Catalyst systems and selective hydrogenation processes

Patent metadata

Field	Value
Publication number	US-9346719-B2
Application number	US-84224010-A
Country	US
Kind code	B2
Filing date	Jul 23, 2010
Priority date	Jul 24, 2009
Publication date	May 24, 2016
Grant date	May 24, 2016

Abstract

A hydrogenation catalyst system is provided. The catalyst system includes a metal complex of Formula (I), an organic lithium compound and an organic compound having a cyclic structure including at least one double bond.

In Formula (I), M is transition metals. R 1 , R 2 , R 3 , R 4 and R 5 are the same or different, including hydrogen, C1-8 alkyl, and C1-8 alkoxy, or two of R 1 , R 2 , R 3 , R 4 and R 5 are linked together to form a ring. X 1 , X 2 and X 3 are a cyclic group, hydrogen, chlorine, bromine, alkyl or alkoxy, wherein when one of X 1 , X 2 and X 3 is a cyclic group, and the others are the same or different, including hydrogen, chlorine, bromine, alkyl or alkoxy. The invention also provides a selective hydrogenation process utilizing the catalyst system.

First claim

What is claimed is:

1. A catalyst system, comprising:
a metal complex of Formula (I):

wherein M is a transition metal, R 1 , R 2 , R 3 , R 4 and R 5 are the same or different, comprising hydrogen, C1-8 alkyl, and C1-8 alkoxy, or two of R 1 , R 2 , R 3 , R 4 and R 5 are linked together to form a ring, and X 1 , X 2 and X 3 are a cyclic group, hydrogen, chlorine, bromine, alkyl or alkoxy, wherein when one of X 1 , X 2 and X 3 is a cyclic group, and the others are the same or different, comprising hydrogen, chlorine, bromine, alkyl or alkoxy;
an organic lithium compound of a formula of LiR, wherein R is C1-6 alkyl; and
an organic compound having a cyclic structure comprising at least one double bond comprising diphenylmethane, diphenylethane, dimethylbiphenyl, ethylbiphenyl, diphenylpropane, benzylbiphenyl, triphenylmethane, indene, methylindene, ethylindene, dihydronaphthalene, methylnaphthalene, ethylnaphthalene, fluorene, methylfluorene or ethylfluorene.

2. The catalyst system as claimed in claim 1 , wherein M is titanium, zirconium or hafnium.

3. The catalyst system as claimed in claim 1 , wherein the metal complex and the organic compound having a cyclic structure containing at least one double bond have a molar ratio of 0.1:1-50:1.

4. The catalyst system as claimed in claim 1 , wherein the organic lithium compound and the metal complex have a molar ratio of 1:1-12:1.

5. The catalyst system as claimed in claim 1 , wherein the organic compound having a cyclic structure containing at least one double bond and the organic lithium compound have a molar ratio of 0.1:1-12:1.

Assignees

• Shih Kuo-Chen
• Chen Hung-Yu
• Hsueh Mao-Lin
• Chen yi-zhen
• Ind Tech Res Inst
• Lee Chang Yung Chemical Industry Corp

Inventors

• Shih Kuo-Chen
• Chen Hung-Yu
• Hsueh Mao-Lin
• Chen yi-zhen

Classifications

• C07C2102/10

  Chemistry & Metallurgy · mapped topic

• C07C2102/08

  Chemistry & Metallurgy · mapped topic

• C07C2103/18

  Chemistry & Metallurgy · mapped topic

• C07C2531/38

  of titanium, zirconium or hafnium · CPC title

• B01J31/2295

  Cyclic compounds, e.g. cyclopentadienyls · CPC title