acrylate containing a hetero-alicyclic group, or a combination thereof.

10. The adhesive film according to claim 1 , wherein the adhesive composition further comprises at least one of an initiator and a crosslinking agent.

11. The adhesive film according to claim 10 , wherein the adhesive composition comprises about 11 wt % to about 40 wt % of the urethane(meth)acrylate copolymer, about 50 wt % to about 80 wt % of the (meth)acrylic copolymer, about 0.001 wt % to about 5 wt % of the initiator, and about 0.01 wt % to about 5 wt % of the crosslinking agent, in terms of solid content.

12. The adhesive film according to claim 10 , wherein the adhesive composition further comprises a non-curable compound.

13. The adhesive film according to claim 12 , wherein the adhesive composition comprises about 11 wt % to about 40 wt % of the urethane(meth)acrylate copolymer, about 50 wt % to about 80 wt % of the (meth)acrylic copolymer, about 0.001 wt % to about 5 wt % of the initiator, about 0.01 wt % to about 5 wt % of the crosslinking agent, and about 0.1 wt % to about 15 wt % of the non-curable compound, in terms of solid content.

14. The adhesive film according to claim 12 , wherein the adhesive film has a thickness of about 10 μm to about 2 mm.

15. A display apparatus comprising:
an optical film; and
the adhesive film according to claim 1 attached to one or both sides of the optical film.

16. The display apparatus according to claim 15 , wherein the optical film is selected from the group consisting of touch panels, windows, polarizing plates, color filters, retardation films, elliptical polarizing films, reflective films, anti-reflective films, compensation films, brightness enhancing films, alignment films, light diffusion films, glass anti-scattering films, surface protective films, plastic LCD substrates, indium tin oxide (ITO) containing films, fluorinated tin oxide (FTO) containing films, aluminum doped zinc oxide (AZO) containing films, carbon nanotube (CNT) containing films, Ag nanowire containing films, and graphene.

Assignees

• Cheil Ind Inc

Inventors

• Kim Lee June
• Kim Ki Yong
• Kim Jee Hee
• Kim Chan Woo
• Mun Sung Hyun
• Cho Ik Hwan
• Han In Cheon

Classifications

• C09J2201/622

  Chemistry & Metallurgy · mapped topic

• C09J133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C09J2203/318

  for the production of liquid crystal displays · CPC title

• C09J2205/114

  Chemistry & Metallurgy · mapped topic

• C09J7/0207

  Chemistry & Metallurgy · mapped topic