Crystalline Sp-Sp2 Hybridized Carbon Allotropes through Dynamic Covalent Synthesis
US-2024286903-A1 · Aug 29, 2024 · US
US9346748B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9346748-B2 |
| Application number | US-201214008532-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 20, 2012 |
| Priority date | Nov 30, 2011 |
| Publication date | May 24, 2016 |
| Grant date | May 24, 2016 |
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Provided are a functional-group-modified carbon material modified with an isocyanate group or amino group, and a method for producing the material. The material is an isocyanate-group-modified carbon material in which an isocyanate group of a diisocyanate compound is bonded to a graphene-like carbon material, or an amino-group-modified carbon material in which a fragment obtained by radical-decomposing an amino-group-containing azo-type radical initiator is added to the graphene-like carbon material by radical-trapping. The method is a method for producing a functional-group-modified carbon material, including heating and stirring, in a solvent, a graphene-like carbon material, and a diisocyanate compound or an amino-group-containing azo-type radical initiator.
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The invention claimed is: 1. A functional-group-modified carbon material, a fragment obtained by radical-decomposing an amino group-containing azo-type radical initiator being added to exfoliated graphite by radical-trapping, wherein the exfoliated graphite is a laminate of plural graphene layers that is obtained by peeling off flakes from non-oxidized ordinary graphite and is a material in which the number of graphene layers laminated is from several to about 200 and the specific surface area is from about 600 to 2500 m 2 /g. 2. A method for producing a functional-group-modified carbon material, comprising: heating and stirring, in a solvent, exfoliated graphite, and an amino-group-containing azo-type radical initiator, wherein the exfoliated graphite is a laminate of plural graphene layers that is obtained by peeling off flakes from non-oxidized ordinary graphite and is a material in which the number of graphene layers laminated is from several to about 200 and the specific surface area is from about 600 to 2500 m 2 /g. 3. The method for producing a functional-group-modified carbon material according to claim 2 , wherein the azo-type radical initiator is an azo-type radical initiator having a secondary or tertiary amino group. 4. A composite material comprising the functional-group-modified carbon material according to claim 1 , and a resin. 5. The composite material according to claim 4 , wherein the resin is in the form of resin fine particles.
Compounds containing {one or more} carbon-to-nitrogen double bonds · CPC title
Nano-sized carbon materials · CPC title
Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title
having isocyanate groups bound to acyclic carbon atoms · CPC title
Amines; Quaternary ammonium compounds · CPC title
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