High flow urea-formaldehyde powders for particleboard and fiberboard manufacture

Patent metadata

Field	Value
Publication number	US-9346926-B2
Application number	US-201414203831-A
Country	US
Kind code	B2
Filing date	Mar 11, 2014
Priority date	Mar 14, 2013
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

Particulate binder compositions made with amine-aldehyde resins and methods for making same are provided. The method for making the particulate binder composition can include spray-drying an amine-aldehyde resin having a total aldehyde compound to total amine compound molar ratio of about 1.55:1 to about 1.65:1 to produce a particulate binder composition. The particulate binder composition can have a fusion diameter of about 35 mm to about 70 mm.

First claim

What is claimed is:

1. A method for making a particulate binder composition, comprising:
spray-drying an amine-aldehyde resin having a total aldehyde compound to total amine compound molar ratio of about 1.55:1 to about 1.65:1 to produce a particulate binder composition, wherein the particulate binder composition has a fusion diameter of about 35 mm to about 70 mm.

2. The method of claim 1 , further comprising mixing an intermediate amine-aldehyde reaction product having a total aldehyde compound to total amine compound molar ratio of about 1.7:1 to about 1.8:1 with a first amine compound to produce the amine-aldehyde resin.

3. The method of claim 2 , wherein the intermediate amine-aldehyde reaction product and the first amine compound are reacted to produce the amine-aldehyde resin, and wherein the amine-aldehyde resin has a viscosity of about 900 cP to about 1,200 cP at a temperature of 25° C.

4. The method of claim 2 , wherein the intermediate amine-aldehyde reaction product comprises a urea-formaldehyde resin and the first amine compound comprises urea, and wherein the intermediate amine-aldehyde reaction product is mixed with the first amine compound at a temperature of about 80° C. or less and at a pH of about 6.2 or greater.

5. The method of claim 2 , further comprising:
reacting an aldehyde compound and a second amine compound at a molar ratio of about 1.85:1 to about 1.95:1 to produce a first intermediate; and
mixing the first intermediate with a third amine compound to produce the intermediate amine-aldehyde reaction product.

6. The method of claim 5 , wherein the first intermediate is reacted with the third amine compound to produce the intermediate amine-aldehyde reaction product, and wherein the intermediate amine-aldehyde reaction product has a viscosity of about 300 cP to about 500 cP at a temperature of 25° C.

7. The method of claim 5 , wherein the aldehyde compound and the second amine compound are reacted at a temperature of about 95° C. or less and at a pH of about 5.3 to about 5.5 to produce the first intermediate, wherein the first intermediate has a viscosity of about 160 cP to about 250 cP at a temperature of 25° C., and wherein the first intermediate is further reacted at a temperature of about 80° C. or less and at a pH of about 5.4 to about 5.7.

8. The method of claim 1 , wherein the particulate binder composition has a stroke cure time of about 30 seconds to about 45 seconds.

9. The method of claim 1 , wherein the amine-aldehyde resin has a total solids content from about 50 wt % to about 70 wt %.

10. The method of claim 1 , wherein:
the amine-aldehyde resin comprises a urea-formaldehyde resin,
the particulate binder composition has a fusion diameter of at least 40 mm to about 70 mm,
the particulate binder composition has a stroke cure time of about 30 seconds to about 45 seconds,
the particulate binder composition has an average particle size of about 0.1 μm to about 150 μm, and
the particulate binder composition has a packed bulk density from about 0.3 g/cm 3 to about 0.8 g/cm 3 .

11. The method of claim 1 , further comprising:
combining the particulate binder composition with a plurality of lignocellulose substrates to form a curable mixture; and
at least partially curing the curable mixture to produce a composite product.

12. The method of claim 11 , wherein the amine-aldehyde resin comprises a urea-formaldehyde resin.

13. A method for making a particulate binder composition, comprising:
reacting an intermediate amine-aldehyde reaction product having a total aldehyde compound to total amine compound molar ratio of about 1.7:1 to about 1.8:1 with a first amine compound to produce a liquid amine-aldehyde resin having a total aldehyde compound to total amine compound molar ratio of about 1.55:1 to about 1.65:1;
agitating the liquid amine-aldehyde resin to produce an aerated mixture; and
spray-drying the aerated mixture to produce the particulate binder composition, wherein the particulate binder composition has a fusion diameter of about 35 mm to about 70 mm.

14. The method of claim 13 , wherein the intermediate amine-aldehyde reaction product comprises a urea-formaldehyde resin and the first amine compound comprises urea, and wherein the intermediate amine-aldehyde reaction product is mixed with the first amine compound at a temperature of about 80° C. or less and at a pH of about 6.2 or more.

15. The method of claim 13 , further comprising:
reacting an aldehyde compound and a second amine compound at a molar ratio of about 1.85:1 to about 1.95:1 to produce a first intermediate; and
reacting the first intermediate to produce the intermediate amine-aldehyde reaction product.

16. The method of claim 13 , wherein the intermediate amine-aldehyde reaction product and the first amine compound are reacted to produce the liquid amine-aldehyde resin having a viscosity of about 900 cP to about 1,200 cP at a temperature of 25° C.

17. A spray-dried particulate binder composition comprising an amine-aldehyde resin having a total aldehyde compound to total amine compound molar ratio of about 1.55:1 to about 1.65:1, wherein the spray-dried particulate binder composition has a fusion diameter of about 35 mm to about 70 mm.

18. The spray-dried particulate binder composition of claim 17 , wherein the amine-aldehyde resin comprises a urea-formaldehyde resin.

19. The spray-dried particulate binder composition of claim 17 , wherein the spray-dried particulate binder composition has a fusion diameter of at least 40 mm to about 70 mm and a stroke cure time of about 30 seconds to about 45 seconds.

20. The spray-dried particulate binder composition of claim 17 , wherein:
the amine-aldehyde resin comprises a urea-formaldehyde resin,
the spray-dried particulate binder composition has a fusion diameter of at least 40 mm to about 70 mm, a stroke cure time of about 30 seconds to about 45 seconds, an average particle size of about 0.1 μm to about 150 μm, and a packed bulk density of about 0.3 g/cm 3 to about 0.8 g/cm 3 .

Assignees

• Georgia Pacific Chemicals Llc

Inventors

• Breyer Robert A
• Krauth Tyler
• Cothran John D
• Baxter Paul S
• Cribb Ashlee

Classifications

• B27N3/02

  from particles · CPC title

• C08L61/24

  with urea or thiourea · CPC title

• C08J3/122 Primary

  Pulverisation by spraying · CPC title

• C08J2361/24

  with urea or thiourea · CPC title

• C08L97/02

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title